膜科学与技术

Position：Home >> Abstract

Effects of membrane-formation substrate on the structure and gas separation performance of carbon membranes

Authors： ZHANG Bing 1, Dang Xiaolong 1, WU Yonghong 1, YU Zhixue 1, WANG Tonghua 2

Units： 1. School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang, Liaoning 111003, China;

KeyWords： Membrane-formation substrate; Carbon membranes; Porous structure; Permeation

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2014,34(6):17-21

Abstract：

Carbon membranes were prepared using resorcinol-formaldehyde as precursor and F127 as additives, through the processes of membrane-forming and carbonization. The thermal stability of precursors and their formation of carbon structure were analyzed by thermogravimetry analysis, Infrared spectroscopy, elemental analysis and transmittance electron microscopy at microscale level. The carbon structure and porous structure of carbon membranes were also measured by X-ray diffraction and N2 adsorption technique. The surface hydrophobicity of membrane-formation substrate was correlated with the shrinkage during membrane formation, carbon structure, porous structure and gas separation performance of resultant carbon membranes. Results have shown that membrane-formation substrate definitely has great effect on the microstructure and separation performance of carbon membranes. Compared with polytetrafluoroethylene and stainless steel, glass plate with higher hydrophobicity is beneficial for deceasing radial shrinkage during membrane formation, resulting into larger specific surface area and pore volume in carbon membranes. A satisfactory O2/N2 selectivity is attained above 10 for carbon membranes formed on glass plate.

Funds：

国家自然科学基金（20906063），辽宁省自然科学基金（20102170），辽宁省高校优秀人才项目（LJQ20120101）和精细化工国家重点实验室开放课题（KF1107）。

AuthorIntro：

张兵（1977－），男，博士，副教授，主要从事炭膜制备及应用研究；

Reference：

[1] Ismail A F, Rana D, Matsuura T, et al. Carbon-based membranes for separation processes[M]. Springer New York Dordrecht Heidelberg London, 2011.
[2] Ismail A F, Saufi S M. Fabrication of carbon membranes for gas separation–a review[J]. Carbon, 2004, 42: 241–259.
[3] Tin P S, Xiao Y, Chung T-S. Polyimide-carbonized membranes for gas separation: structural, composition, and morphological control of precursors[J]. Sep Puri? Rev, 2006, 35: 285–318.
[4] Salleh W N W, Ismail A F, Matsuura T, et al. Precursor selection and process conditions in the preparation of carbon membrane for gas separation: a review[J]. Sep Puri? Rev, 2011, 40: 261–311.
[5] 张兵,王同华,呼立红,等. 聚酰亚胺基气体分离炭膜的进展[J]. 膜科学与技术, 2007, 27: 97-101.
[6] Wang C, Mao Y, Wang D, et al. Fabrication of highly ordered microporous thin films by PS-b-PAA self-assembly and investigation of their tunable surface properties[J]. J Mater Chem, 2008, 18: 683–690.
[7] Fuertes A B, Centeno T A. Preparation of supported carbon molecular sieve membrane [J]. Carbon, 1999, 37: 679–684.
[8] Tseng H-H, Shih K, Shiu P-T, et al. Influence of support structure on the permeation behavior of polyetherimide-derived carbon molecular sieve composite membrane[J]. J Membr Sci, 2012, 405–406: 250–260.
[9] 刘诗丽. 聚醚砜酮预氧化机理及其炭膜制备工艺优化[D]. 大连：大连理工大学博士学位论文, 2008.
[10] 孟繁妍.有序纳米孔炭膜的制备及表征[D]. 沈阳: 沈阳工业大学硕士学位论文, 2012.
[11] 同小刚，王芬，冯海涛. 疏水型二氧化硅气凝胶薄膜的制备[J]. 中国陶瓷, 2006, 42：29–31.
[12] Zhang B, Wang T, Zhang S, et al. Preparation and characterization of carbon membranes made from poly(phthalazinone ether sulfone ketone) [J]. Carbon, 2006, 44: 2764-2769.
[13] 马伟.酚醛树脂的热解研究[D]. 重庆: 重庆大学硕士学位论文, 2007.
[14] 李淑君，李坚，刘一星，等. 用TG-DSC-FTIR联用技术研究酚醛树脂的热解行为[J]. 东北林业大学学报，2007, 35: 56-58.
[15] Lin H P, Chang-Chien C Y, Tang C Y, et al. Synthesis of p6mm hexagonal mesoporous carbons and silicas using pluronic F127-PF resin polymer blends [J]. Microporous and Mesoporous Mater, 2006, 93: 344–348.
[16] 姜华玮，王同华，李琳，等. 有序介孔复合炭膜的制备及其性能研究[J]. 新型炭材料, 2010, 25: 273–278.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com