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Recent progress on structure and performance control of hydrophobic PVDF membranes prepared by non-solvent induced phase separation
Authors: XU XiaoJie, YU Mengchao, WANG Yu, WANG Tao, FENG YingNan, ZHAO ZhiPing
Units: School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488
KeyWords: hydrophobic polymeric membranes; non-solvent induced phase separation; spray-assisted non-solvent induced phase separation; membrane distillation
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2024,44(1):147-156

Abstract:
  Non-solvent induced phase separation (NIPS) is an efficient method to prepare porous hydrophobic membranes. It involves thermodynamic and kinetic factors which have deterministic effects on the structure and performance of hydrophobic porous membranes. Hence, a commonly used material for hydrophobic membrane preparation, PVDF, is taken as the research object in this paper. This paper systematically summarizes the influencing factors and membrane formation mechanisms of traditional immersion precipitation method and emerging spray-assisted non-solvent induced phase separation method in the membrane preparation process, focusing on the effects of different fabrication conditions on the membrane structure and performance (hydrophobicity, pore size and porosity, etc.), which could lay a foundation for the controllable preparation of hydrophobic membranes.

Funds:
国家自然科学基金(22208016),北京理工大学青年教师学术启动计划。

AuthorIntro:
徐小洁(2000-),女,河北邯郸人,硕士研究生,研究方向为有机膜制备及应用,E-mail:xxj001221@163.com

Reference:
 [1] Pagliero M, Bottino A, Comite A, et al. Novel hydrophobic PVDF membranes prepared by nonsolvent induced phase separation for membrane distillation[J]. Journal of Membrane Science, 2020, 596: 117575.
[2] Liu F, Hashim N A, Liu Y, et al. Progress in the production and modification of PVDF membranes[J]. Journal of Membrane Science, 2011, 375(1-2): 1-27.
[3] Kang G, Cao Y. Application and modification of poly(vinylidene fluoride) (PVDF) membranes – A review[J]. Journal of Membrane Science, 2014, 463: 145-165.
[4] Shi L, Wang R, Cao Y, et al. Fabrication of poly(vinylidene fluoride-co-hexafluropropylene) (PVDF-HFP) asymmetric microporous hollow fiber membranes[J]. Journal of Membrane Science, 2007, 305(1-2): 215-225.
[5] Wongchitphimon S, Wang R, Jiraratananon R, et al. Effect of polyethylene glycol (PEG) as an additive on the fabrication of polyvinylidene fluoride-co-hexafluropropylene (PVDF-HFP) asymmetric microporous hollow fiber membranes[J]. Journal of Membrane Science, 2011, 369(1-2): 329-338.
[6] Shi L, Wang R, Cao Y, et al. Effect of additives on the fabrication of poly(vinylidene fluoride-co-hexafluropropylene) (PVDF-HFP) asymmetric microporous hollow fiber membranes[J]. Journal of Membrane Science, 2008, 315(1-2): 195-204.
[7] Gu J, Xu S, Lu X, et al. Study on the membrane formation mechanism of PVDF/PVDF-CTFE blends[J]. Journal of the Taiwan Institute of Chemical Engineers, 2023, 142: 104655.
[8] Saïdi S, Macedonio F, Russo F, et al. Preparation and characterization of hydrophobic P(VDF-HFP) flat sheet membranes using Tamisolve® NxG solvent for the treatment of saline water by direct contact membrane distillation and membrane crystallization[J]. Separation and Purification Technology, 2021, 275: 119144.
[9] Neinhuis C. Characterization and Distribution of Water-repellent, Self-cleaning Plant Surfaces[J]. Annals of Botany, 1997, 79(6): 667-677.
[10] Wang H-T, Lu M-C, Shi M-S, et al. Regulation of the microstructure of polyvinylidene fluoride membrane via incorporation of nano-ZIF-7 for improving hydrophobicity and antiwetting performance[J]. Journal of the Chinese Chemical Society, 2020, 67(5): 732-743.
[11] Li C, Liu W, Mao J, et al. Superhydrophobic PVDF membrane modified by dopamine self-polymerized nanoparticles for vacuum membrane distillation[J]. Separation and Purification Technology, 2023, 304:122182.
[12] Celia E, Darmanin T, Taffin de Givenchy E, et al. Recent advances in designing superhydrophobic surfaces[J]. Journal of Colloid and Interface Science, 2013, 402: 1-18.
[13] 刘敏, 贺兵, 姜馨淳, 等. NIPS法一步制备PVDF疏水分离膜的研究进展[J]. 净水技术, 2020, 39(7): 77-83.
[14] Chung T S, Teoh S K, Hu X. Formation of ultrathin high-performance polyethersulfone hollow-fiber membranes[J]. Journal of Membrane Science, 1997, 133(2): 161-175.
[15] Abdulla AlMarzooqi F, Roil Bilad M, Ali Arafat H. Improving Liquid Entry Pressure of Polyvinylidene Fluoride (PVDF) Membranes by Exploiting the Role of Fabrication Parameters in Vapor-Induced Phase Separation VIPS and Non-Solvent-Induced Phase Separation (NIPS) Processes[J]. Applied Sciences, 2017, 7(2): 181.
[16] 俞三传, 高从堦. 浸入沉淀相转化法制膜[J]. 膜科学与技术, 2000(5): 36-41.
[17] Yeow M L, Liu Y T, Li K. Morphological study of poly(vinylidene fluoride) asymmetric membranes: Effects of the solvent, additive, and dope temperature[J]. Journal of Applied Polymer Science, 2004, 92(3): 1782-1789.
[18] Gregorio R. Determination of the α, β, and γ crystalline phases of poly(vinylidene fluoride) films prepared at different conditions[J]. Journal of Applied Polymer Science, 2006, 100(4): 3272-3279.
[19] Tao M, Liu F, Ma B, et al. Effect of solvent power on PVDF membrane polymorphism during phase inversion[J]. Desalination, 2013, 316: 137-145.
[20] Li Q, Xu Z-L, Yu L-Y. Effects of mixed solvents and PVDF types on performances of PVDF microporous membranes[J]. Journal of Applied Polymer Science, 2010, 115(4): 2277-2287.
[21] Wu C, Tang W, Zhang J, et al. Preparation of super-hydrophobic PVDF membrane for MD purpose via hydroxyl induced crystallization-phase inversion[J]. Journal of Membrane Science, 2017, 543: 288-300.
[22] Toh M J, Oh P C, Chew T L, et al. Antiwettability enhancement of PVDF-HFP membrane via superhydrophobic modification by SiO2 nanoparticles[J]. Comptes Rendus Chimie, 2019, 22(5): 369-372.
[23] Zou L, Zhang G, Yu J. Desirable PVDF hollow fiber membrane engineered with synergism between small molecular weight additives for DCMD treating of a hypersaline brine[J]. Journal of Water Process Engineering, 2022, 45: 102528.
[24] 史艳阳, 陈小乐, 苗闪闪, 等. PVDF超疏水膜的研制及空气过滤初探[J]. 膜科学与技术, 2023: 1-11.
[25] Zhang R, Tang W, Gao H, et al. In-situ construction of superhydrophobic PVDF membrane via NaCl-H2O induced polymer incipient gelation for membrane distillation[J]. Separation and Purification Technology, 2021, 274: 117762.
[26] Zheng L, Wu Z, Wei Y, et al. Preparation of PVDF-CTFE hydrophobic membranes for MD application: Effect of LiCl-based mixed additives[J]. Journal of Membrane Science, 2016, 506: 71-85.
[27] Ouchn R, Chaouqi Y, Louafy R, et al. Polymer Inclusion membranes with long term-stability in desalination via membrane distillation[J]. Chemical Engineering and Processing - Process Intensification, 2023, 191: 109442.
[28] 李硕, 王兴娅, 王文治, 等. 高疏水PVDF微孔膜及其膜蒸馏分离生物质发酵乙醇性能[J]. 膜科学与技术, 2019, 39(3): 110-118.
[29] Munirasu S, Banat F, Durrani A A, et al. Intrinsically superhydrophobic PVDF membrane by phase inversion for membrane distillation[J]. Desalination, 2017, 417: 77-86.
[30] Mazinani S, Darvishmanesh S, Ehsanzadeh A, et al. Phase separation analysis of Extem/solvent/non-solvent systems and relation with membrane morphology[J]. Journal of Membrane Science, 2017, 526: 301-314.
[31] Song H-M, Zhu L-J, Wang G, et al. Salt-induced and alcohol-induced hydrophobic and underoil superhydrophobic poly (vinylidene fluoride) membranes for effective oil collection[J]. Journal of Environmental Chemical Engineering, 2021, 9(1): 104714.
[32] Akbari B, Lashanizadegan A, Darvishi P, et al. Preparation of hydrophobic flat sheet membranes from PVDF-HFP copolymer for enhancing the oxygen permeance in nitrogen/oxygen gas mixture[J]. Chinese Journal of Chemical Engineering, 2020, 28(6): 1566-1581.
[33] Li Q, Xu Z-L, Liu M. Preparation and characterization of PVDF microporous membrane with highly hydrophobic surface[J]. Polymers for Advanced Technologies, 2011, 22(5): 520-531.
[34] 张琳. PVDF平板疏水膜的制备及其应用[D]. 南昌:南昌大学, 2012.
[35] 王兴娅. 超疏水膜的制备及其膜蒸馏分离发酵乙醇的研究[D]. 北京:北京理工大学, 2016.
[36] Lin J, Du J, Xie S, et al. Durable superhydrophobic polyvinylidene fluoride membranes via facile spray-coating for effective membrane distillation[J]. Desalination, 2022, 538: 115925.
[37] Zhang W, Li Y, Liu J, et al. Fabrication of hierarchical poly (vinylidene fluoride) micro/nano-composite membrane with anti-fouling property for membrane distillation[J]. Journal of Membrane Science, 2017, 535: 258-267.
[38] Lu K J, Zhao D, Chen Y, et al. Rheologically controlled design of nature-inspired superhydrophobic and self-cleaning membranes for clean water production[J]. npj Clean Water, 2020, 3(1): 1-10.
[39] Lu K-J, Liang C Z, Chen Y, et al. Unlock the secret of air blowing in developing high strength and superhydrophobic membranes for membrane distillation[J]. Desalination, 2022, 527: 115579.
[40] Yang H-R, Huang Y-H, Wang C-F, et al. Green fabrication of PVDF superhydrophobic membranes using a green solvent triethyl phosphate (TEP) for membrane distillation[J]. Desalination, 2023, 566: 116934.

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