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Preparation and properties of high performance internally pressurized hollow fiber nanofiltration membrane

Authors： LIU Shaoxiao, LV Xinghua, WANG Enlin, LIU Liyang, LI Shuxuan, SU Baowei

Units： Key Laboratory of Marine Chemistry Theory and Technology （Ocean University of China）, Ministry of Education, 238 Songling Road, Qingdao, 266100, China; College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao, 266100, China

KeyWords： Nanofiltration membrane; Hollow fiber; Heavy mental ions; Internally pressurized type

ClassificationCode：TQ 028.8

year,volume(issue):pagination： 2022,42(4):9-21

Abstract：

Nanofiltration (NF) membrane has been widely used in seawater softening and wastewater recycling. Internally pressurized hollow fiber (HF) NF membrane has broad development prospects as it possesses high filling density and difficult to damage the polyamide layer. In this paper, Polysulfone (PSf) HF ultrafiltration membrane was used as the substrate membrane, the internally pressurized HFNF membrane was prepared by interfacial polymerization (IP) on the inner surface of the substrate membrane with piperazine (PIP) and Trimesoyl chloride (TMC) as aqueous and organic monomers and Sodium dodecyl sulfate (SDS) and triethylamine (TEA) as aqueous additives. The effects of water phase flow rate, N2 purging time, PIP concentration and TEA concentration on the separation performance of internally pressurized HFNF membrane were studied. The performance test results showed that the internally pressurized HFNF membrane prepared under the optimal conditions had higher water permeability of 93 L/ (m2 h MPa) and the Na2SO4 rejection of 97.2% for 2000 mg/L Na2SO4 solution at 0.4 MPa. For 2000 mg/L heavy metal salt solution, the rejection of ZnSO4 and MnSO4 in ZnSO4 and MnSO4 solution could reach 93%. Moreover, the prepared internally pressurized HFNF membrane showed good anti-fouling performance and chlorine resistance performance.

Funds：

山东省重点研发计划项目（No. 2019GGX102040）

AuthorIntro：

刘少校（1997-），男，山东青岛人，硕士研究生，研究方向：中空纤维纳滤膜分离技术E-mail:lsx158799@foxmail.com

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