Study on the mass transfer characteristics of acrylic acid in anion-exchange membranes |
Authors: Chen Jing1,2 , Song Yudong2 , Zhou Yuexi1,2 , Wang Ya-e1 , Li Jie1 |
Units: 1.School of Environmental and Municipal Engineering,Lanzhou Jiaotong University,Lanzhou 730070;2. Research Center of Water Pollution Control Technology,Chinese Research Academy of Environmental Sciences,Beijing 100012 |
KeyWords: bipolar membrane electrodialysis; acrylic acid; anion-exchange membrane; mass transfer characteristics |
ClassificationCode:TQ028 |
year,volume(issue):pagination: 2013,33(5):38-42 |
Abstract: |
the mass transfer characteristics of the acrylic acid in two different anion exchange membranes (JAM-I-10 and ACM homogeneous membrane) were studied. It was indicated that the effect of temperature and acrylic acid concentration on mass transfer coefficient across JAM-I-10 and ACM membranes was the same. In the range of 15 to 30℃, the mass transfer coefficient increased with the increase of the temperature and followed the Arrhenius' Equation. At the temperature of 20℃, when the concentration of acrylic acid increased from 0.5mol/L to 4.0mol/L, the mass transfer coefficient changed little. Under the same condition, the mass transfer coefficient of acrylic acid in the ACM homogeneous membrane was significantly lower than that in the JAM-I-10 homogeneous membrane. |
Funds: |
基金项目:国家“水体污染控制与治理”科技重大专项(2012ZX07201-005) |
AuthorIntro: |
陈 静(1987-),女,甘肃静宁人,硕士研究生,主要从事水污染控制技术研究工作。E-mail chjing_0726@163.com *通讯联系人:周岳溪,E-mail zhouyuexi@263.net |
Reference: |
[1] 张立岩,戴伟.丙烯氧化合成丙烯酸工艺及催化剂的研究进展[J].石油化工,2010,39(7):818-822. [2] 洪仲苓.化工有机原料的加工[M].北京:化学工业出版社,1997. 363-400. [3] 范志庆,宋玉栋,周岳溪,等.离子色谱法测定丙烯酸丁酯生产废水中丙烯酸和对甲基苯磺酸[J].中国环境监测,2010,26(3):26-28. [4] 赵英,路光杰,尹连庆,等.双极膜电渗析法制备酸碱的研究[J].天津化工,2003,17(2):1-3. [5] 徐芝勇,张建国.双极膜电渗析技术在有机酸生产中的应用进展[J].膜科学与技术,2007,27(3):75-79. [6] 林涛,余立新.双极性膜电渗析技术在酒石酸生产中的应用研究[J].化学工程,2002,30(3):58-61. [7] 李娟,陈振,王鹏,等.双极膜电渗析分离发酵液中L-乳酸[J].生物加工过程,2009,7(6):45-50. [8] 张鹏,彭勇,余立新,等.双极性膜电渗析法连续处理酚钠的工业实验研究[J].膜科学与技术,2010,30(2):86-88. [9] 雷智平,凌开成.双极膜电渗析法处理谷氨酸水溶液的过程性能研究[J].环境污染治理技术与设备,2003,4 (2):33-35. [10] 李鑫,宋玉栋,周岳溪,等.双极膜电渗析法回收丙烯酸丁酯废水中的有机酸[J].化工环保,2011,31(3):197-201. [11] Wodzki R, Nowaczyk J. Membrane transport of organics. II. Permeation of some carboxylic acids through bipolar polymer membrane[J]. Appl Polym Sci, 1999,71: 2179-2190. [12] Wodzki R, Nowaczyk J. Membrane transport of organics. III. Permeation of some carboxylic acids through strongly basic polymer membrane[J]. Appl Polym Sci, 2001,80: 2705-2717. [13] Narebska A, Kurantowicz M, Staniszewski M. Separation of fermentation products by membrane techniques. IV. Electrodialytic conversion of carboxylates to carboxylic acids[J].Sep Sci Technol, 2001,36:443-455. [14] 余立新,郭庆丰,黄科,等.极稀醋酸废水处理的双极性膜电渗析法[J]. 膜科学与技术,2000,20(2):31-38. [15] Jaime-Ferrer J S, Couallier E, Viers P, et al. Three-compartment bipolar membrane electrodialysis for splitting of sodium formate into formic acid and sodium hydroxide: Role of diffusion of molecular acid[J]. J Membr Sci, 2008,325:528-536. [16] Gineste J L, Pourcelly G, Lorrain Y, et al. Analysis of factors limiting the use of bipolar membranes: a simplified model to determine trends[J]. J Membr Sci, 1996, 112:199-208. [17] 靳福泉.阿累尼乌斯方程探讨[J].大学化学,2007,22(5):45-53. [18] Jaime-Ferrer J S, Couallier E, Viers P, et al.Two-compartment bipolar membrane electrodialysis for splitting of sodium formate into formic acid and sodium hydroxide: Modelling[J]. J Membr Sci, 2009,328:75-80 |
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