膜科学与技术

Position：Home >> Abstract

Fabrication and performance of maltitol-based polyester composite nanofiltration membrane

Authors： ZHANG Quanhe，LIU Dapeng，HONG Yaoliang

Units： 1.School of Environment Science and Engineering，Suzhou University of Science and Technology，Suzhou 215009，China；2. Jiangsu Separation and Purification Materials and Technology Engineering Research Center, Suzhou 215009，China;3.Jiangsu Collaborative Innovation Center of Water Treatment Technology and Material，Suzhou 215009，China

KeyWords： loose nanofiltration membrane; interfacial polymerization; Maltitol; dye/salt

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2024,44(3):133-142

Abstract：

Loose nanofiltration membranes with excellent dye/salt selective separation are expected to fulfill the urgent need for dye/salt mixture separation in textile wastewater treatment. In this study, Maltitol with abundant hydroxyl groups was used as a novel aqueous monomer, and Maltitol/TMC loose nanofiltration membrane with high dye/salt selectivity and high water permeance was fabricated by interfacial polymerization (IP) with trimesoyl chloride (TMC) on the surface of Polyethersulfone (PES) ultrafiltration membranes for the excellent separation of dye/salt mixed solutions.The performance of the membranes was optimized by adjusting the concentration of Maltitol, and the optimized membranes had water permeance of 800.1 L· m2·h/MPa, with dyes rejection to 99.3 %, 95.1 % and 97.2 % for Congo red (CR), Direct red 23 (DR 23) and Eriochrome black T (EBT), the rejection of Na2SO4 and NaCl were only 10.3 % and 4.4 %, respectively. The optimized membranes showed flux recovery ratio (FRR) of around 90 % for all three dyes, and good long-term stability for the mixed salt/dye solutions. The new maltitol-based nanofiltration membrane has excellent application prospects in textile wastewater treatment.

Funds：

国家自然科学基金（51908394）

AuthorIntro：

张全合（1999-），河南信阳人，硕士，主要从事污水处理与回用技术。

Reference：

[1] Zheng J, Zhao R, Uliana A A, et al. Separation of textile wastewater using a highly permeable resveratrol-based loose nanofiltration membrane with excellent anti-fouling performance [J]. Chem Eng J, 2022, 434:134705.
[2] Samanta K K, Pandit P, Samanta P, et al. Water consumption in textile processing and sustainable approaches for its conservation [M]//MUTHU. Water in Textiles and Fashion:Consumption, Footprint, and Life Cycle Assessment. Cambridgeshire:.Woodhead Publishing. 2019: 41-59.
[3] Holkar C R, Jadhav A J, Pinjari D V, et al. A critical review on textile wastewater treatments: Possible approaches [J]. J Environ Manage, 2016, 182:351-366.
[4] Liu Y, Zhu J, Zheng J, et al. A facile and scalable fabrication procedure for thin-film composite membranes: Integration of phase inversion and interfacial Polymerization [J]. Environ Sci Technol, 2020, 54(3):1946-1954.
[5] Zheng J, Li Y, Xu D, et al. Facile fabrication of a positively charged nanofiltration membrane for heavy metal and dye removal [J]. Sep Purif Technol, 2022, 282:120155.
[6] Ritt C L, Werber J R, Wang M, et al. Ionization behavior of nanoporous polyamide membranes [J]. Proc Natl Acad Sci U S A, 2020, 117(48):30191-30200.
[7] Ding J, Wu H, Wu P. Preparation of highly permeable loose nanofiltration membranes using sulfonated polyethylenimine for effective dye/salt fractionation [J]. Chem Eng J, 2020, 396:125199.
[8] Li Q, Liao Z, Fang X, et al. Tannic acid assisted interfacial polymerization based loose thin-film composite NF membrane for dye/salt separation [J]. Desalination, 2020, 479:114343.
[9] Guo S, Wan Y, Chen X, et al. Loose nanofiltration membrane custom-tailored for resource recovery [J]. Chem Eng J, 2021, 409:127376.
[10] Metecan A, Cihano?lu A, Alsoy Altinkaya S. A positively charged loose nanofiltration membrane fabricated through complexing of alginate and polyethyleneimine with metal ions on the polyamideimide support for dye desalination [J]. Chem Eng J, 2021, 416:128946.
[11] Feng X, Peng D, Zhu J, et al. Recent advances of loose nanofiltration membranes for dye/salt separation [J]. Sep Purif Technol, 2022, 285:120228.
[12] Arribas P, García-Payo M C, Khayet M, et al. Improved antifouling performance of polyester thin film nanofiber composite membranes prepared by interfacial polymerization [J]. J Membr Sci, 2020, 598:117774.
[13] Cheng J, Shi W, Zhang L, et al. A novel polyester composite nanofiltration membrane formed by interfacial polymerization of pentaerythritol (PE) and trimesoyl chloride (TMC) [J]. Appl Surf Sci, 2017, 416:152-159.
[14] Seman M N A, Khayet M, Hilal N. Nanofiltration thin-film composite polyester polyethersulfone-based membranes prepared by interfacial polymerization [J]. J Membr Sci, 2010, 348(1):109-116.
[15] Cai W, Wang M, Yang G Q, et al. High-performance nanofiltration membranes with a polyamide-polyester composite layer and a polydopamine surface layer for desalination and dye pollutant removal [J]. Polymer, 2023, 268:125720.
[16] Waheed A, Baig U. Exploiting phase inversion for penta-amine impregnation of ultrafiltration support matrix for rapid fabrication of a hyper-cross-linked polyamide membrane for organic solvent nanofiltration [J]. Process Saf Environ Prot, 2023, 169:24-33.
[17] Wang S, Wang Z, Zhu S, et al. Highly porous ultrathin polyamide membranes for fast separation of small molecules from organic solvents [J]. J Membr Sci, 2023, 675:121540.
[18] Xie T, Chen K, Xie H, et al. Highly negatively charged nanofiltration membrane prepared with a novel diamino-sulfonamide aqueous monomer for efficient removal of anionic dyes [J]. Appl Surf Sci, 2022, 599:153914.
[19] Yang L, Zhang X, Ma W, et al. Trimethylamine N-oxide-derived zwitterionic polyamide thin-film composite nanofiltration membranes with enhanced anti-dye deposition ability for efficient dye separation and recovery [J]. J Membr Sci, 2023, 665:121083.
[20] Jin P, Zhu J, Yuan S, et al. Erythritol-based polyester loose nanofiltration membrane with fast water transport for efficient dye/salt separation [J]. Chem Eng J, 2021, 406:126796.
[21] He J, Wu H, Ni F, et al. Mechanistic insight into developing a novel loose nanofiltration membrane for effective dye/salt separation by epigallocatechin gallate [J]. Sep Purif Technol, 2023, 318:123983.
[22] Pei T, Deng M, Ma C, et al. Loose nanofiltration membranes based on interfacial glutaraldehyde-amine polymerization for fast and highly selective dye/salt separation [J]. Chem Eng J, 2022, 450:138057.
[23] Liu J, Hua D, Zhang Y, et al. Precise molecular sieving architectures with Janus pathways for both polar and nonpolar molecules [J]. Adv Mater, 2018, 30(11):1705933.
[24] Gao Q, Bouwen D, Yuan S, et al. Robust loose nanofiltration membrane with fast solute transfer for dye/salt separation [J]. J Membr Sci, 2023, 674:121518.
[25] Zhu J, Tian M, Zhang Y, et al. Fabrication of a novel “loose” nanofiltration membrane by facile blending with Chitosan–Montmorillonite nanosheets for dyes purification [J]. Chem Eng J, 2015, 265:184-193.
[26] Zhao S, Wang Z. A loose nano-filtration membrane prepared by coating HPAN UF membrane with modified PEI for dye reuse and desalination [J]. J Membr Sci, 2017, 524:214-224.
[27] Schaep J, Van der Bruggen B, Vandecasteele C, et al. Influence of ion size and charge in nanofiltration [J]. Sep Purif Technol, 1998, 14(1):155-162.
[28] Alventosa-deLara E, Barredo-Damas S, Zuriaga-Agustí E, et al. Ultrafiltration ceramic membrane performance during the treatment of model solutions containing dye and salt [J]. Sep Purif Technol, 2014, 129:96-105.
[29] Jin P, Chergaoui S, Zheng J, et al. Low-pressure highly permeable polyester loose nanofiltration membranes tailored by natural carbohydrates for effective dye/salt fractionation [J]. J Hazard Mater, 2022, 421:126716.
[30] 常国梁, 龚耿浩. 联苯酚基聚芳酯疏松纳滤膜的制备及其性能 [J]. 膜科学与技术, 2023, 43(1):74-82.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com