膜科学与技术

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Surface modification using plasma-induced vapor-phase grafting of vinyl monomers onto polyethylene film

Authors： XIE Linkun, DU Guanben, DAI Qinling, CHAI Xijuan

Units： Yunnan Provincial Key Laboratory of Wood Adhesives and Glued Products, Southwest Forestry University, Kunming 650224, China

KeyWords： plasma; low density polyethylene film; vinyl monomer; vapor-phase grafting

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2015,35(6):28-32

Abstract：

The low density polyethylene (LDPE) film surface was activated with oxygen plasma and induced vapor-phase grafting of vinyl monomers, which were acrylic acid (AA) and methacrylic acid (MAA) respectively. The film surface properties of before and after modification were characterized by static water contact angle, bond performance, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy(SEM ). The results showed that the water contact angle decreased and the peel strength increased with the increase of the time for vapor-phase grafting AA or MAA onto the LDPE film surface. The film surface formed some containing oxygen functional groups, such as C-O, C=O/O-C-O and O=C-O. Furthermore, the modified LDPE film surface appeared some granular substance in variety of size.

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[1] Fombuena V, García-Sanoguera D, Sánchez-Nácher L, et al. Optimization of atmospheric plasma treatment of LDPE films: influence on adhesive properties and ageing behavior[J]. J Adhes Sci Technol, 2014, 28(1): 97-113.
[2] 任煜，邱夷平. 低温等离子体对高聚物材料表面改性处理时效性的研究进展[J].材料导报，2007，21（1）：56-59.
[3] Wavhal D S, Fisher E R. Hydrophilic modification of polyethersulfone membranes by low temperature plasma-induced graft polymerization[J]. J Membr Sci, 2002, 209 (1): 255-269.
[4] Hsieh Y L, Wu M. Residual reactivity for surface grafting of acrylic acid on argon glow-discharged poly(ethylene terephthalate) (PET) films[J]. J Appl Polym Sci, 1991,43 (11): 2067-2082.
[5] Song B, Meng L H , Huang Y D. Influence of plasma treatment time on plasma induced vapor phase grafting modification of PBO fiber surface[J]. Appl Surf Sci, 2012, 258 (14): 5505-5510.
[6] Gupta B, Hilborn J G, Bisson I, et al. Plasma-induced graft polymerization of acrylic acid onto poly(ethylene terephthalate) films[J]. J Appl Polym Sci, 2001, 81 (12): 2993-3001.
[7] Wirsen A, Sun H, Albertsson A C. Solvent-free vapor-phase photografting of acrylamide onto poly(ethylene terephthalate)[J]. Biomacromolecules, 2005, 6(5) : 2697-2702.
[8] 张丹霞，陈翠仙，李继定，等. 聚丙烯腈超滤膜的等离子体接枝改性（Ⅰ）膜材料的表面结构与性能[J]. 膜科学与技术，2003，23（5）:15-18,23.
[9] 王月然，王振欣，魏俊富，等. 低温等离子体引发聚丙烯薄膜气相接枝丙烯酸[J]. 纺织学报，2011，32（5）：10-15.
[10] 解林坤，李树材. 氨低温等离子体处理低密度聚乙烯薄膜的XPS分析. 塑料
工业，2010，38（10）：74-76.
[11] 解林坤，李树材. 低温O2等离子体对HDPE薄膜的表面改性. 高分子材料科学与工程，2010，26（8）：116-119.
[12] 祝振鑫. 膜材料的亲水性、膜表面对水的湿润性和水接触角的关系[J]. 膜科学与技术，2014，34（2）：1-4.
[13] Yang W T, Ranby B. Bulk surface photografting process and its applications. II. Principal factors affecting surface photografting[J]. J Appl Polym Sci, 1996, 62(3): 545-555.
[14] Luo K Q, Jin J H, Yang S L, et al, Improvement of surface wetting properties of poly(p-phenylene benzoxazole) by incorporation of ionic groups[J], Mater Sci Eng, B, 2006, 132 (1-2): 59-63.
[15] Gancarz I, Pozniak G, Bryjak M, et al. Modification of polysulfone membranes. 2. Plasma grafting and plasma polymerization of acrylic acid[J]. Acta Polym, 1999, 50(9): 317-326.
[16] Kim K S, Ryu C M, Park C S, et al. Investigation of crystallinity effects on the surface of oxygen plasma treated low density polyethylene using X-Ray photoelectron spectroscopy[J]. Polymer, 2003, 44(20): 6287-6295.
[17] Bongiovanni R, Di Gianni A, Priola A, et al. Surface modification of polyethylene for
improving the adhesion of a highly fluorinated UV-cured coating [J]. Eur Polym J, 2007,
43(9): 87-3794.

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