Sodium alginate modified magnetic nanoparticle draw solution and its forward osmosis performance |
Authors: CHI Rujing, WANG Zhichao, ZHANG Mengbo, ZHU Kaihao, CAO Dongyun, DU Chunhui |
Units: School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310018, China |
KeyWords: magnetic particles; sodium alginate; forward osmosis; draw solution |
ClassificationCode:TQ028.8 |
year,volume(issue):pagination: 2020,40(4):72-79 |
Abstract: |
Fe3O4-SA magnetic nanoparticles with good dispersibility and magnetic response were prepared by emulsification blending precipitation method. The structure and performance of the magnetic nanoparticles were characterized by the infrared spectroscopy, transmission electron microscopy, hysteresis loops and thermogravimetric analysis, and at the same time the forward osmosis performance of FO using Fe3O4-SA magnetic nanoparticles as the draw solution was also investigated. The results showed that SA was coated successfully on the surface of Fe3O4 particles and the nanoparticle size is about 20nm. The osmotic pressure of 80 g/L Fe3O4-SA aqueous solution reached 1270 mOSM/L. When 8 wt% Fe3O4-SA aqueous solution was used as the draw solution for the FO process, the permeation flux could reach 2.04 L/(m2·h). Fe3O4-SA aqueous solution had low reverse solute flux, its value was 0.04 g/(m2·h) which was much lower than those of NaCl and SA when the concentrations were 80g/L. These phenomena suggested that this magnetic nanoparticle had good forward osmosis separation performance. |
Funds: |
国家级大学生创新创业训练计划项目(项目编号:GJ201823002) |
AuthorIntro: |
第一作者简介:池如镜(1998-),女,浙江温州人,在读本科生,环境工程专业,E-mail: 909547405@qq.com 通讯作者,E-mail: chunhuidu@zjgsu.edu.cn |
Reference: |
[1] 尉凤珍. 正渗透技术研究综述及应用展望[J]. 工业水处理, 2017, 037(010):16-18,47. [2] Safari J, Zarnegar Z. Magnetic nanoparticle supported ionic liquid as novel and effective heterogeneous catalyst for synthesis of substituted imidazoles under ultrasonic irradiation[J]. Cheminform, 2013, 144(9):1389-1396. [3] 李青连, 韩丽娜, 常丽萍,等. 磁性纳米材料在污水中重金属离子处理中的究进展[J]. 现代化工, 2016, 36(9):28-31. [4] Bai H, Liu Z, Sun D D, Highly water soluble and recovered dextran coated Fe3O4 magnetic nanoparticles for brackish water desalination[J]. Sep. Purif. Technol. 2011, 81:392-399. [5] Ge Q, Su J, Chung T S, Hydrophilic superparamagnetic nanoparticles: synthesis, characterization, and performance in forward osmosis processes[J]. Ind. Eng. Chem. Res. 2011, 50:382-388. [6] Na Y, Yang S, Lee S. Evaluation of citrate-coated magnetic nanoparticles as draw solute for forward osmosis[J]. Desalination, 2014, 347:34–42. [7] Ma B, Wang S, Cao S, et al. Biological nitrogen removal from sewage via anammox: recent advances[J]. Bioresource Technology, 2016, 200:981-990. [8] Fu K M, Li H, Zhou H T, et al. Optimization of the nitrogen removal performance on the CANON process in a biofilm reactor: from FBBR to MBBR[J]. Environmental Science, 2018, 39(5):2256-2264. [9] 王清, 朱世侦, 杨文娟,等. 磁性四氧化三铁海藻酸钠复合物吸附剂去除水溶液中的Cr(VI). 西华师范大学学报(自然科学版), 2017, 38(3):282-286. [10] 孙俊芝, 王静霞, 倪茂君,等. 改性海藻酸钠微球对Pb2+吸附性能的研究[J]. 环境科学与技术, 2019, 42(07):100-104+110. [11] 颜秋平, 李富荣, 汤顺清,等. 新型磁性海藻酸钠复合微球的制备与表征. 材料科学与工程学报, 2005, 23(5):587-589. [12] 刘继伟. 功能性海澡酸复合微球的制备研究[D]. 2010. [13] 盘茂东. 反相乳液-凝胶法制备海藻酸钙凝胶微球及载药试验研究[D]. 2009. [14] Zarnegar Z, Safari J. Magnetic nanoparticles supported imidazolium-based ionic liquids as nanocatalyst in microwave-mediated solvent-free Biginelli reaction[J]. Journal of Nanoparticle Research, 2014, 16(8):2509. [15] Cao K T, Jiang Z Y, Zhao J, et al. Enhanced water permeation through sodium alginate membranes by incorporating graphene oxides[J]. Journal of Membrane Science, 2014, 469. |
Service: |
【Download】【Collect】 |
《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com
京公网安备11011302000819号