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PS-b-PAA/PLA ordered porous antibacterial film

Authors： ZHU Ting1 CHEN Haiyan1,3 XU Weichao1 ZHANG Ming1,2

Units： 1 School of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu Yangzhou, Zip Code 225002, 2 Yangzhou University test center, Jiangsu Yangzhou, Zip Code 225009, 3Yangzhou Polytechnic College, Jiangsu Yangzhou, Zip Code 225127

KeyWords： atom transfer radical polymerization; amphiphilic block copolymer; PLA; antibacterial films

ClassificationCode：O631；TB324

year,volume(issue):pagination： 2015,35(4):1-6

Abstract：

Amphiphilic Block copolymers of polystyrene and poly(acrylic acid) were prepared by atom transfer radical polymerization techniques(ATRP). The molecular weights and polydispersities, composition, structure and hydrolytic percentage of the polymers were determined by gel permeation chromatography (GPC), 1HNMR spectra, FT-IR and titration. The as-synthesized amphiphilic PS-b-PAA was introduced to assist the fabrication of ordered porous PLA film. Several influencing factors on the morphology of film were investigated, such as the length of PAA block, the addition content of PS-b-PAA, concentration of solution and relative humidity. Then the pores of PS-b-PAA/PLA films were filled with tea polyphenol to achieve the antibacterial film whose antibacterial performance were evaluated by antibacterial ring method. The results indicated that the presence of film hole and aperture have an impact on load amount of antibacterial agent, which will effect the antibacterial performance.

Funds：

江苏省环境材料与环境工程重点实验室开放课题（K13073）

AuthorIntro：

朱婷（1990-），女，江苏靖江人，硕士研究生。

Reference：

[1] Danelle B, Kok Hou W, Charles W, et al. Honeycomb-structure porous films from polypyrrole-containning block copolymers prepared via RAFT polymerization as a scaffold for cell growth[J]. Biomacromolecules, 2006, 4(7): 1072-1082.
[2] Ke Beibei, Wan Lingshu, Zhang Wenxu, et al. Controlled synthesis of linear and comb-like glycopolymers for preparation of honeycomb-patterned films[J]. Polymer, 2010, 51(10): 2168-2176.
[3] Widawski G, Rawiso M, Francois B. Self-organized honeycomb morphology of star-polymer polystyrene films[J]. Nature, 1994. 387-389
[4]兰平，李剑，龚剑亮，等. 甲醇气氛静态呼吸图法制备蜂窝状多孔膜[J]. 化学学报，2012,1(70): 45-50
[5] Li Xiaoyan, Zhao Qiaoling, Xu Tingting, et al. Highly ordered microporous polystyrene-b-poly (acrylic acid) films: Study on the influencing factors in their fabrication via a static breath-figure method[J]. European Polymer Journal, 2014, 50: 135-141.
[6] Fukuhira Y, Kitazono E, Hayashi T, et al. Biodegradable honeycomb-patterned film composed of poly (lactic acid) and dioleoylphosphatidylethanolamine[J]. Biomaterials, 2006, 27(9): 1797-1802.
[7] 孙巍. 基于水滴模板法构建微纳复合功能界面的研究[D]. 浙江大学, 2010
[8] 刘瑞来, 韩静, 陈秀娟, 等. 聚乳酸蜂窝状多孔膜的形成与控制[J]. 高分子学报, 2012 (3): 291-298.
[9] 孙巍, 沈利燕, 王家鸣, 等. 基于粒子辅助水滴模板法制备仿生复眼结构的研究[J]. 高分子学报, 2012 (10): 1151-1156.
[10] 王莹. 茶多酚的抗氧化和抑菌活性及其增效剂[J]. 生物学杂志, 2007, 24(5): 54-56.
[11] Navarro-Martínez M D, García-Cánovas F, Rodríguez-López J N. Tea polyphenol epigallocatechin-3-gallate inhibits ergosterol synthesis by disturbing folic acid metabolism in Candida albicans[J]. Journal of Antimicrobial Chemotherapy, 2006, 57(6): 1083-1092.
[12] 王文娟, 孙京新, 罗欣, 等. 茶多酚对肉源腐败菌和致病菌的抑制效果[J]. 食品科技, 2010 (2): 102-105.
[13] Davis K A, Matyjaszewski K. Atom transfer radical polymerization of tert-butyl acrylate and preparation of block copolymers[J]. Macromolecules, 2000, 33(11): 4039-4047.

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