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Studies on measuring method of Molecular Weight Cut Off for ultrafiltration membrane with mixture of Polyethylene Glycol and Polyethylene Oxide

Authors： YU Xiaoyan，Zhang Chuan，Zhang Xiaohui

Units： National Center of Ocean Standard and Metrology，Tianjin 300112，China

KeyWords： hollow fiber ultrafiltration membrane；Molecular Weight Cut Off；High Performance Size Exclusion Chromatography；retention rate；Polyethylene Glycol

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2016,36(4):84-90

Abstract：

The mixture retention solutionwith Polyethylene Glycol (PEG) and Polyethylene Oxide(PEO), the relative molecular mass range from 2000 to 230000, is prepared to measure the Molecular Weight Cut Off (MWCO) for ultrafiltration membrane by High Performance Size Exclusion Chromatography (HPSEC) in reference operating conditions. The relative error of the result of the MWCO among the three parallel testing by single sample is 5.1%～5.6%. The reference operating conditions are: the temperature is (25±1)℃,the trans-membrane pressure (TMP) is (100±5)kPa, theReynolds numbers (Re) of the testing system is controlled to be 1600～1800,the cross-flow velocity is controlled to be 1.4m/s ~2.3 m/s in operation，the recovery rate is controlled to be smaller than 5%,20~30 fibers with170~180mm length in one standard membrane module package；the membrane inthe standard membrane module need to be back washed after each testing with TMP in 150kPa by 15min or more ,the standard of the module could be measured again is the pure water fluxes of the membrane recovered tolarger than the 70% of its initial pure water fluxes.

Funds：

国家海洋公益性行业科研专项项目（201105025）

AuthorIntro：

第一作者简介：于小焱（1982-），男，山东威海市人，硕士，工程师，从事分离膜性能检测工作。：Email:yuxiaoyan@ncosm.gov.cn，

Reference：

[1] Rohani M M, Zydney A L，Role of electrostatic interactions during protein ultrafiltration [J].Adv. Colloid Interface Sci, 2010, 160:40–48.
[2]Sakai K, Determination of pore-size and pore-size distribution. 2. Dialysis membranes [J].J Membr Sci, 1994, 96:91–130.
[3] Higuchi A, Tamai M, Ko Y A, et al. Polymeric membranes for chiral separation of pharmaceuticals and chemicals [J].Polymer Reviews,2010,50:113–143.
[4] Arkhangelsky E, Lerch A, Uhl W, et al. Organic fouling and floc transport in capillaries [J].Sep Purif Technol,2011, 80:482–489.
[5]祝振鑫.关于推荐使用“切割分子量”一词的建议[J].膜科学与技术,2006,26(2):82-983.
[6] 中国国家标准化管理委员会.GB/T 20103-2006,膜分离技术术语[S].北京：中国标准出版社,2006.
[7] Nobrega R, Balmann H D, Aimar P, et al. Transfer of dextran through ultrafiltration membranes: a study of rejection data analysed by gel permeation chromatography [J].J Membr Sci, 1989, 45:17-36.
[8] 董声华，郑领英.凝胶色谱法表征我国几种有代表性超滤膜的截留率——分子量曲线[J].水处理技术;1991, 17:268-271.
[9] Tam C M, Tremblay A Y. Membrane pore characterization-comparison between single and multicomponent solute probe techniques [J].J Membr Sci, 1991, 57: 271-287.
[10] 田燕，董声华，林一铮.中空纤维超滤膜截留率测定规范化方法的研讨[J].水处理技术.1994.20(4):192-196.
[11] 祝振鑫，吴立明，胡晓珺.用鸡蛋清中的卵清蛋白测定常用超滤膜的切割分子量[J].膜科学与技术.1999.19(5):44-50.
[12] 戴海平,张惠新,梁福海,等. 用葡聚糖测定超滤膜切割分子量的简易方法[J].膜科学与技术,2005,25( 4):63-65.
[13] Platt S,Mauramo M, Butylina S, et al. Retention of pegs in cross-flow ultrafiltration through membranes[J].Desalination.2002, 149:417–422.
[14] 罗鸣,尚闽,郑祥.蛋白截留法评价超滤膜分离性能研究[J].膜科学与技术,2014,34(6):56-61
[15] 鄢忠森,瞿芳术,梁恒等.超滤膜污染以及膜前预处理技术研究进展[J] .膜科学与技术,2015,35(4):44-50
[16] Schlichter B, Mavrov V, Chmiel H. Comparative characterization of different commercial UF membranes for drinking water production[J]. J Water SRT, 2000, 49(6):321–328.
[17] Brown P, Assessing the molecular weight cut-off value of UF membranes [J].Membr Technol, 1995, 61:7–9.
[18] Christel Causserand, Gwenaelle Pierre, Sophie Rapenne, et al.Characterization of ultrafiltration membranes by tracer's retention: Comparison of methods sensitivity and reproducibility [J]. Desalination, 2010, 250: 767–772
[19] French Standard NF X 45-103, AFNOR Association Française de Normalisation, 1997.
[20]G. Jonsson, Charmme project, 2001.
[21] Pradanos P, Arribas J I, Hemandez A, Hydraulic Permeability, Mass Transfer, and Retention of PEGs in Cross-Flow Ultrafiltration Through a Symmetric Microporous Membrane[J].SepSci Tech, 1992, 27:2121- 2142.
[22]Schock G, Miquel A, Birkenberger R, Characterization of ultrafiltration membranes: cut-off determination by gel permeation chromatography [J].J Membr Sci,1989, 41:55-67.
[23]于小焱,张晓慧,庞永超.凝胶排阻色谱法测定中空纤维超滤膜组件对聚乙二醇的截留率[J].化学分析计量,2015,24(1):28-32.

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