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Fabrication of ordered porous films from soluble polyimide based on Breath figures

Authors： LIU Yan hua1,2, WANG Li hua2*, HAN Xu tong1

Units： 1. Laboratory of New Materials, Institute of Chemistry,

KeyWords： soluble polyimide; ordered porous films; Breath figure; self-assembly;hydrophobic surface

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2013,33(4):7-11

Abstract：

The breath figure is the method to prepare ordered porous films using condensed water droplet arrays as template which is formed by self-assembly. This method has attracted considerable attention due to its facility and the automatic removal of the condensed water droplets. The ordered porous films are successfully prepared from a soluble polyimide named BTDA-DMMDA which is synthesized from 3,3’, 4,4’-benzophenone -tetracarboxylic dianhydride (BTDA) and 4,4’-diamino-3,3’-dimethyldiphenylmethane (DMMDA). Several influencing factors on the morphologies of the ordered pores, such as different humid atmosphere, relative humidity (RH), and solid substrates, are investigated. Furthermore, the hydrophilicity of the porous film is discussed. The results indicate that the pore size, ranging from 400nm to 2μm, can be dynamically controlled by changing RH, that the hydrophilic substrates is more conducive to form ordered porous films and that the contact angle increases a lot by peeling off the porous film’s surface. The film with surface being peeled off has potential application in super hydrophobic surface.

Funds：

国际973项目（2009CB623407）和北京分子科学中心创新培育项目（CMS-PY-201220）

AuthorIntro：

刘艳花（1987-），女，山西省忻州市人，硕士，研究方向为聚酰亚胺膜的构筑及应用。*通讯联系人，E-mail：wanglh@iccas.ac.cn

Reference：

[1] Takazawa K. Micrometer-sized rings self-assembled from thiacyanine dye molecules and their waveguiding properties[J]. Chem Mater, 2007, 19: 5293-5301.
[2] HU Xiaobin, LI Guangtao, LI Maohan, etal. Ultrasensitive specific stimulant assay based on molecularly imprinted photonic hydrogels[J]. Adv Funct Mater, 2008, 18(4): 575-583.
[3] Corma A , Davis M E. Issues in the synthesis of crystalline molecular sieves: Towards the
crystallization of low framework-density structures[J]. Chem Phys Chem, 2004, 5(3): 304-313.
[4] Nakanishi K M, Soga N, Tanaka N J. Structure design of double-pore silica and its application to HPLC[J]. Sol-Gel Sci Technol, 1998, 13: 163-169.
[5] Hoa M L K, Lu M, Zhang Y. Preparation of porous materials with ordered hole structure[J]. Advances in Colloid and Interface Science, 2006, 121: 9-23.
[6] Widawski G, Rawiso M, Francois B. Self-organized honeycomb morphology of star-polymer polystyrene films[J]. Nature, 1994, 369: 387-389.
[7] 田野，王丽华，丁怀宇，等．可溶性聚酰亚胺规整多孔膜的形成与控制[J]．膜科学与技术，2009，29(4)：2338-2344．
[8] 王丽华，赵之平，李继定，等．一种可溶性聚酰亚胺的合成及其渗透汽化脱有机硫化物性能测试[J]．高分子学报，2006，(4)：496-499．
[9] Harris F W, Cheng S Z D. Process for Preparing aromatic polyimide fibers[P]. US Patent, 5378420, 1995.
[10] Alexander A, Kuznetsov. One-pot polyimide synthesis in carboxylic acid medium[J]. High Performance Polymers, 2000, 12: 445-460.
[11] Yabu H, Tanaka M，Ijiro K, etal. Preparation of honeycomb-patterned polyimide films by self -organization[J]. Langmuir, 2003, 19: 6297-6300.
[12] 景晓辉，黄丹，乔旭．共缩聚型可溶性聚酰亚胺的合成与性能[J]. 现代塑料加工应用，2005，(6)：1-3．
[13] Alexander A K, Marina Y Y, Pavel V B, etal. New alternating copolyimides by high temperature synthesis in benzoic acid medium[J]. High Performance Polymers, 2004, 16: 89-100.
[14] 赵晓勇，蔡晴，石桂欣，等．水蒸气辅助法制备LA-GA共聚物蜂窝状多孔膜[J]．膜科学与技术，2004，24(2)：1-6．
[15] Tian Ye, Jiao Qingze, Ding Huaiyu, etal．The formation of honeycomb structure in polyphenylene oxide films[J]. Polymer, 2006, 47(11): 3866-3873．
[16] Wang Lihua, Tian Ye, Ding Huaiyu, etal. Formation of ordered macroporous films from fluorinated polyimide by water droplets templating[J]. Euro Polym J, 2007, 43: 862-869.
[17] Srinivasarao M, Ollings D, Philips A, etal . Three-dimensionally ordered array of air bubbles in a polymer film[ J] . Science, 2001, 292: 79-83.
[18] Yabu H., Takebayashi M., Tanaka M, etal. Superhydrophobic and lipophobic properties of self-organized honeycomb and pincushion structures[J]. Langmuir, 2005, 21(8): 3235-3237.
[19] Stenzel M H. Formation of regular honeycomb-patterned porous film by self-organization[J]. Aust J Chem, 2002, 55(4): 239-243.
[20] Wong K H, Davis T P, Barner-Kowollik C, etal. Honeycomb structured porous films from amphiphilic block copolymers prepared via RAFT polymerization[J]. Polymer, 2007, 48(17): 4950-4965.

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