Position:Home >> Abstract

Preparation and properties of PVA-CS/PHBV composite membrane 
Authors: ZHAO Xiaohua, ZHAO Xiaoyan, WANG Ming, JI Junling
Units: College of Petrochemical Engineering, Changzhou University, Changzhou 213164,China
KeyWords: PVA-CS/PHBV; composite membrane;electrospinning; filtration
ClassificationCode:TQ342
year,volume(issue):pagination: 2014,34(3):63-68

Abstract:
PVA-CS/PHBV composite membranes were prepared by coating the PVA/CS solution on the surface of PHBV electrospun fibers. The properties of PVA-CS/PHBV composite membranes were investigated throught adjusting the volume ratio of PVA/CS. The viscosity and mass ratio of PVA/CS were the main factors that influenced on the morphology of the PVA-CS/PHBV composite membranes. SEM was used to observe the surface and cross-sectional morphology of these membranes. The uniform PHBV fibers as based layer could be obtained at 8 wt%. After adjusting the proper PVA/CS solutions, the smooth and fully CS-PVA coated layer was covered on the PHBV scaffold surface as 8 wt% PVA-2.5 wt%CS (PVA/CS, 5:5 ). As the results, the permeate flux and ovalbumin rejection of PVA-CS/PHBV composite membranes could reach 6.41×103 L/(m2?h) and 89.94%, respectivily. Further more, the composite membranes exhibited good adsorption and separation of heavy metal ion and disperse dyes

Funds:
国家自然科学基金青年基金项目(51103016);江苏省自然科学基金项目(BK2011241);东华大学纤维改性国家重点实验室项目(LK1001)

AuthorIntro:
赵晓画(1987?),女,河南许昌人,硕士,从事纤维复合膜制备及性能研究

Reference:
[1] Haider S, Park S Y. Preparation of electrospun chitosan nanofibers and their applications to the adsorption of Cu(II) and Pb(II) ions from an aqueous solution[J]. Journal of Membrane Science, 2009, 328:90-96.     
[2] Chauhan G S, Chauhan K, Kumar S, et al. Functionalization of pine needles by carboxymethylation and network formation for use as supports in the adsorption of Cr6+[J]. Carbohydrate Polymer, 2007, 70 :415-421.
[3]Wang Y X, Yu J. Adsorption and degradation of synthetic dyes on the mycelium of trametes versicolor[J].Water Science and Technology, 1998, 38(4): 233-238.
[4] Mazalevska O, Struszczyk M H, Krucinska I. Design of Vascular Prostheses by Melt Electrospinning-Structural Characterizations[J]. Journal of Applied Polymer Science, 2013, 129:779-792.
[5] Sun M G , Zhang Y P, Zhao Y M, et al. The structure-property relationships of artificial silk fabricated by dry-spinning process[J]. Journal of Materials Chemistry, 2012, 22: 18372-18379.
[6]Olsson Ca, Westman G. Wet Spinning of Cellulose from Ionic Liquid Solutions-Viscometry and Mechanical Performance[J]. Journal of Applied Polymer Science, 2013, 127: 4542-4548.
[7]Liang D H, Benjamin S H, Benjamin C. Functional electrospun nanofibrous scaffolds for biomedical applications[J]. Advanced Drug Delivery Reviews,2007, 59 :1392-1412.
[8] 顾红霞, 潘凯, 董泽刚, 等. 聚丙烯腈静电纺丝膜表面界面聚合制备复合纳滤膜[J]. 膜科学与技术, 2012, 32: 50-54.
[9] 陈哲, 林晓艳, 李莹, 等. PLA/TCMC静电纺丝膜的制备及溶液中Cu2+离子的去除[J]. 膜科学与技术, 2013, 33: 86-91.
[10] Ran Wang, Yang Liu, Brandon Li, et al. Electrospun nanofibrous membranes for high flux microfiltration[J]. Journal of Membrane Science, 2012, 392-393:167-174.
[11]Gopal R, Kaur S, Matsuura T, et al. Electrospun nanofibrous polysulfone membranes as pre-filters: Particulate removal[J]. Journal of Membrane Science, 2007, 289: 210-219.
[12]Zong X H, Hsiao B S, Chu B, et al. Structure and process relationship of electrospun bioabsorbable nanofiber membranes[J]. Polymer, 2002, 43:4403-4412.
[13]陈龙, 陈彦模, 朱美芳, 等. β-羟基丁酸与β-羟基戊酸共聚物的流动性能[J]. 合成纤维, 2002, 31: 3-5.
[14] Zuo W W, Zhu M F, Chen Y M, et al. Experimental Study on Relationship Between Jet Instability and Formation of Beaded Fibers During Electrospinning[J]. Polymer engineering and science, 2005,45: 704-709.
[15] 张锴, 朱美芳, 陈彦模, 等. PHBV/ CH2Cl2溶液体系静电纺纤维直径及其分布控制[J]. 合成纤维, 2007, 7: 21-26.
[16] Wang C C, Yang F L, Zhang H M. Fabrication of non-woven composite membrane by chitosan coating for resisting the adsorption of proteins and the adhesion of bacteria[J]. Separation and Purification Technology, 2010, 75: 358-365.
[17] Yoon K, Wang X F, Hsiao B S, et al. High flux ultrafiltration membranes based on electrospun nanofibrous PAN scaffolds and chitosan coating[J]. Polymer, 2006, 47: 2434-2441.
[18] Fong H, Chun I, Reneker D H. Beaded nanofibers formed during electrospinning[J]. Polymer,1999,40:585-592.
[19] 赵涛, 廖萍, 代鹏. 光交联壳聚糖-(PVA-SbQ)共混膜的制备与性能表征[J].功能材料,  2009,7:1204-1207.
[20] P.C. Srinivasa, M.N. Ramesh, R.N. Tharanathan. Effect of plasticizers and fatty acids on mechanical and permeab

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号