膜科学与技术

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Recent research of nanofiltration membrane preparation based on metal-organic frameworks (MOFs)

Authors： DU Haiyang, ZHANG Wenjuan, WEN Shu, CHANG Jing, WANG Shaopo, ZHANG Yufeng

Units： Tianjin Key Laboratory of Aquatic Science and Technology, School of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin, 300384, P. R. China

KeyWords： mixed matrix membrane; nanofiltration membrane; metal organic frameworks(MOFs);TFN membrane

ClassificationCode：TQ028;TB333

year,volume(issue):pagination： 2022,42(2):154-162

Abstract：

The permeability and retention of nanofiltration membrane restrict each other. Metal organic frameworks (MOFs) materials have attracted much attention because of their large porosity, high specific surface area and controllable pore size. Introducing MOFs as a nanoparticle additive into nanofiltration membrane can effectively alleviate the restriction effect between membrane selectivity and permeability, and endow the nanofiltration membrane with some other characteristics, such as hydrophilicity, antibacterial and anti-fouling. In this paper, the classification, characteristics and synthesis methods of MOFs used in nanofiltration membranes are introduced, and several polymer substrates commonly used in MOFs nanofiltration membranes in recent years are listed, including polyvinylidene fluoride, polysulfone, polyethersulfone, polyimide and polyacrylonitrile. Some methods for the preparation of MOFs nanofiltration membranes, such as in-situ growth, blending and interfacial polymerization, are described in detail. Finally, some problems encountered in the research of MOFs nanofiltration membrane are summarized, and the development of MOFs nanofiltration membrane in the future is prospected.

Funds：

国家自然科学基金（52100011）；天津市教委科研计划项目（2018KJ161），天津城建大学科研启动基金（180501412）

AuthorIntro：

杜海洋(1997-)，男，河北沽源人，硕士，研究方向为基于金属有机骨架纳滤膜的制备

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