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Preparation of High Performance Mullite Ceramic Membrane Support Prepared at Medium Temperature

Authors： ZHANG Lijian,WANG Yongqing,HU Xuebing,ZHANG Xiaozhen, CHANG Qibing, XU Zeyue

Units： 1.University Key laboratory of Inorganic Membrane in Jiang xi Province,Jingdezhen Ceramic Institute, Jingdezhen 333001,China;2. ResearchInstitute of Jiangsu Ceramic Co.Ltd.

KeyWords： capacitor mullite powder；coal fly ash；support

ClassificationCode：TQ174

year,volume(issue):pagination： 2020,40(4):107-112

Abstract：

The mullite ceramic support was prepared by a pressing method using capacitor mullite powder as a starting material, coal fly ash as sintering additive and activated.The effectsof sintering temperature on phase composition, microstructure and chemical resistance of the samples were systematically studied. The results show that the best support with mullite of 85 wt% , coal fly ash of 15 wt% sintered at 1350℃has a porosity of 37.15%, a mean pore size of 2.31 μm,a flexural strength of 59.85 MPa, a water flux of 14.5 m3·m-2 ·h-1 ·MPa-1. The flexural strength decreases from 59.85 to 55.65 MPa and 47.72 MPa when the support immerses in 15% HCl and 15% NaOH for 40 h respectively. The support hasgood chemical corrosion resistance.

Funds：

国家自然科学基金（51662019），江西省自然科学基金重点项目（20161ACB21008 20143ACB21022）江西省5511优势科技创新团队项目（20165BCB19014）

AuthorIntro：

第一作者简介：张利剑（1995-02-01），男，河北张家口人，硕士研究生，主要研究方向为陶瓷膜及其应用，E-mail:390333373@qq.com 通讯作者：汪永清，E-mail:wyq8248@126.com 通讯作者：胡学兵，E-mail:xuebinghu2010@gmail.com

Reference：

[1]肖汉宁,熊敏,郭文明,等.多孔陶瓷膜及其在液固和气固分离中的应用[J].陶瓷学报，2017, 38(6), 791-798.
[2]张利剑,汪永清,胡学兵,等.中温制备高性能刚玉-莫来石质陶瓷膜支撑体[J].膜科学与技术，2019,39(5) :52-57.
[3]胡学兵,于云,汪永清.氧化石墨烯对不同孔径Al2O3微滤膜纯水渗透通量的作用[J].膜科学与技术，2016,36(6): 32-35.
[4]ChenG Q, Wang Y, S Cerneaux, et al. Preparation ofmicrofiltration membrane supports using coarse alumina grains coatedby nano TiO2 as raw materials[J]. J Eur Ceram Soc, 2014,34(16):4355–4361.
[5] Hua KH, Xi XA, Xu LF, et al. Effects of AlF3 and MoO3 on properties of mullite whisker reinforced porous ceramics fabricated from construction waste[J].Ceram Int, 2016,42: 4819-4826.
[6] Li CX, Zhou Y, Tian YM. Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash[J]. Ceram Int, 2019, 45: 5613-5616.
[7]Luo Y, Ma SH, Zhao ZQ, et al.Preparation and characterization of whisker-reinforced ceramics from coal fly ash[J]. Ceram Int, 2017, 43:1-11.
[8]P Nath, P K Sarker, W K Biswas.Effect of fly ash on the service life, carbon footprint and embodied energy of high strength concrete in the marine environment[J].Energy Build,2018, 158: 1694-1702.
[9] Zhou MK, Ge XX, Wang HD, et al. Effect of the CaO content and decomposition of calcium-containing minerals on properties and microstructure of ceramic foams from fly ash[J].Ceram Int, 2017, 43: 9451-9457.
[10] Li CX, Zhou Y, Tian YM, et al.Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash[J]. Ceram Int, 2019, 45: 5613-5616.
[11] L Winnubst, Zhu L, Dong Y, et al.Waste-to-resource preparation of a porous ceramic membrane support featuring elongated mullite whiskers with enhanced porosity and permeance[J].J Eur Ceram Soc, 2015, 35: 711–721.
[12]Li S, Du H, Guo A, et al. Preparation of self-reinforcement of porous mullite ceramics through in situ synthesis of mullite whisker in flyash body[J].Ceram Int, 2012, 38: 1027–1032.
[13] Dong YC, Zhou J E, Lin B, et al. Reaction-sintered porous mineral-based mullite ceramic membrane supports made from recycled materials[J].JHazardMater, 2009, 172:180-186.
[14]Zhu JB, Yan H.Microstructure and properties of mullite-based porous ceramics produced from coal fly ash with added Al2O3[J].Int J Min Met Mater, 2017, 24(3): 309-315.
[15]ZongYB, Wan QL, CangDQ. Preparation of anorthite-based porous ceramics using high-alumina fly ash microbeads and steel slag[J].Ceram Int,2019, 45: 22445-22451.
[16] Li S, Du H, Guo A, et al. Preparation of self-reinforcement of porousmullite ceramics through in situ synthesis of mullite whisker in flyash body[J].CeramInt,2012, 38:1027–1032.
[17] Y. Dong, S. Hampshire, B. Lin, et al. Recycling of fly ash for preparing porous mullite membrane supports with titania addition[J]. J Hazard Mater,2010, 180: 173–180.
[18] Chen M, Zhu L, Dong Y, et al. Waste-to-resource strategy to fabricate highly porous whisker-structured mullite ceramic membrane for simulated oil-in-water emulsion wastewater treatment[J].ACS Sustain Chem Eng, 2016, 4: 2098–2106.
[19] Fu M, Liu J, Dong X F, et al. Waste recycling of coal fly ash for design of highly porous whisker structured mullite ceramic membrane[J]. J Eur Ceram Soc,2019, 39: 5320-5331.
[20] Wei ZL, Hou J, Zhu ZW.High-aluminum fly ash recycling for fabrication of cost-effective ceramic membrane supports[J]. J Alloys Comp,2016, 683: 474-480.
[21] Zhang JH, Wu HD, Zhang SX.Preparation of mullite whiskers and their enhancement effect on ceramic matrix composites[J].JTech-Mater Sci,2013, 28: 471-475.
[22] LMontanaro, JM Tulliani, CPerrot, et al. Sintering of industrial mullites[J].J Eur Ceram Soc,1997, 11: 1715-1723.
[23] 王峰，贺智勇，张启富等.低温制备高纯氧化铝陶瓷支撑体[J] .硅酸盐学报，2017,45(6):817-822.

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