膜科学与技术

Position：Home >> Abstract

Construction of electroneutral hollow fiber loose nanofiltration separation layer based on aldol condensation reaction and the investigation on dye removal

Authors： TANG Shenyi，WU Biao, CUI Zhenyu

Units： 1. School of Material Science and Engineering, Tiangong University, Tianjin 300387，China; 2. Tianjin TisunItacsa Technology CO., LTD, Tianjin 300382, China

KeyWords： electroneutrality; chemical cross-linking; hollow fiber membrane; loose nanofiltration; dye removal

ClassificationCode：TQ028，TB34

year,volume(issue):pagination： 2024,44(2):125-133

Abstract：

In this work, polyvinylidene fluoride (PVDF)/styrene maleic anhydride (SMA) hollow fiber ultrafiltration membrane was used as a substrate matrix, a robust and compact electroneutral hollow fiber loose nanofiltration (LNF)separation layer was constructed based on the aldol condensation reaction by sequentially introducing three hydrophilic compounds (triethylene glycol (TEG), glutaraldehyde (GA), polyvinyl alcohol (PVA)) on the membrane surface. The microstructural characteristics and separation performance of the membrane were systematically analysed. The acquired results indicated hydrophilicity gradually increased and charge relatively neutral as chemical reaction occurred. Both negatively charged Sunset Yellow (SY) and positively charged Crystal Violet (CV) dyes can be completely removed while maintaining high permeation flux (27.8 L/(m2 h), 28.9 L/(m2 h)). In addition, the membrane exhibited excellent chemical stability and long-term operation stability. This work provides a novel method to fabricate electroneutral hollow fiber LNF membrane with high separation performance.

Funds：

国家自然科学基金面上项目（21978213）

AuthorIntro：

汤申艺（1998-），女，山东聊城人，硕士生，主要从事膜材料制备及应用研究，E-mail：932624861@qq.com

Reference：

[1] Wang J, Qin L, Lin J, et al.Enzymatic construction of antibacterial ultrathin membranes for dyes removal[J].Chemical Engineering Journal, 2017, 323:56-63.
[2] Liu J, Zhuo Z, Xie w, et al.Interaction effects of chlorine and phosphorus on thermochemical behaviors ofheavy metals during incineration of sulfur-rich textile dyeing sludg[J]. Chemical Engineering Journal,2018, 351:897-911.
[3] Bili´nska L, Blus K, Gmurek M, et al.Coupling of electrocoagulation andozone treatment for textile wastewater reuse[J]. Chemical Engineering Journal,2019, 358:992-1001.
[4] Zhu J, Tian M, Hou J, et al. Surface zwitterionic functionalized graphene oxide for a novel loose nanofiltration membrane[J]. Journal of Materials Chemistry A, 2016, 4:1980-1990.
[5] Cheng X, Wang Z, Zhang Y, et al. Bio-inspired loose nanofiltration membranes with optimized separation performance for antibiotics removals[J]. Journal of Membrane Science, 2018, 554:385-394.
[6] Li Q, Chen G Q, Liu L, et al. Spray assisted layer-by-layer assembled one-bilayer polyelectrolyte reverse osmosis membranes[J]. Journal of Membrane Science, 2018, 564:501-507.
[7] Fan L, Ma Y, Su Y, et al. Green coating by coordination of tannic acid and iron ions for antioxidant nanofiltration membranes[J]. RSC Advances, 2015, 5:107777-107784.
[8] Bian L, Shen C, Song C, et al. Compactness-tailored hollow fiber loose nanofiltration separation layers based on “chemical crosslinking and metal ion coordination” for selective dye separation[J]. Journal of membrane science, 2021, 620:118948.
[9] Yang Y, Tian Z, Zhang J, et al. Fabrication of hollow fiber loose nanofiltration separation layers based on nucleophilic addition and Schiff base reactions and the investigation on separation performance of low molecular weight dye/salt systems[J]. Journal of Membrane Science, 2021, 640:119761.
[10] Tang S, Jiao Y, Yan F, et al. Construction of hollow fiber nanofiltration separation layer with bridging network structure by polymer-anchored co-deposition for high-concentration heavy metal ion removal[J]. Journal of membrane science, 2022, 661:120864.
[11] Song C, Tang S, Yue S, et al. Design of microstructure for hollow fiber loose nanofiltration separation layer and its compactness-tailoring mechanism[J]. Journal of Hazardous Materials, 2022, 421:126800.
[12] Saba A, Alireza A, Vahid V, et al. Fabrication and characterization of a novel polyvinyl alcohol-grapheneoxide-sodium alginate nanocomposite hydrogel blended PES nanofiltrationmembrane for improved water purification[J]. Separation and Purification Technology, 2020, 250:117216.
[13] Shen C, Bian L, Zhang P, et al. Microstructure evolution of bonded water layer and morphology of grafting membrane with different polyethylene glycol length and their influence on permeability and anti-fouling capacity[J]. Journal of membrane science, 2020, 601:117949.
[14] Wei Q, Wu C, Zhang J, et al. Fabrication of surface microstructure for the ultrafiltration membrane based on “active–passive” synergistic antifouling and its antifouling mechanism of protein[J]. Reactive and Functional Polymers, 2021, 169:105068.
[15] Tang S, Yang J, Wu B, et al. Fabrication of hollow fiber nanofiltration membrane with high permselectivity based on "co-deposition, biomineralization and dual cross-linking" process[J]. Journal of Membrane Science, 2023, 670:121388.
[16] Liu S, Wang Z, Ban M, et al. Chelation–assisted in situ self-assembly route to prepare the loose PAN–based nanocomposite membrane for dye desalination[J]. Journal of Membrane Science, 2018, 566:168-180.
[17] Chen P, Ma X, Zhong Z, et al. Performance of ceramic nanofiltration membrane for desalination of dye solutions containing NaCl and Na2SO4[J]. Desalination, 2017, 404:102-111.
[18] Jiang G, Zhang S, Zhu Y, et al. Hydrogel-embedded tight ultrafiltration membrane with superior anti-dye-fouling property for low-pressure driven molecule separation[J]. Journal of Materials Chemistry A, 2018, 6(7):2927-2934.
[19] Bian L, Wei Q, Li J, et al. Hollow fiber composite membranes engineered via the combination of “anionic crosslinking and in-situ biomineralization” for dye removal[J]. European Polymer Journal, 2022, 179:111587.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com