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Synthesis and properties of bisphenol S type copoly(phthalazinone ether sulfone) membrane materials

Authors： ZHANG Yingnan, WANG Xu, XU Peiqi WANG Hao, XU Shugang, ,ZHANG Shouhai*, JIAN Xigao

Units： College of chemical engineering, Dalian University of Technology, Liaoning Technology Innovation Center of High Performance Resin Materials, Liaoning Key Laboratory of Polymer Science and Engineering, Dalian Key Laboratory of Membrane Materials and Process, Dalian 116024, China

KeyWords： copoly(phthalazinone ether sulfone); synthesize; polymeric membrane；hollow fiber membrane

ClassificationCode：TQ324.8

year,volume(issue):pagination： 2023,43(5):37-43

Abstract：

A series of bisphenol S type copoly(phthalazinone ether sulfone) (PPESS) were synthesized from (4-(4'-hydroxylphenyl)-2,3-phthalazin-1-one, bisphenol S, and 4,4'-dichlorodiphenyl sulfone. The structure of PPESS were characterized by nuclear magnetic resonance, infrared spectra, and X-ray diffraction spectra. Intrinsic viscosity, molecular weight, solubility, hydrophilicity, and tensile properties of PPESS were investigated. Thermal performance of PPESS were analyzed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The PPESS hollow fiber membranes were prepared by dry-wet phase conversion, and the effect of the proportion of phthalazinone moieties on the membrane permeability selectivity was investigated. The results show that the glass transition temperature (Tg) of PPESS was in the range of 249-288 ℃, the 5% mass-loss temperature (T5%) was in the range of 449-518 ℃, and the thermal performance increases with the increase of the proportion of phthalazinone moiety in PPESS. In addition, the water flux of the membranes increase with the increase of the proportion of phthalazinone moiety in PPESS, while the bovine serum protein (BSA) retention rate does not change significantly; PPESS-80 membrane has the best permeation selectivity, with pure water flux of 51.8 L-2 h-1 and BSA retention rate of 97.2%.

Funds：

基金项目：国家自然科学基金委创新研究群体项目(22021005)；中央高校基本科研业务费专项资金资助(DUT22LAB605)

AuthorIntro：

张瑛楠（1998-），女，山东潍坊人，硕士，从事高性能高分子膜材料研究

Reference：

[1]王伟, 李静. 浅析中水回用技术[J]. 应用能源技术, 2011, (4): 38-39.
[2]Wang H, Liu Y, Peng D, et al. Development of membrane separation technology and its application prospect[J]. Applied Chemical Industry, 2013, 42(3): 532-53.
[3]Xiao Q C, Wang J, Wang X, et al. A hydrophilicity gradient control mechanism for fabricating delamination-free dual-layer membranes[J]. Journal of Membrane Science, 2017, 539: 392-402.
[4]Rodriguez-Saez L, Patsios S I, Senan-Salinas J, et al. A novel application of recycled ultrafiltration membranes in an aerobic membrane bioreactor (aMBR): A proof-of-concept study[J]. Membranes, 2022, 12(2): 218.
[5]Ismail A F, Lau W J. Theoretical studies on structural and electrical properties of PES/SPEEK blend nanofiltration membrane[J]. AIChE Journal, 2009, 55(8): 2081-2093.
[6]刘晓伟, 胡梦洋, 陶然, 等. 聚醚砜/磺化聚砜/磺化聚醚砜共混疏松纳滤膜的制备及其染料/盐选择分离性能[J]. 膜科学与技术, 2021, 41(4): 65-72.
[7]Jo Y J, Choi E Y, Kim S W, et al. Fabrication and characterization of a novel polyethersulfone/aminated polyethersulfone ultrafiltration membrane assembled with zinc oxide nanoparticles[J]. Polymer, 2016, 87: 290-299.
[8]柳周洋, 张守海, 石婉玲, 等. 磺化含侧苯基杂萘联苯聚芳醚砜膜材料的制备与性能[J]. 膜科学与技术, 2019, 39(5): 87-95.
[9]Simin N, Amira A. Surface zwitterionization of hemodialysis membranes for hemocompatibility enhancement and protein-mediated anti-adhesion: A critical review[J]. Biomedical Engineering Advances, 2022, 3: 100026.
[10]孙宇轩, 张所波. 官能化聚醚砜(酮)膜材料制备与性能研究[J]. 膜科学与技术, 2020, 40(1): 328-339.
[11]Huang Z Y, Liu J H, Xu Y C, et al. Enhanced permeability and antifouling performance of polyether sulfone (PES) membrane via elevating magnetic Ni@MXene nanoparticles to upper layer in phase inversion process[J]. Journal of Membrane Science, 2021, 623: 119080.
[12]徐象贤, 张守海, 刘乾, 等. 杂萘联苯共聚醚砜血液透析膜的制备与性能[J]. 膜科学与技术, 2020, 40(5): 1-8.
[13]Liu Q, Zhang S H, Wang Z Q, et al. Effect of pendent phenyl and bis-phthalazinone moieties on the properties of N-heterocyclic poly(aryl ether ketone ketone)s[J]. Polymer, 2020, 198: 122525.
[14]Xu P Q, Zhang S H, Liu Q, et al. Polyarylates containing phthalazinone moieties with excellent thermal resistance[J]. High Performance Polymers, 2023.
[15]Zhang P Y, Wang Y L, Xu Z L, et al. Preparation of poly(vinyl butyral) hollow fiber ultrafiltration membrane wet-spinning method using PVP as additive[J]. Desalination, 2011, 278: 186-193.
[16]Hoseinpour V, Ghaee A, Vatanpour V, et al. Surface modification of PES membrane via aminolysis and immobilization of carboxymethylcellulose and sulphated carboxymethylcellulose for hemodialysis[J]. Carbohydrate Polymers, 2018, 188: 37-47.
[17]Mahdie S, Vahid V, Alireza K. Preparation and characterization of graphene oxide/TiO2 blended PES nanofiltration membrane with improved antifouling and separation performance[J]. Desalination, 2016, 393: 65-78.
[18]肖丽红. 含杂萘联苯结构多元共聚芳醚的合成与性能[D]. 大连: 大连理工大学, 2008.
[19]步肖曼, 张守海, 薛仁东, 等. 聚醚砜与杂萘联苯共聚醚砜共混超滤膜的制备[J]. 膜科学与技术, 2018, 38(6):56-62.
[20]Han R L, Zhang S H, Yang D L, et al. Preparation and characterization of novel copoly(phthalazinone ether sulfone) ultrafiltration membranes with excellent thermal stability[J]. Journal of Membrane Science, 2010, 358(1-2): 142-149.

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