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Research progress of polymer of intrinsic microporosity for gas separation membrane

Authors： LI Kaihua,a ZHU Zhiyang,b CHEN Bowen,a LI Jianxin,b MA Xiaohuab

Units： a State Key Laboratory of Membrane Separation and Membrane Process, College of Textile Science and Engineering，Tiangong University, Tianjin, China, 300387 a State Key Laboratory of Membrane Separation and Membrane Process, College of Material Science and Engineering, Tiangong University, Tianjin, China, 300387

KeyWords： Polymer of intrinsic microporosity; BET surface area; Gas separation; Membrane; Ladder polymer; Polyimide

ClassificationCode：TQ31

year,volume(issue):pagination： 2020,40(5):118-128

Abstract：

Membrane-based gas separation had a variety of industrial applications such as chemical engineering, medical, environment, energy and so on. Polymer membrane is one of the most important parts in gas separation membranes. Recently, the emerging of polymer of intrinsic microporosity (PIM), a special polymer composed of “kinked” structure unit combined by some very rigid connectors. The site-of-contortions prevent the polymer main chain from close packing in the condensed phase that resulting in large volume of micropore (diameter < 2 nm). Besides, PIMs also demonstrate good mechanical strength, excellent solubility, thermal stabilities, etc., that are attracting great attention in both industrial and academic research. PIMs combined the advantages of easy processibility for polymer membranes and high permeability and selectivity of inorganic molecular sieve membranes, which demonstrated great potential in gas and liquid molecular separations. This review summarized the classification, synthesis and gas separation properties of intrinsically microporous polymers in gas field, and the perspective of this material.

Funds：

国家自然科学基金（51703036），教育部创新团队项目（IRT17R80），天津市科技计划项目（18PTZWHZ00210，19PTSYJC0030），煤转化国家重点实验室开放基金（J19-20 -907）。

AuthorIntro：

李凯华（1991-），男，河北唐山人，博士，主要从事气体分离膜研究。E-mail：likh_199109@163.com；通讯作者，马小华，E-mail：xhuama@126.com；xhuama@tiangong.edu.cn程博闻，E-mail:bowen15@tjpu.edu.cn)

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