Preparation of Carbon Nanotube/Bismaleimide Composite Film by In-situ Prepreg Process |
Authors: LIN Jia Hao, ZHAN Hang, WANG Jian Nong |
Units: School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237 |
KeyWords: Carbon nanotube; Resin; In-situ prepreg; Composite film; Mechanical property |
ClassificationCode:TB332 |
year,volume(issue):pagination: 2021,41(2):25-32 |
Abstract: |
Carbon nanotube (CNT) shows advantages such as high strength, high modulus and light weight, which can be potentially applied in the aerospace, electronics and other fields. Resin has the characteristics of mature technology, large output and low cost. Therefore, it is necessary to combine the two to prepare composites. In this paper, an in-situ prepreg process was used to prepare CNT/bismaleimide (BMI) composite films. The CNT assembly was grown by the high-temperature catalytic spray pyrolysis method and combined with a resin solution in situ on the winding drum to obtain the prepreg composite. Subsequent operations such as multi-layer stacking, solvent removal, and hot-press curing were performed to prepare a CNT/BMI composite film. The influences of the orientation and mass fraction of CNTs on the mechanical properties of the composite film were studied. Characterization was carried out using polarized Raman spectroscopy, SEM, and TGA. Finally, when the mass fraction of CNTs was 59.8%, the composite film achieved a tensile strength of 1.02 GPa, elongation at break of 8.59%, and toughness of 48.9 J/cm3. |
Funds: |
国家自然科学基金(U1362104) |
AuthorIntro: |
林家豪(1995-),男,江苏无锡人,硕士研究生,研究方向:碳纳米管材料,E-mail:linjiahao@mail.ecust.edu.cn |
Reference: |
[1] Yakobson B I, Brabec C J, Bernholc J. Nanomechanics of carbon tubes: Instabilities beyond linear response[J]. Phys Rev Lett, 1996, 76(14):2511-2514. [2] Zhou X, Zhou J J, Ou-Yang Z C. Strain energy and Young’s modulus of single-wall carbon nanotubes calculated from electronic energy-band theory[J]. Phys Rev B: Condens Matter, 2000, 62(20):13692-13696. [3] Bai Y, Zhang R, Ye X, et al. Carbon nanotube bundles with tensile strength over 80 GPa[J]. Nature Nanotech, 2018, 13(7):589-595. [4] Yu M, Files B S, Arepalli S, et al. Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties[J]. Phys Rev Lett, 2014, 84(3-4):5552-5555. [5] Salvetat J P, Briggs G A, Bonard J M, et al. Elastic and shear moduli of single-walled carbon nanotube ropes[J]. Phys Rev Lett, 1992, 82(5):944-947. [6] Jia X L, Zhang Q, Huang J Q, et al. The direct dispersion of granular agglomerated carbon nanotubes in bismaleimide by high pressure homogenization for the production of strong composites[J]. Powder Technol, 2012, 217:477-481. [7] 高翔宇, 贺高红, 梁健. 多壁碳纳米管(MWNT)/聚丙烯腈(PAN)共混复合膜的制备及性能研究[J]. 膜科学与技术, 2013, 33(3):17-22. [8] Chen Z, Dai X J, Magniez K, et al. Improving the mechanical properties of epoxy using multiwalled carbon nanotubes functionalized by a novel plasma treatment[J]. Composites Part A, 2013, 45:145-152. [9] Li P, Li T, Yan H. Mechanical, tribological and heat resistant properties of fluorinated multi-walled carbon nanotube/bismaleimide/cyanate resin nanocomposites[J]. J Mater Sci Technol, 2017, 33(10):1182-1186. [10] Cheng Y, Xia B, Fang C, et al. Structure, mechanical and thermal properties of BMI/E-44/CNTs ternary composites via amination method[J]. J Mater Sci Technol, 2017, 33(10):1187-1194. [11] Di J, Fang S, Moura F A, et al. Strong, twist-stable carbon nanotube yarns and muscles by tension annealing at extreme temperatures[J]. Adv Mater, 2016, 28(31):6598-6605. [12] Wu T, Wang J N. Carbon nanotube springs with high tensile strength and energy density[J]. RSC Adv, 2016, 6(44):38187-38191. [13] Liu T, Zhang M, Wang Y L, et al. Engineering the surface/interface of horizontally oriented carbon nanotube macrofilm for foldable lithium-ion battery withstanding variable weather[J]. Adv Funct Mater, 2018, 8(30):1802349. [14] Wang S, Downes R, Young C, et al. Carbon fiber/carbon nanotube buckypaper interply hybrid composites: Manufacturing process and tensile properties[J]. Adv Eng Mater, 2015, 17(10):1442-1453. [15] Zou J, Liu J, Karakoti A, et al. Ultralight multiwalled carbon nanotube aerogel[J]. ACS Nano, 2010, 4(12):7293-7302. [16] Zeng Z, Gui X, Lin Z, et al. Carbon nanotube sponge-array tandem composites with extended energy absorption range[J]. Adv Mater, 2013, 25(8):1185-1191. [17] Mecklenburg M, Mizushima D, Ohtake N, et al. On the manufacturing and electrical and mechanical properties of ultra-high wt.% fraction aligned MWCNT and randomly oriented CNT epoxy composites[J]. Carbon, 2015, 91:275-290. [18] Yao X, Falzon B G, Hawkins S C, et al. Aligned carbon nanotube webs embedded in a composite laminate: A route towards a highly tunable electro-thermal system[J]. Carbon, 2018, 129:486-494. [19] 吕慧, 陈爱平, 张哲,等. 原位CVD法生长碳纳米管组装CNT/TiO2多孔复合膜[J]. 膜科学与技术, 2014, 34(3):15-22. [20] Chen H, Chen Y, Zhan H, et al. Preparation of carbon nanotube/epoxy composite films with high tensile strength and electrical conductivity by impregnation under pressure[J]. Front Mater Sci, 2019, 13(2):165-173. [21] Kim J W, Sauti G, Siochi E J, et al. Toward high performance thermoset/carbon nanotube sheet nanocomposites via resistive heating assisted infiltration and cure[J]. ACS Appl Mater Inter, 2014, 6(21):18832-18843. [22] Downes R D, Hao A, Park J G, et al. Geometrically constrained self-assembly and crystal packing of flattened and aligned carbon nanotubes[J]. Carbon, 2015, 93:953-966. [23] Nam T H, Goto K, Kamei T, et al. Improved mechanical properties of aligned multi-walled carbon nanotube/thermoplastic polyimide composites by hot stretching[J]. J Compos Mater, 2019, 53(9):1241-1253. [24] Jiang Q, Wang X, Zhu Y, et al. Mechanical, electrical and thermal properties of aligned carbon nanotube/polyimide composites[J]. Composites Part B, 2014, 56:408-412. [25] Li M, Wang Z, Liu Q, et al. Carbon nanotube film/epoxy composites with high strength and toughness[J]. Polym Compos, 2017, 38:588-596. [26] Mikhalchan A, Gspann T, Windle A. Aligned carbon nanotube-epoxy composites: The effect of nanotube organization on strength, stiffness, and toughness[J]. J Mater Sci, 2016, 51(22):10005-10025. [27] Dong L, Park J G, Leonhardt B E, et al. Continuous synthesis of double-walled carbon nanotubes with water-assisted floating catalyst chemical vapor deposition[J]. Nanomaterials, 2020, 10(2):365. [28] Bradford P, Wang X, Zhao H, et al. A novel approach to fabricate high volume fraction, aligned, long carbon nanotube composites[J]. Compos Sci Technol, 2010, 70(13):1980-1985. [29] Qiu L, Guo P, Yang X, et al. Electro curing of oriented bismaleimide between aligned carbon nanotubes for high mechanical and thermal performances[J]. Carbon, 2019, 145:650-657. [30] Nam T H, Goto K, Yamaguchi Y, et al. Improving mechanical properties of high volume fraction aligned multi-walled carbon nanotube/epoxy composites by stretching and pressing[J]. Composites Part B, 2016, 85:15-23. [31] Cheng Q F, Wang J P, Wen J J, et al. Carbon nanotube/epoxy composites fabricated by resin transfer molding[J]. Carbon, 2010, 48(1):260-266. [32] Nam T H, Goto K, Nakayama H, et al. Effects of stretching on mechanical properties of aligned multi-walled carbon nanotube/epoxy composites[J]. Composites Part A, 2014, 64:194-202. |
Service: |
【Download】【Collect】 |
《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com
京公网安备11011302000819号