膜科学与技术

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A study on the modified hydrotalcite composite nanofiltration membrane for dye/salt separation

Authors： TIAN Chen, ZHU Liping, FENG Xiaoquan, SHAN Meixia, ZHANG Yatao

Units： 1School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001 China; 2 Zhengzhou Key Laboratory of Advanced Separation Technology, Zhengzhou 450001 China

KeyWords： LDH, LDH-PSS, Composite nanofiltration membrane, Dye rejection, Desalination

ClassificationCode：TQ051.893

year,volume(issue):pagination： 2021,41(2):33-40

Abstract：

The hydrotalcite (LDH) was prepared by low saturated coprecipitation. Sodium p-styrene sulfonate (PSS) was then grafted onto the surface of hydrotalcite lamella by reverse atomic transfer radical polymerization (RATRP) to prepare LDH-PSS. Finally, LDH/LDH-PSS composite membranes were prepared by self-assembly method. The separation performance of dye and divalent salt of the prepared composite membrane was studied and the effect of the addition amount and layers of LDH/LDH-PSS on the membrane separation performance was further investigated. The rejection of monovalent salt, divalent salt and reactive black 5 and the pure water permeability of the composite membrane were analyzed to study the separation performance of the composite membrane. The results show that the pure water permeability of the composite membrane decreases as the number of hydrotalcite and modified hydrotalcite layers increases, the pure water flux of the membrane is 14.5 L/(m2·h·bar), the rejection rate of the membrane to reactive dye reaches over 96.7%, and the rejection of divalent inorganic salt magnesium sulfate is below 20%.

Funds：

国家自然科学基金项目（U1704139）

AuthorIntro：

田陈(1994-03-14)，男，河南商丘人，硕士研究生，从事膜分离技术的研究。 E-mail：1690899743@qq.com。

Reference：

[1] 董应超, 马丽宁, 等. 碳纳米管复合膜的制备及水处理应用研究进展[J]. 膜科学与技术, 2016, 36(6): 1-10.
[2] Bouazizi N, Bargougui R, Thebault P, et al. Development of a novel functional core-shell-shell nanoparticles: From design to anti-bacterial applications[J]. Journal of Colloid and Interface Science, 2018, 513: 726-735.
[3] 徐小颖, 曹兵, 等. PVA/PES复合膜的制备及其渗透汽化脱盐性能研究[J]. 北京化工大学学报: 自然科学版, 2016, 43(5): 39-44.
[4] Ou W, Zhang G, Yuan X, et al. Experimental study on coupling photocatalytic oxidation process and membrane separation for the reuse of dye wastewater[J]. Journal of Water Process Engineering, 2015, 6: 120-128.
[5] Peng Y, Yu Z, Pan Y, et al. Antibacterial photocatalytic self-cleaning poly(vinylidene fluoride) membrane for dye wastewater treatment[J]. Polymers for Advanced Technologies, 2018, 29: 254-262.
[6] Cotillas S, Llanos J, Pablo Cañizares, et al. Removal of procion red MX-5B dye from wastewater by conductive-diamond electrochemical oxidation[J]. Electrochimica Acta, 2018, 263: 1-7.
[7] Li N, Wei D, Sun Q, et al. Fluorescent component and complexation mechanism of extracellular polymeric substances during dye wastewater biotreatment by anaerobic granular sludge[J]. Royal Society Open Science, 2018, 5: 171445-171445.
[8] 严海琳, 汤雯雯, 等. 镁盐和亚铁盐处理活性染料废水的实验研究[J]. 南京师大学报(自然科学版), 2010, 33(4): 39-44.
[9] Chen X, Zhao Y, Moutinho J, et al. Recovery of small dye molecules from aqueous solutions using charged ultrafiltration membranes[J]. Journal of Hazardous Materials, 2015, 284: 72-74.
[10] Yu L, Deng J, Wang H, et al. Improved salts transportation of a positively charged loose nanofiltration membrane by introduction of poly(ionic liquid) functionalized hydrotalcite nanosheets[J]. ACS Sustainable Chemistry & Engineering, 2016, 4: 3292-3304.
[11] Lau W J, Ismail A F. Polymeric nanofiltration membranes for textile dye wastewater treatment: Preparation, performance evaluation, transport modelling, and fouling control — a review[J]. Desalination, 2009, 245: 321-348.
[12] Zhang R, Ji S, Wang N, et al. Coordination-driven in situ self-assembly strategy for the preparation of metal–organic framework hybrid membranes†[J]. Angewandte Chemie, 2014, 53: 9775-9779.
[13] Abels C, Carstensen F, Wessling M. Membrane processes in biorefinery applications[J]. Journal of Membrane Science, 2013, 444: 285-317.
[14] 刘垚, 吕陈美, 朱玲. 沸石分子筛膜合成的新方法[J]. 膜科学与技术, 2020, 40(3): 145-150.
[15] Aydiner C, Mert B K, et al. Novel hybrid treatments of textile wastewater by membrane oxidation reactor: Performance investigations, optimizations and efficiency comparisons[J]. Science of the Total Environment, 2019, 683: 411–426.
[16] Abid M F, Zablouk M, Abidalameer A M, et al. Experimental study of dye removal from industrial wastewater by membrane technologies of reverse osmosis and nanofiltration[J]. Iranian Journal of Environmental Health Science & Engineering, 2012, 9: 17-17.
[17] Paul M, Jons S D. Chemistry and fabrication of polymeric nanofiltration membranes: a review[J]. Polymer, 2016, 103: 417-456.
[18] Zhang Z, Kang G, Yu H, et al. Fabrication of a highly permeable composite nanofiltration membrane via interfacial polymerization by adding a novel acyl chloride monomer with an anhydride group[J]. Journal of Membrane Science, 2019, 570-571: 403-409.
[19] Lin J, Ye W, Zeng H, et al. Fractionation of direct dyes and salts in aqueous solution using loose nanofiltration membranes[J]. Journal of Membrane Science, 2015, 477: 183-193.
[20] Lin J, Tang C Y, Ye W, et al. Unraveling flux behavior of superhydrophilic loose nanofiltration membranes during textile wastewater treatment[J]. Journal of Membrane Science, 2015, 493: 690-702.
[21] Dhar J, Patil S. Self-assembly and catalytic activity of metal nanoparticles immobilized in polymer membrane prepared via layer-by-layer approach[J]. ACS Applied Materials & Interfaces, 2012, 4: 1803-1812.
[22] Zhu C, Liu P, Mathew A P, et al. Self-assembled TEMPO cellulose nanofibers: Graphene oxide-based biohybrids for water purification[J]. ACS Applied Materials & Interfaces, 2017, 9: 21048-21058.
[23] Rives V, Arco M D, Martin C, et al. Intercalation of drugs in layered double hydroxides and their controlled release: A review[J]. Applied Clay Science, 2014, 88: 239-269.
[24] Srivastava V. Functionalized hydrotalcite tethered ruthenium catalyst for carbon sequestration reaction[J]. Catalysis Letters, 2018, 148: 1879-1892.
[25] Pan L, Huang H, Niederberger M, et al. Layered cobalt hydrotalcite as an advanced lithium-ion anode material with high capacity and rate capability[J]. Journal of Materials Chemistry, 2019, 7: 21264-21269.
[26] Velu S, Shah N, Jyothi T M, et al. Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg-Al layered double hydroxides[J]. Microporous and Mesoporous Materials, 1999, 33: 61-75.
[27] Arcanjo G S, Mounteer A H, Bellato C R, et al. Heterogeneous photocatalysis using TiO2 modified with hydrotalcite and iron oxide under UV–visible irradiation for color and toxicity reduction in secondary textile mill effluent[J]. Journal of Environmental Management, 2018, 211: 154-163.
[28] Wu X, Luo B, Chen F, et al. Heterogeneous fenton degradation of azo dye 4BS over Co–Mn–Fe ternary hydrotalcites[J]. Chemical Papers, 2018, 72: 2433-2441.
[29] Gaini L E, Lakraimi M, Sebbar E, et al. Removal of indigo carmine dye from water to Mg-Al-CO3-calcined layered double hydroxides[J]. Journal of Hazardous Materials, 2009, 161: 627-632.
[30] 朱军峰, 拓欢, 朱婷, 等. 含磺酸基和氮氧自由基共聚合物的合成及性能研究[J]. 功能材料, 2020, 3(51): 03096-03101.

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