膜科学与技术

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Fabrication of In(III)-MOF incorporated thin-film composite membrane for forward osmosis and studies on its anti-fouling property

Authors： HAN Xueli, WANG Duo, WANG Meng

Units： College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China

KeyWords： forward osmosis membrane；polyamide composite membrane；In(Ⅲ)-MOF；membrane fouling

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2021,41(2):71-80

Abstract：

Adding Metal-Organic Framework (MOFs) to form polyamide composite membrane is a simple process to improve the performance of forward osmosis membranes greatly. In this paper，a certain amount of the metal salt In(NO3)3·6H2O and tridentate carboxylic acid ligands H3CTTA was dissolved in N, N - dimethyl formamide to get In(Ⅲ)-MOF (BUT - 172) crystal by the solvothermal method；Then，the prepared MOF particles were added to the polyamide active separation layer by interfacial polymerization，and the modified TFC- FO membrane was obtained. In addition，the effects of different concentration of BUT-172 particles on the structure and properties were also studied. The results showed that the incorporation of BUT-172 particles provided additional channels for the diffusion of water molecules，which greatly improved the water flux of the modified TFC-FO membrane. Moreover，when the BUT-172 concentration was 0.04wt%，the modified membrane had a higher water flux and a lower salt water ratio. The study on pollution resistance of humic acid showed that the modified membrane had better pollution resistance and the performance of the polluted membrane can be recovered by simple cleaning.

Funds：

：国家自然科学基金项目（21576249）

AuthorIntro：

韩雪笠（1995-），女，山东滨州人，在读硕士，从事功能膜材料的制备研究，联系电话：0532-66786513

Reference：

[1]方彦彦,田野,王晓琳.正渗透的机理[J].膜科学与技术,2011,31(6):95-100.
[2]McCutcheon J R，McGinnis R L，Elimelech M. A Novel ammonia-carbon dioxide forward (direct) osmosis desalination process [J]. Desalination，2005，174：1-11.
[3]胡群辉,邹昊,姜莹,等.正渗透膜分离关键技术及其应用进展[J].膜科学与技术,2014,34(5):109-115.
[4]Holloway R W，Childress A E，Dennett K E，et al. Forward osmosis for concentration of anaerobic digester centrate[J]. Water Research，2007，41：4005-4014.
[5]李刚，李雪梅，柳越，王铎，何涛，高从堦. 正渗透原理及浓差极化现象[J]. 化学进展，2010，22（5）：812-821.
[6]Ma N，Wei J，Liao R H，et al. Zeolite-polyamide thin film nanocomposite membranes: Towards enhanced performance for forward osmosis[J]. Journal of Membrane Science，2012，405-406(7)：149-157.
[7]樊晋琼，苏燕，王铎. 二氧化钛/聚酰胺正渗透复合膜的制备与表征[J]. 水处理技术，2012，38（009）：43-46.
[8]Huang Y，Jin H，Yu P，et al. Polyamide thin-film composite membrane based on nano-silica modified polysulfone microporous support layer for forward osmosis [J]. Desalination Water Treatment， 2016，57(43)： 20177-20187.
[9]Wu X，Field R W，Wu J J，et al. Polyvinylpyrrolidone modified graphene oxide as a modifier for thin film composite forward osmosis membranes[J]. Journal of Membrane Science，2017，540：251-260.
[10]Zirehpour A，Rahimpour A，Ulbricht M. Nano-sized metal organic framework to improve the structural properties and desalination performance of thin film composite forward osmosis membrane[J]. Journal of Membrane Science，2017，531： 59-67.
[11]Tang C，Wang Z，Petrini? I，et al. Biomimetic aquaporin membranes coming of age[J]. Desalination，2015， 368：89-105.
[12]Li H，Eddaoudi M，O'Keeffe M，et al. Design and synthesis of an exceptionally stable and highly porous metalorganic framework[J]. Nature，1999，402 ( 6759 )：276 -279.
[13]Burtch N C，Jasuja H，Walton K S. Water Stability and Adsorption in Metal-Organic Frameworks [J]. Chemical Reviews，2014，114(20)：10575-10612.
[14]Zhong W B，Ru-Xia Li，Jie-Lv，He T，et al. Two isomeric In(III)-MOFs：unexpected stability difffference and selective flfluorescence detection of flfluoroquinolone antibiotics in water[J]. Inorganic Chemistry Frontiers，2020，7：1161–1171.
[15]He Y R，Tang Y P，Ma D C，et al. UiO-66 incorporated thin-fifilm nanocomposite membranes for efficient selenium and arsenic removal[J]. Journal of Membrane Science，2017，541：262-270.
[16]Xiao F，Xiao P，Zhang W J，et al. Identification of key factors affecting the organic fouling on low-pressure ultrafiltration membranes[J]. Journal of Membrane Science，2013，447（1）：144-152.
[17]Granik V T，Smith B R，Lee S C，et al. Osmotic pressures for binary solutions of non-electrolytes[J].Biomedical Microdevices，2002，4：309-321.
[18]Shah D，Kissick K，Ghorpade A，et al. Pervaporation of alcohol-water and dimethylformamide-water mixtures using hydrophilic zeolite NaA membranes: mechanisms and experimental results[J]. Journal of Membrane Science，2000，179(1)： 185-205.
[19]Dutta D，Bhattacharyya A，Ganguly B N. Microstructural study of aromatic polyamide membrane material[J]. Journal of Membrane Science，2003，224(1)： 127-135.
[20]Zhang D P，Yao Z C，Zhang H，et al.A novel strategy to fabricate thin film nanocompsite reverse osmosis membranes with enhanced desalination performance[J].Desalination and water treatment，2019,145:70-82.

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