Preparation and Application of Bipolar Membrane of Extracting Potassium Selectively from Seawater |
Authors: XIAO Yan-chun1,2 ,CHEN Biao1,HUANG Jing1,LIU Ming-hua3 |
Units: 1Institute of Agri- engineering Technology,Fujian Academy of Agricultural Science Fuzhou 350003; |
KeyWords: 18–Crown–6; IIBPM; Preparation; Characterization; Application |
ClassificationCode:TQ443.3 |
year,volume(issue):pagination: 2015,35(3):85-91 |
Abstract: |
Sodium carboxymethyl cellulose (CMC) and Chitosan (CS) were prepared as natural materials,then modified by 18–crown–6 (18–C–6) and glutaraldehyde (GA), respectively. mCMC+18–C–6/mCS ion imprinted bipolar membrane(IIBPM)was prepared by a paste method.The IIBPM was characterized by moisture content,Infrared Spectroscopy (IR), transmembrane voltage, AC impedance,thermal stability,respectively. The results showed that the property of IIBPM was improved after modified by 18–C–6.mCMC+18–C–6/mCS IIBPM was applied to extract potassium resources in Ningde city. When the penetration time was 150 min, the permeability rate of K+ through the mCMC+18–C–6/mCS IIBPM was up to 95%. |
Funds: |
福建省省属公益类优势领域项目(2014R1015-13);2014年度农科院院青年科技创新项目(2014CX-14、2014CX-13) |
AuthorIntro: |
第一作者简介:肖艳春(1984-),女,工学硕士,福建省农业科学院,助理研究员,主要从事农业环境保护技术研究。 *通讯作者:陈彪,副研究员,0591-87869461,E-mail:ny_chenbiao@sohu.com。]*, |
Reference: |
[1] 徐铜文.离子交换膜的重大国家需求和创新研究[J].膜科学与技术,2008,28(5):1~10. [2] 陈双,陈巧平,郑曦,等.三明治式双极膜的制备及其光催化性能[J].应用化学, 2010, 27(11):1301~1305. [3] 马秀玲,陈日耀,郑曦,等.柚皮苷分子印迹膜的水相制备与识别[J].高分子学报, 2010,4(4):416~421. [4] 小田良平,庄野利之,田伏岩夫编,杨季秋,彭第基译.王冠醚化学[M].北京,原子能出版社,1985:1~10. [5] Muzzarelli R.Vivo biochemical significance of chitin-based medical items [M]. Dumitriu S.Polymeric Biomaterials. New York: Marcel Dekker,1993:179~197. [6] 毛晖,梁渠,林平,等.冠醚研究的新进展[J].江苏化工.2008:36(2):21~29. [7] 张来新,赵卫星,杨琼,等.蓬勃发展的冠醚化学[J].合成老化及应用,2011: 40(4):37~40. [8] 王世伟,高保娇,高学超,等.固载化冠醚二苯并-18-冠-6在苯甲酸丁酯合成反应中的相转移催化作用[J].物理化学学报,2010,26(4):927~930. [9] GUO Xiaojing,ZHU Yudan,WEI Mingjie,et.al.Theoretical Study of Hydration Effects on the Selectivity of 18-Crown-6 Between K+ and Na+[J].Chinese Journal of Chemical Engineering.2011,19(2): 212~216. [10] 庾莉萍.我国积极破解钾盐矿资源短缺迷局[J].盐湖研究,2007,15(4):49~55. [11] 庾莉萍.世界钾肥生产垄断局面及供应紧张形势[J].磷肥与复肥,2009,24(1): 18~20. [12] 烟伟,黄西平,张琦,等.我国海水提钾的产业化前景[J].海湖盐与化工,2004,33(4): 13~17. [13] Kielland J. Individual activity coefficients of ions in aqueous solutions[J]. J. Am. Chem. Soc., 1937, 59 (9): 1675~1678 . [14] 松下浩.海水等ょりロ●ル土盒さ採取ょゐ方法[P]. JP 45 -38961,1970 -12 -18. [15] 古映莹,钟世安.隐锰型MnO2对K+、Na+的离子交换选择性[J].贵州大学学报, 2001,18 (2):124 ~126. [16] 吴成泰.冠醚化学[M].北京:科学出版社,1992:120~121. [17] Simons R. A novel memod for preparing bipolar mem-branes[J]. Electrochim Acta,1986,31(9):1175~1177. |
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