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Preparation and properties of mixed matrix membranes based on amino acids MOF

Authors： ZHANG Xiaocan, MA Huixiao, ZHU Ziyuan

Units： Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, College of science, China University of Petroleum (Beijing), Beijing 102249, China

KeyWords： metal organic framework; membrane fouling; polysulfone ultrafiltration membrane; anti-fouling properties

ClassificationCode：TQ028.3+8

year,volume(issue):pagination： 2023,43(4):75-83

Abstract：

Hydrophilic modification is one of the most important strategies to enhance antifouling properties of polysulfone (PSf) membranes. Blending of PSf with hydrophilic material MIP-202 is an efficient way. The polysulfone (PSf)/MIP-202 mixed matrix membrane was prepared via non solvent induced phase separation (NIPS) using N,N-dimethylacetamide (DMAc) as the solvent and PVP as the pore forming agent. The effect of MIP-202 content on the structure and performance of PSf ultrafiltration membrane was studied. The composite membranes were characterized by XRD, SEM and FTIR, and water contact angle, water flux, porosity and average pore size were also analyzed. The composite membrane exhibited optimum properties with 4% MIP-202, and the water contact angle decreased from 81° to 70 °. The maximum pure water flux was 550 L/(m2·h) with BSA rejection up to 95%, and it was 1.8 times of the DI water flux of the pristine membrane [300 L/(m2·h)]. The flux recovery ratio increased from 42 % to 75 %, and the antifouling performance was significantly improved compared with that of pristine PSf membrane.

Funds：

国家自然科学基金（22105225），中国石油大学（北京）校级自主科研基金（2462022YXZZ00 7）

AuthorIntro：

张晓灿（1982-），女，籍贯河南新乡，副教授，博士，主要从事高分子复合膜材料的研究，E-mail：xiaocan.zhang@cup.edu.cn

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