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Effect of Fe0/H2O2 on the performance and mechanism of forward osmosis treatment of practical printing and dyeing wastewater

Authors： Wu Qianqian, Huang Manhong, Song Jialing, Zheng Shengyang

Units： College of Environmental Science and Engineering，Donghua University，Shanghai 201620，China

KeyWords： Fe0/H2O2 system; Printing and dyeing wastewater; Forward osmosis; Membrane;

ClassificationCode：X703.1

year,volume(issue):pagination： 2021,41(5):105-113

Abstract：

Fe0/H2O2 system is used as the forward osmosis (FO) pretreatment technology for treating effluent from the secondary sedimentation tank of a printing and dyeing wastewater treatment plant. Through analyzing the effects of Fe0 dosage, H2O2 dosage and pH on the removal rate of COD and UV254 under different reaction time, the optimal experimental conditions for pretreatment are determined. The effects of pretreatment on the properties of FO and membrane fouling were investigated, and the mechanism of the effects was analyzed by SEM, contact Angle, EEM, XPS and other characterization methods. The results show that under the optimal pretreatment conditions, namely 1.5 g/L and 10 mM Fe0 and H2O2 dosage, pH=2~3 and reaction time of 60 min, the decrease rate of specific flux of FO membrane can be greatly slowed down, and the rejection rate of FO membrane to pollutants is increased by more than 10%. The XPS characterization of Fe0 before and after the reaction verified that hydroxyl radicals and iron (hydrogen) oxides, which can effectively remove organic matter, were produced in the reaction process of Fe0 and H2O2. The EEM before and after the wastewater treatment showed that the Fe0/H2O2 system produced significant degradation of protein samples and SMP substances in the wastewater. The SEM and contact Angle measurements on the membrane surface show that Fe0/H2O2 pretreatment can significantly reduce the FO membrane fouling.

Funds：

国家重点研发计划（2019YFC0408304）；中央高校基本科研业务费专项资金资助（2232020G-04）

AuthorIntro：

第一作者简介：邬倩倩（1997— ），女，湖北孝感人，硕士研究生，研究方向：正渗透的组合工艺及其应用。E-mail：qianqianwu18@163.com。

Reference：

[1] 王开花. 印染废水处理技术现状及发展趋势 [J]. 资源节约与环保, 2020, 12): 79-80.
[2] 罗瑛, 刘辉, 龙慧君, et al. 印染废水预处理技术研究进展(续一) [J]. 印染助剂, 2020, 37(11): 5-8.
[3] 刘燕,张铭元,王军,李洪,邓会宁.正渗透技术浓缩氯碱阳极淡盐水[J].膜科学与技术,2019,39(04):96-103.
[4] 吴科霖,骆华勇,方茜,荣宏伟.电场敏感水凝胶的制备及其正渗透脱盐性能研究[J].膜科学与技术,2020,40(06):58-64.
[5] SUWAILEH W, PATHAK N, SHON H, et al. Forward osmosis membranes and processes: A comprehensive review of research trends and future outlook [J]. Desalination, 2020, 485(11): 44-55.
[6] YADAV S, SALEEM H, IBRAR I, et al. Recent developments in forward osmosis membranes using carbon-based nanomaterials [J]. Desalination, 2020, 482(114): 63-75.
[7] 周宗尧,胡云霞,刘中云,Edo Bar-Zeev.海水淡化膜集成系统的发展现状及优势分析[J].膜科学与技术,2017,37(06):129-135.
[8] LY Q V, NGHIEM L D, CHO J, et al. Insights into the roles of recently developed coagulants as pretreatment to remove effluent organic matter for membrane fouling mitigation [J]. Journal of Membrane Science, 2018, 564(643-52.
[9] 张燕, 杨瑞雪. 芬顿氧化在印染废水深度处理中的应用实验研究 [J]. 广州化工, 2019, 47(17): 94-106.
[10] PAN Y, ZHOU M, CAI J, et al. Significant enhancement in treatment of salty wastewater by pre-magnetization Fe0/H2O2 process [J]. Chemical Engineering Journal, 2018, 339(4): 11-23.
[11]吴敏杰,黄满红,陈刚,蔡腾,宋佳玲.正渗透膜对印染废水中铬的处理特性[J].膜科学与技术,2019,39(04):124-131.
[12] LI J, JI Q, LAI B, et al. Degradation of p-nitrophenol by Fe0/H2O2/persulfate system: Optimization, performance and mechanisms [J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 80(6): 86-94.
[13] DONADELLI J A, CARLOS L, ARQUES A, et al. Kinetic and mechanistic analysis of azo dyes decolorization by ZVI-assisted Fenton systems: pH-dependent shift in the contributions of reductive and oxidative transformation pathways [J]. Applied Catalysis B: Environmental, 2018, 231(117): 51-61.
[14] QASIM M, DARWISH N A, SARP S, et al. Water desalination by forward (direct) osmosis phenomenon: A comprehensive review [J]. Desalination, 2015, 374(4): 57-69.
[15] CHEN W, WESTERHOFF P, LEENHEER J A, et al. Fluorescence Excitation-Emission Matrix Regional Integration to Quantify Spectra for Dissolved Organic Matter [J]. Environmental Science and Technology, 2003, 37(24): 01-10.
[16] YAMASHITA Y, TANOUE E. Chemical characterization of protein-like fluorophores in DOM in relation to aromatic amino acids [J]. Marine Chemistry, 2003, 82(3-4): 55-71.
[17] CHO Y, CHOI W. Visible light-induced reactions of humic acids on TiO2 [J]. Journal of Photochemistry and Photobiology A: Chemistry, 2002, 148(1-3): 29-35.
[18] ZHANG H, WANG J, ZHANG X, et al. Enhanced removal of lomefloxacin based on peroxymonosulfate activation by Co3O4/δ-FeOOH composite [J]. Chemical Engineering Journal, 2019, 369(8): 34-44.
[19] LEE G-H, SEON KIM Y, KIM D-W. Redox effect of Fe2+/Fe3+ in iron phosphates for enhanced electrocatalytic activity in Li-O2 batteries [J]. Chemical Engineering Journal, 2020, 388(124): 82-94.
[20] HUANG T, ZHANG G, ZHANG N, et al. Fe0-H2O2 for advanced treatment of citric acid wastewater: Detailed study of catalyst after several times use [J]. Chemical Engineering Journal, 2018, 336(2): 33-40.
[21] WANG F, LUO Y, RAN G, et al. Sequential coagulation and Fe0-O3/H2O2 process for removing recalcitrant organics from semi-aerobic aged refuse biofilter leachate: Treatment efficiency and degradation mechanism [J]. Science of The Total Environment, 2020, 699(134): 63-71.
[22] SHEN L, CUI X, YU G, et al. Thermodynamic assessment of adsorptive fouling with the membranes modified via layer-by-layer self-assembly technique [J]. Journal of Colloid and Interface Science, 2017, 494(56): 194-203.
[23] YAN H, NIAN Y, ZHOU Y, et al. A detailed dissolved organic matter characterization of starch processing wastewater treated by a sedimentation and biological hybrid system [J]. Microchemical Journal, 2017, 130(29): 285-300.

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