膜科学与技术

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Preparation and enantiomer resolution of chiral conjugated microporous polymer mixed matrix membranes containing menthol ester

Authors： Xie Yujie, Zang Yu, Wang Jianjun, Xu Liang, Zhang Chuanfang, Cui Jia, Lei Tianyang, Jing Boyu, Miao Fengjuan

Units： 1College?of?Materials?Science?and?Engineering, Qiqihar?University, Qiqihar161006，China; 2Analysis and Testing Center, Qiqihar University, Qiqihar 161006，China; 3College of Communications and Electronics Engineering, Qiqihar University, Qiqihar 161006，China

KeyWords： menthol ester; conjugated microporous polymer; mixed matrix membrane; enantiomer separation

ClassificationCode：TQ317；TQO28.8

year,volume(issue):pagination： 2022,42(2):78-88

Abstract：

In this paper, two kinds of chiral conjugated microporous polymers (CCMP) containing menthol esters were successfully synthesized by the "bottom-up" strategy. Using CCMP as dispersed-phase, cellulose acetate (CA) and ethyl cellulose (EC) as substrates, three mixed-matrix membranes were prepared by phase conversion method.Scanning electron microscopy showed that CCMP was evenly dispersed in the matrix.When the mass fraction of CDCMP-1 was 4%, the permeability of (D,L) -phenylalanine was 7.75×10-9 m2/h, and the excess of enantiomer was 60.6% ee, showing high enantiomer separation performance.

Funds：

国家自然科学基金（52173202）；2019黑龙江省省属本科高校基本科研业务费青年创新人才项目（135409201）；黑龙江省自然科学基金（JQ20197003,ZD20197004）

AuthorIntro：

谢禹杰（1997-），男，河南省洛阳市，硕士研究生在读，研究方向为分离功能高分子膜

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