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Structure and properties of bisphenol S copoly(phthalazinone ether sulfone) hollow fiber membrane

Authors： LI Chao, XU Peiqi, LYU Fei, WANG Xukun, FENG Huimei, LI Hailong, ZHANG Shouhai, JIAN Xigao

Units： College of chemical engineering, Dalian University of Technology, Liaoning High Performance Polymer Engineering Research Center, Liaoning Key Laboratory of Polymer Science and Engineering, Dalian Key Laboratory of Membrane Materials and Process

KeyWords： bisphenol S copoly(phthalazinone ether sulfone); drywet phase inversion; structure and performance

ClassificationCode：TQ326.6

year,volume(issue):pagination： 2024,44(5):75-81

Abstract：

The hollow fiber membrane was prepared by drywet phase conversion method with bisphenol S copoly(phthalazinone ether sulfone) as the membrane material and polyethylene glycol (PEG2000) as the additive. The relationship between polymer content, additive content, drafting rate, air gap distance and bore fluid composition on membrane structure and property were investigated. SEM was used to observe the microscopic morphology of hollow fiber membranes, and its properties were studied. The results showed that an increase in polymer concentration and additive content would lead to an increase in the apparent viscosity of the casting solution, a gradual increase in the proportion of sponge pores, and a decrease in water flux. The increase in takeup speed and air gap distance leads to a decreasing trend in the water flux of the membrane. When the drafting rate is 9 m/min and the air gap distance is 10 cm, the membrane has good separation performance, with a water flux of 106 L/(m2·h), a bovine serum albumin（BSA） retention rate of 99.8%, and a clearance rate of 52.4% for urea.

Funds：

大连市高层次人才创新支持计划(2019RD08)

AuthorIntro：

李潮（1998-），男，山东省青岛市人，硕士生，从事血液透析中空纤维膜的制备.*通讯作者，E-mail：zhangshh@dlut.edu.cn

Reference：

［1］Radu E, Voicu S. Functionalized hemodialysis polysulfone membranes with improved hemocompatibility\[J\]. Polymers, 2022, 6(14):1130.
\[2\]胡晓宇, 肖长发. 熔融纺丝制备中空纤维膜研究进展\[J\]. 高分子通报, 2008, 1(6):1-7.
\[3\]Kim J, Jang T, Kwon Y, et al. Structural study of microporous polypropylene hollow fiber membranes made by the meltspinning and coldstretching method\[J\]. J Membr Sci, 1994, 93(3):209-215.
\[4\]Zhao J, Shi L, Loh C, et al. Preparation of PVDF/PTFE hollow fiber membranes for direct contact membrane distillation via thermally induced phase separation method\[J\]. Desalination, 2018, 430:86-97.
\[5\]Lin Y, Chen G, Yang J, et al. Formation of isotactic polypropylene membranes with bicontinuous structure and good strength via thermally induced phase separation method\[J\]. Desalination, 2009, 236(1/2/3):8-15.
\[6\]Ataka M, Sasaki K. Gravimetric analysis of membrane casting: I. Cellulose acetateacetone binary casting solutions\[J\]. J Membr Sci, 1982, 11(1):11-25.
\[7\]Ohno S, Nakata I, Nagumo R, et al. Development of lowfouling PVDF membranes blended with poly(2-methoxyethyl acrylate) via NIPS process\[J\]. Sep Purif Technol, 2021, 276:119331.
\[8\]Kong X, Lu X, Ren K. Towards highperformance polysulfone membranes: A controllable membrane formation process using surfactant in NIPS\[J\]. J Taiwan Inst Chem Eng, 2021, 129:171-179.
\[9\]Jia J, Liang F, Zhang X, et al. Advancement in separation materials for blood purification therapy\[J\]. Chin J Chem Eng, 2019, 27(6):1383-1390.
\[10\]Zhang P Y, Wang Y L, Xu Z L, et al. Preparation of poly(vinyl butyral) hollow fiber ultrafiltration membrane wetspinning method using PVP as additive\[J\]. Desalination, 2011, 278:186-193.
\[11\]Huang Z Y, Liu J H, Xu Y C, et al. Enhanced permeability and antifouling performance of polyether sulfone (PES) membrane via elevating magnetic Ni@MXene nanoparticles to upper layer in phase inversion process\[J\]. J Membr Sci, 2021, 623:119080.
\[12\]袁国栋. 聚乙烯吡咯烷酮性质及其在血液透析膜中的作用\[J\]. 河南化工, 2023, 40(6):13-17.
\[13\]Kin J Y, Lee H K, Kin S C. Surface structure and phase separation mechanism of polysulfone membranes by atomic force microscopy\[J\]. J Membr Sci, 2019, 163:159-166.
\[14\]翟腾波. 高性能聚砜中空纤维膜的制备及性能研究\[D\]. 天津:天津工业大学, 2017.
\[15\]沈诗雨, 赵东, 袁彬瑞,等. 制备工艺对聚醚砜中空纤维膜外表面孔结构的影响\[J\]. 工程塑料应用, 2023, 51(8):57-65.
\[16\]Han M J, Nam S T. Thermodynamic and rheological variation in polysulfone solution by PVP and its effect in the preparation of phase inversion membrane\[J\]. J Membr Sci, 2002, 202(1/2):55-61.
\[17\]Khulbe K C, Feng C Y, Matsuura T, et al. Characterization of surfacemodified hollow fiber polyethersulfone membranes prepared at different air gaps\[J\]. J Appl Polym Sci, 2007, 104(2):710-721.
\[18\]Ju J, Liang F, Zhang X, et al. Advancement in separation materials for blood purification therapy\[J\]. Chin J Chem Eng, 2019, 27(6):1383-1390.
\[19\]张瑛楠, 王旭, 徐培琦,等. 双酚S型杂萘联苯共聚醚砜膜材料的合成与性能研究\[J\]. 膜科学与技术, 2023, 43(5):37-43.
\[20\]张瑛楠. 双酚S型杂萘联苯共聚醚砜中空纤维膜的研制\[D\]. 大连：大连理工大学, 2023.
\[21\]王旭. 杂萘联苯共聚醚砜血液透析膜的研制与性能\[D\]. 大连：大连理工大学, 2022.
\[22\]王萍, 申向, 赵义平,等. 卷绕PVDFgP速度对NIPAAm/PVDF中空纤维膜的影响研究\[C\]//中国功能材料及其应用学术会议. 中国仪表功能材料学会, 2010.

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