膜科学与技术

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PEI modified MWCNTs used to prepare high-throughput composite nanofiltration membranes

Authors： Yunhao Hei, Jun Xiang, Guiying Tian, Na Tang

Units： 1. College of Chemical Engineering and Materials Science, Tianjin university of science and technology, Tianjin 300457, China;2. Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization, Tianjin 300457, China

KeyWords： Multi-walled carbon nanotubes; polyethyleneimine modification; flux; nanofiltration; rejection rate;

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2021,41(5):87-96

Abstract：

In this work, polyethyleneimine modified multi-walled carbon nanotubes were prepared, polysulfone ultrafiltration membrane, polyethyleneimine and trimesoyl chloride were as the base membrane, water phase monomer, and organic phase monomer, respectively. Modified multi-walled carbon nanotubes were added into the water phase, and the organic-inorganic hybrid composite nanofiltration membrane was prepared by the interfacial polymerization method. The microscopic morphology/chemical properties and dispersion properties of the modified multi-walled carbon nanotubes were analyzed and characterized. The microstructure, infrared spectrum and contact angle of the base membrane and nanofiltration membrane were analyzed and characterized, and the influence of the addition amount of polyethyleneimine modified multi-walled carbon nanotubes on the membrane performance was discussed. The results show that the water flux of the composite nanofiltration membrane with 100mg·L-1 modified multi-walled carbon nanotubes can reach 11.95L·m−2·h−1·bar−1, and the rejection rate of MgCl2 is 94.4%. At the same time, the rejection rate for the four common commercial dyes is about 98%.

Funds：

国家自然科学基金(U20A20148)，天津市科技项目计划(18YFZCSF00330)，教育部科研创新团队培育计划(IRT-17R81)，天津市高等学校创新团队培养计划(TD13-5008)

AuthorIntro：

黑云皓（1995-），男，天津，硕士研究生，从事纳滤膜制备与膜法水处理研究，E-mail：18722460197@163.com.

Reference：

[1] Cadotte J E, Petersen R J, Larson R E, et al. A new thin-film composite seawater reverse osmosis membrane[J]. Desalination, 1980, 32(1-3): 25-31.
[2] Yang Z, Fang W, Wang Z, et al. Dual-skin layer nanofiltration membranes for highly selective Li+/Mg2+ separation[J]. J Membr Sci, 2021, 620.
[3] Mollahosseini A, Rahimpour A. Interfacially polymerized thin film nanofiltration membranes on TiO2 coated polysulfone substrate[J]. J Ind Eng Chem, 2014, 20(4): 1261-1268.
[4] Zhang H-Z, Xu Z-L, Shen Q. High-performance nanofiltration membrane intercalated by FeOOH nanorods for water nanofiltration[J]. Desalination, 2021, 498.
[5] Lai G S, Lau W J, Goh P S, et al. Development of thin film nanocomposite membrane incorporated with plasma enhanced chemical vapor deposition-modified hydrous manganese oxide for nanofiltration process[J]. Compos, 2019, 176.
[6] Jin L M, Yu S L, Shi W X, et al. Synthesis of a novel composite nanofiltration membrane incorporated SiO2 nanoparticles for oily wastewater desalination[J]. Polymer, 2012, 53(23): 5295-5303.
[7] Ping X A, Jha B, Zx B, et al. Positively charged nanofiltration membrane based on (MWCNTs-COOK)-engineered substrate for fast and efficient lithium extraction[J].Sep. Purif, 2021.
[8] Echaide-Górriz C, Zapata J A, Etxeberría-Benavides M, et al. Polyamide/MOF bilayered thin film composite hollow fiber membranes with tuned MOF thickness for water nanofiltration[J].Sep. Purif, 2020, 236.
[9] Li C, Li S, Tian L, et al. Covalent organic frameworks (COFs)-incorporated thin film nanocomposite (TFN) membranes for high-flux organic solvent nanofiltration (OSN)[J]. J Membr Sci, 2019, 572: 520-531.
[10] Mahdavi M R, Delnavaz M, Vatanpour V. Fabrication and water desalination performance of piperazine–polyamide nanocomposite nanofiltration membranes embedded with raw and oxidized MWCNTs[J]. J Taiwan Inst Chem E, 2017, 75: 189-198.
[11] Peydayesh M, Mohammadi T, Bakhtiari O. Water desalination via novel positively charged hybrid nanofiltration membranes filled with hyperbranched polyethyleneimine modified MWCNT[J]. J Ind Eng Chem, 2019, 69: 127-140.
[12] Zhao F Y, Ji Y L, Weng X D, et al. High-Flux Positively Charged Nanocomposite Nanofiltration Membranes Filled with Poly(dopamine) Modified Multiwall Carbon Nanotubes[J]. ACS Appl. Mater., 2016, 8(10): 6693-700.
[13] Granados-Martínez F G, Contreras-Navarrete J J, Ambriz-Torres J M, et al. MWCNTs-polymer composites characterization through spectroscopies: FTIR and Raman[J]. MRS Advances, 2018, 3(63): 1-6.
[14] Repalle S, Chen J, Drozd V, et al. The Raman spectroscopic studies of aligned MWCNTs treated under high pressure and high temperature[J]. J Mech Phys Solids, 2010, 71(8): 1150-1153.
[15] Manawi Y, Kochkodan V, Hussein M A, et al. Can carbon-based nanomaterials revolutionize membrane fabrication for water treatment and desalination?[J]. Desalination, 2016.
[16] Yang Z, Huang X, Wang J, et al. Novel polyethyleneimine/TMC-based nanofiltration membrane prepared on a polydopamine coated substrate[J]. Front Chem Sci Eng, 2017, 12(2): 273-282.
[17] Zhang H-Z, Xu Z-L, Ding H, et al. Positively charged capillary nanofiltration membrane with high rejection for Mg2 + and Ca2 + and good separation for Mg2 + and Li +[J]. Desalination, 2017, 420: 158-166.
[18] 俞昌朝, 储月霞, 沈江南,等. 纳米碳管改性聚哌嗪酰胺复合纳滤膜的制备[J]. 高校化学工程学报, 2014, 28(01): 84-91.
[19] Zhao H, Qiu S, Wu L, et al. Improving the performance of polyamide reverse osmosis membrane by incorporation of modified multi-walled carbon nanotubes[J]. J Membr Sci, 2014, 450: 249–256.
[20] Zhao F Y, An Q F, Ji Y L, et al. A novel type of polyelectrolyte complex/MWCNT hybrid nanofiltration membranes for water softening[J]. J Membr Sci, 2015, 492: 412-421.
[21] Ormanci-Acar T, Tas C E, Keskin B, et al. Thin-film composite nanofiltration membranes with high flux and dye rejection fabricated from disulfonated diamine monomer[J]. . J Membr Sci, 2020, 608.
[22] Zhao F-Y, An Q-F, Ji Y-L, et al. A novel type of polyelectrolyte complex/MWCNT hybrid nanofiltration membranes for water softening[J]. J Membr Sci, 2015, 492: 412-421.
[23] Shen J N, Yu C C, Ruan H M, et al. Preparation and characterization of thin-film nanocomposite membranes embedded with poly(methyl methacrylate) hydrophobic modified multiwalled carbon nanotubes by interfacial polymerization[J]. J Membr Sci, 2013, 442: 18-26.
[24] Vatanpour V, Esmaeili M, Farahani M H D A. Fouling reduction and retention increment of polyethersulfone nanofiltration membranes embedded by amine-functionalized multi-walled carbon nanotubes[J]. J Membr Sci, 2014, 466: 70-81.
[25] 江志彬, 杨浩, 李诗情,等. 荷正电聚酰胺有机/无机杂化复合纳滤膜的制备和脱盐性能研究[J]. 现代化工, 2018, 38(03): 156-160.

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