Analysis of the Development Trend of Helium Recovery from Natural Gas Technology Based on Incopat Patent Information |
Authors: Chao ZHANG, Peijun ZHENG, Pengfei FEI, Houyuan LU,Shuangjiang LUO |
Units: 1. National Science Library, Chinese Academy of Sciences, Beijing 100190, China 2. Department of Library Information and Archives Management, School of Economics and Management, University of the Chinese Academy of Sciences, Beijing 100190, China 3. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 4. School of Economics and Management, Shanxi University, Taiyuan Shanxi 030006, |
KeyWords: helium separation from natural gas; patent analysis; membrane separation |
ClassificationCode:TQ460.6+4 |
year,volume(issue):pagination: 2024,44(3):163-173 |
Abstract: |
Helium is a non renewable inert gas associated with natural gas, playing an irreplaceable role in fields such as high-temperature gas cooled reactors, nuclear magnetic resonance, semiconductor manufacturing, and large-scale scientific facilities. In recent years, the global consumption of helium has been increasing year by year, but the production capacity of helium cannot meet its consumption. Developing low-cost and high-efficiency natural gas helium extraction technology is of great significance. This article uses the Incopat global patent search and analysis system to accurately search for patent technologies related to natural gas helium extraction. It introduces the overall situation of patents in the field of helium separation and reveals key patents. The system summarizes and discusses the development trends of this technology. Through in-depth analysis of key patented technologies, it is found that China, the United States, Japan, Germany, and Russia have relatively high technological innovation capabilities and activity levels, and are the main holders of patents in this field. The top three helium extraction technologies are cryogenic method, membrane separation method, and multi technology coupling method. Membrane separation technology is a rapidly developing separation technology among key patents; This article focuses on the latest research progress of natural gas helium extraction membrane separation technology from two directions: membrane materials and membrane separation processes. Research has found that developing and designing cost-effective membrane processes, such as membrane separation and low-temperature technology coupling processes, for system integration and optimization, is key to further improving the economy of helium extraction. This article aims to reveal the global research and development trend of natural gas helium extraction technology, especially membrane separation helium technology, to help researchers accurately grasp research trends and provide support for scientific research institutions to formulate scientific policies and strategic plans. |
Funds: |
中国科学院文献情报建设能力建设专项资助:支撑产业链供应链自主可控的产业创新情报研究(E1291115);中国科学院稳定支持基础研究领域青年团队项目(YSBR-017) |
AuthorIntro: |
张 超(1982年-),博士,研究馆员,山东滨州人。主要研究方向为化工能源领域学科情报研究。 |
Reference: |
[1] 彭桂林, 龚 智, 章学华. 氦气提纯技术发展现状与应用分析[J]. 低温与超导, 2012, 40(6):4-7. [2] 王 露. 二维多孔材料分子筛的理论研究[D]. 山东: 山东大学, 2021. [3] 周军 , 陈玉麟, 王璿清, 等. 氦气资源产量及市场发展现状分析[J]. 天然气化工, 2022, 47(5):42-48. [4] 张 哲, 王春燕, 王秋晨, 等. 浅谈中国氦气供应链技术壁垒与发展方向[J]. 油气与新能源, 2022, 34(2):14-19. [5] 李长俊, 张财功, 贾文龙, 等. 天然气提氦技术开发进展[J]. 天然气化工 (C1化学与化工) , 2020, 45(4):108-116. [6] 河南大学郑州校区学术发展部, 中国科学院院士张锁江:突破核心技术 加速氦气国产化[EB/OL]. [2024-03-15]. https://xsfzb.henu.edu.cn/info/1053/1251.htm. [7] Soleimany A, Hosseini S S, Gallucci F. Recent progress in developments of membrane materials and modification techniques for high performance helium separation and recovery: A review[J]. Chem Eng Process, 2017, 6(1):296-318. [8] Hamedi H. An innovative integrated process for helium and NGL recovery and nitrogen removal[J]. Cryogenics, 2021, 113(11):103224. [9] Choi S S, Melhan M A, Abdulrahman A, et al. Preparation and characterization of multilayer thin-film composite hollow fiber membranes for helium extraction from its mixtures[J]. Sep. Purif. Technol., 2019, 222(1):152-161. [10] Choi S H, Qahtani M S, Qasem E A. Multilayer thin-film composite membranes for helium enrichment[J]. J. Membr. Sci., 2018, 553(1):180-188. [11] Air Prod Chem. Process for recovering helium from a multi-component gas stream[P]. 美国,专利,US4717407A.1986-06-16. [12] Nitrotec Corp. PEnhanced helium recovery[P]. 美国,专利,US08517469.1995-08-21. [13] Ube Industries. Method of preparing high purity light gas by multiple-step gas separation[P]. 美国,专利,US07199319.1988-05-26. [14] Costain Petrocarbon. Purification of helium [P]. 美国,专利,US06713572.1985-03-18. [15] 西安保埃罗环保科技有限公司. System for purifying helium from natural gas liquefied helium-containing tail gas[P]. 中国,专利,CN201920423931.2019-03-29. [16] 上海浦江特种气体有限公司. Ultrapure helium purification equipment[P]. 中国,专利,CN201120110987.4.2011-04-15. [17] Federal'noe Gosudarstvennoe Bjudzhetnoe Uchrezhdenie Natsional'nyj Issledovatel'skij Tsentr Kurchatovskij Institut. METHOD OF EXTRACTING HELIUM FROM NATURAL GAS[P]. 俄罗斯,专利,RU2478569C1.2011-11-16. [18] Shoji K, Moriya A. Method of producing high-purity helium[P]. 美国,专利,US10444052.2003-05-22. [19] 郑佩君, 谢 威, 白 菊, 等. 气体分离膜技术在天然气提氦中的研究进展[J]. 膜科学与技术, 2022, 42(6):168-177. [20] 栾永超, 熊亚林, 何广利, 等. 氢气分离膜研究进展[J]. 中国工程科学, 2022, 24(3):140-152. [21] 张丽萍, 巨永林. 天然气及液化天然气蒸发气提氦技术研究进展[J]. 天然气化工(C1化学与化工), 2022, 47(5):32-41. [22] Scholes C A, Ghosh U. Helium separation through polymeric membranes: selectivity targets[J]. J. Membr. Sci., 2016, 520(1):221-230. [23] None. Process Could Hit Helium Jackpot[J]. Chem.eng.news, 1958, 36(19):42. [24] Homa H, Iftekhar A K, Truls G. A novel cost-effective silica membrane based process for helium extraction from natural gas[J]. Comput. Chem. Eng., 2019, 121(2):633-638. [25] Pirouzfar V, Moghaddam A Z, Omidkhah M R, et al. Investigating the effect of dianhydride type and pyrolysis condition on the gas separation performance of membranes derived from blended polyimides through statistical analysis[J]. J. Ind. Eng. Chem., 2014, 20(3):1061-1070. [26] Hosseini S S, Omidkhah M R, Zarringhalam M A, et al. Enhancing the properties and gas separation performance of PBI–polyimides blend carbon molecular sieve membranes via optimization of the pyrolysis process[J]. Sep. Purif. Technol., 2014, 122(1):278-289. [27] Ash R, Barrer R M, Lowson R T. Diffusion of helium through a microporous carbon membrane[J]. Surf. Sci., 1970, 21(2):265-272. [28] Fu S, Sanders E S, Kulkarni S S, et al. Temperature dependence of gas transport and sorption in carbon molecular sieve membranes derived from four 6FDA based polyimides: Entropic selectivity evaluation[J]. Carbon, 2015, 95(1):995-1006. [29] Dai Z D, Deng J, He X Z, et al. Helium separation using membrane technology: Recent advances and perspectives[J]. Sep. Purif. Technol., 2021, 274(1):119044. [30] Lei L, Bai L, Lindbråthen A, et al. Carbon membranes for CO2 removal: Status and perspectives from materials to processes[J]. Chem. Eng. J., 2020, 401(1):126084. [31] Jiao Y, Wu Q, Xu W, et al. Coordination enhancement of hydrogen and helium recovery in polybenzimidazole-based carbon molecular sieve membranes[J]. Sep. Purif. Technol., 2023, 315(1):123691. [32] 李立博, 王 勇, 王小青, 等. 柔性金属有机骨架材料(MOFs)用于气体吸附分离[J]. 化工进展, 2016, 35(6):1794-1803. [33] 李成帅, 舒 震, 史德青, 等. 基于MOFs的混合基质膜在气体分离方面的研究进展[J]. 现代化工, 2021, 41(11):63-66. [34] 马英楠, 何兴艳, 唐少华, 等. MOFs/PEI混合基质膜的制备及CO2分离性能研究[J]. 化学工业与工程, 2023, 40(3):84-95. [35] 高逸飞, 易 群, 齐 凯, 等. MOFs基膜材料的研究现状及其在H2/CH4分离中的应用[J]. 化工进展, 2022, 41(12):6395-6407. [36] 牛照栋, 张德华, 孟凡凡, 等. 锆基金属有机骨架材料的合成及其对CO2/N2的吸附与分离性能研究[J]. 化工新型材料, 2018, 46(10):123-125+129. [37] Yoo B M, Shin J E, Lee H D, et al. Graphene and graphene oxide membranes for gas separation applications[J]. Current Opinion in Chemical Engineering, 2017, 16(1):39-47. [38] Chen C, Ozcan A, Yazaydin A O, et al. Gas permeation through single-crystal ZIF-8 membranes[J]. J. Membr. Sci., 2019, 575(1):209-216. [39] Comesana-Gandara B, Chen J, Bezzu C G, et al. Redefining the Robeson upper bounds for CO2/CH4 and CO2/N2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity[J]. Energy Environ. Sci., 2019, 12(9):2733-2740. [40] Hsiao S H, Lin K H. A comparative study on the properties of aromatic polyamides with methyl-or trifluoromethylsubstituted triphenylamine groups[J]. J Fluorine Chem., 2016, 188:33-42. [41] 卢衍波. 膜法天然气提氦技术研究进展[J]. 石油化工, 2020, 49(5):513-518. [42] Jiao Y, Liu M, Qi W, et al. Finely tuning the microporosity in phosphoric acid doped triptycene-containing polybenzimidazole membranes for highly permselective helium and hydrogen recovery[J]. J. Membr. Sci., 2023, 672:121474. [43] Yavari M, Fang M, Nguyen H, et al. Dioxolane-Based Perfluoropolymers with Superior Membrane Gas Separation Properties[J]. Macromolecules, 2018, 51(7):2489-2497. [44] Galizia M, Chi W S, Smith Z P, et al. 50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities[J]. Macromolecules, 2017, 50(20):7809-7843. [45] 俞江南, 李 康, 陈 飞, 等. 面向CO2分离的混合基质膜研究进展[J]. 化学工业与工程, 2023, 40(3):74-83. [46] Molavi H, Shojaei A, Mousavi A. Improving Mixed-Matrix Membrane Performance Via PMMA Grafting From Functionalized NH2-UiO-66[J]. J. Mater. Chem. A, 2018, 6(6):2775–2791. [47]丁佰锁, 刘华丽, 彭 婷. 一种用于天然气中提取氦气的混合基质MOF膜的制备方法和产品[P]. 中国,专利,CN116351253A.2023-06-30. [48] Quader M A, Thomas E R, Simon S. Modeling and cost analysis of helium recovery using combined-membrane process configurations[J]. Sep. Purif. Technol., 2020, 236 (1):116269. [49] Scholes C A., Ghosh U K. Review of Membranes for Helium Separation and Purification[J]. Membranes, 2017, 7(1):9. [50] Quader M A, Simon S, Thomas E R. Techno-economic evaluation of multistage membrane combinations using three different materials to recover helium from natural gas[J] Comput. Aided Chem. Eng., 2018, 44(1):1201-1206. [51] He X, Hägg M B, Kim T J. Hybrid FSC membrane for CO2 removal from natural gas: Experimental, process simulation, and economic feasibility analysis[J]. AiChE J., 2015, 60(12):4174-4184. [52] 巴斯特, 温格兰克,·维尔瑟恩. 分离气体的方法[P]. 奥地利,专利,CN104023821A.2014-09-03. [53] Quader M A, Rufford T E, Smart S. Integration of hybrid membrane-distillation processes to recover helium from pre-treated natural gas in liquefied natural gas plants[J]. Sep. Purif. Technol., 2021, 263(1):118355. [54] 徐 鹏, 熊联友, 赵光明, 等. 一种氨气生产系统和生产方法[P]. 中国,专利,CN109631494AIP1.2019-04-16. |
Service: |
【Download】【Collect】 |
《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com
京公网安备11011302000819号