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Study on the preparation method of novel polyether sulfone/sulfonated polyether sulfone blended ultrafiltration membrane

Authors： ZHAO Jinli，WANG Jianyou*，ZHANG Yuzhong

Units： 1.College of Environmental Science and Engineering, Nankai University,Tianjin, 300350； 2. School of Material Science and Engineering,Tianjin Polytechnic University,Tianjin 300387

KeyWords： SPES solution; blended membrane; coagulation bath temperature; evaporation time; additive

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2018,38(4):33-42

Abstract：

Based on self-made sulfonated polyethersulfone（SPES）solution, casting solution was prepared by blending SPES solution with polyethersulfone （PES）directly. Novel PES/SPES blended ultrafiltration membranes were prepared in order to simplify the preparation process in this paper. Effect of content of PES and SPES, coagulation bath temperature, evaporation time and additive on morphology and performance of blended membranes were investigated. The result showed that reduced viscosity increased with decrease of temperature of casting solution and increase of content of acid in casting solution. All the blended membranes presented asymmetric morphology consisting of dense top layer and porous sub-layer. With increase of content of PES and SPES, the pure water flux of blended membrane decreased and the rejection rate for PEG6000 increased. With increase of coagulation bath temperature and evaporation time, the pure water flux of blended membrane increased and the rejection rate decreased. The addition of polyethylene glycol 200（PEG200）and acetone were helpful to improve the overall performance of the blended membrane. With addition of 2%wt, the pure water fluxes were more than 460L/m2?h and rejection rates of PEG6000 were more than 85%.

Funds：

国家重点研发计划（No.2016YFC0400707-2, No.2017YFC0404003）

AuthorIntro：

第一作者简介：赵津礼（1987-），男，山东临沂市人，博士研究生，主要从事膜分离、电驱动膜方向，E-mail：zhaojinli-1016@163.com；通讯作者，E-mail：wangjy72@nankai.edu.cn

Reference：

[1] 孙中华, 赵高杰, 陈夫山，等.Ｎ,Ｎ-二甲基乙酰胺/氯化锂体系下醋酸纤维素/聚醚砜共混膜的制备与表[J]. 膜科学与技术, 2017, 37（6）：46-52.
[2] Wang W, Zhu L, Shan B, et al. Preparation and characterization of SLS-CNT/PES ultrafiltration membrane with antifouling and antibacterial properties [J]. J. Membr. Sci., 2018, 54：459-469.
[3] Gholamia F, Zinadinia S, Zinatizadeha A，et al. TMU-5 metal-organic frameworks（MOFs）as a novel nanofiller for flux increment and fouling mitigation in PES ultrafiltration membrane [J]. J. Membr. Sci., 2018, 194：272-280.
[4] Liu Z, Mi Z, Chen C, et al. Preparation of hydrophilic and antifouling polysulfone ultrafiltration membrane derived from phenolphthalin by copolymerization method [J]. Appl. Surf. Sci., 2017, 401：69-78.
[5] 芦文慧，黄肖容.聚砜超滤膜亲水改性的研究进展[J]，现代化工，2017，37（8）：23-27.
[6] Xu C, Liu X, Xie B，et al. Preparation of PES ultrafiltration membranes with natural aminoacids based zwitterionic antifouling surfaces [J]. Appl. Surf. Sci., 2016, 385：130-138.
[7] Chen X, Tang B, Luo J，et al. Towards high-performance polysulfone membrane: The role of PSF-b-PEG copolymer additive [J]. Microporous Mesoporous Mater., 2017, 241：355-365.
[8] Chen Y, Wei M, Wang Y，et al. Upgrading polysulfone ultrafiltration membranes by blending with amphiphilic blockcopolymers: Beyond surface segregation [J]. J. Membr. Sci., 2016, 505：53-60.
[9] 任彦荣, 李志强. 磺化聚醚砜的研究及其应用进展[J]. 化学推进剂与高分子材料, 2005, 3（2）：23-27.
[10] 刘海菊, 皇甫风云，白云东等. 磺化聚醚砜的制备与表征[J]. 天津工业大学学报, 2010, 29（4）：14-17.
[11] 赵津礼, 张玉忠，林立刚等. 新型聚醚砜/磺化聚醚砜共混超滤膜的制备及性能[J]. 天津工业大学学报, 2013, 32（3）：1-7.
[12] Ismail. A, Hassan. A. Effect of additive contents on the performances and structural properties of asymmetric polyethersulfone（PES）nanofiltration membranes [J]. Sep. Purif. Technol., 2007 , 55 (1): 98-109.
[13] 俞三传, 高从堦. 浸入沉淀相转化法制膜[J]. 膜科学与技术，2000, 20（2）：36-41.
[14] 钟金成, 何颖，秦舒浩，等. 聚醚砜/磺化聚砜共混纳滤膜的制备及性能[J]. 膜科学与技术, 2016, 36（2）：1-6.
[15] 赵翔，鲁建江，赵颂，等. 添加剂对聚醚砜超滤膜性能影响研究[J]. 膜科学与技术, 2016, 36（3）：33-40.
[16] 朱思君, 孙俊芬，赵有中，等. 凝固条件对聚醚砜膜结构和性能的影响[J]. 东华大学学报，2006, 32（6）： 128-133.
[17] 朱士龙, 张俊生，李勇，等. 制膜条件对聚偏氟乙烯/酚酞型聚醚砜共混膜性质的影响[J]. 吉首大学学报, 2010, 31（4）：98-102.
[18] 左丹英, 徐又一, 刘洪涛. 凝固浴温度对PVDF铸膜液相分离过程和膜结构的影响[J]. 功能高分子学报，2008，2008 , 21（4）：380-384.
[19] 孙俊芬, 陈景草, 赵娟. 预蒸发时间对复合膜结构与性能的影响[J]. 成都纺织高等专科学校学报，2016，33（2）：6-10.

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