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Preparation of “sandwich-like” structure composite membrane modified by quaternized polyphenylene oxide and UiO-66

Authors： RUAN Huimin, XU Jingwen, PAN Nengxiu, GAO Shangshang, LIAO Junbin, SHEN Jiangnan

Units： College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

KeyWords： polyphenylene oxide; UiO-66 composite membrane; monovalent anion perm-selectivity; electrodialysis

ClassificationCode：O658.6+8

year,volume(issue):pagination： 2022,42(6):31-40

Abstract：

A series of “sandwich-like” structure composite membranes has been prepared by modifying the anodic alumina (AAO) membrane as support layer with quaternized polyphenylene oxide (QPPO) and UiO-66-NH2, which were used for surface modification on each side, and the influence of the modified layers on the surface resistance and hydrophilicity of the prepared composite films was investigated. Electrodialysis test results show, the investigation demonstrates that the selectivity of UiO-66-NH2 layer is 15, which is higher than that of QPPO layer (1). However, as for the composite membrane, the selectivity of the two as separation layers is approximately (7.12). The high selectivity of UiO-66-NH2 may result from its pore size, which accurately screens ions with different sizes. However, the low selectivity of QPPO layer limits the ability of the composite membrane to selectively screen separators, resulting in that the monovalent ion selectivity of the composite membrane is not as good as that of the monolayer UiO-66-NH2-AAO membrane.

Funds：

浙江省重点研究发展计划（No. 2021C03170）；国家自然科学基金项目（No. 21878273和No. 22008214）；浙江省自然科学基金资助项目（No. LQ20B060005）.

AuthorIntro：

阮慧敏（1976–），女，浙江玉环，副教授，研究生，博士，研究方向为膜法水处理技术、海水综合利用

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