Position:Home >> Abstract

Study on preparation and seawater desalination performance of
biomass-based mixed hydrogel evaporation membrane
Authors: QIU Chunxia, WANG Siwen, XU Yuanlu, LIU Yu, FAN Xinfei, SONG Chengwen
Units: 1.Transport Planning and Research Institute Ministry of Transport, Beijing 100028,China; 2. School of Environmental Science and Engineering, Dalian Maritime University, Dalian 116026,China; 3. Guotou Caofeidian Port Co., Ltd., Tangshan 063200,China
KeyWords: biomass; solar interfacial evaporation; hydrogel; seawater desalination
ClassificationCode:TQ427.2+6;TK519
year,volume(issue):pagination: 2025,45(6):80-90

Abstract:
 Due to the increasingly serious freshwater crisis caused by the continuous growth of the population, solar-driven interfacial evaporation, as a green, low-energy consumption and environmentally friendly seawater desalination technology, has become a research hotspot for achieving the increase of freshwater sources. In this study, based on a simple gelatinization-freeze-thaw process, biomass-based mixed hydrogel [octopus ink@ polyvinyl alcohol (PVA) hydrogel] solar evaporation membrane was prepared for efficient solar-driven interfacial evaporation. The physical properties such as the microscopic morphology, structural characteristics, wetting performance and photothermal performance of the evaporation membrane were systematically studied, and a comprehensive assessment of its application prospects in the field of seawater desalination was conducted. The research results showed that the superhydrophilicity and the porous water delivery channels formed by freeze-thaw cycling acted synergistically to ensure the excellent water supply capacity of the evaporation membrane. Under the standard solar radiation intensity, the evaporation rate could reach 2.49 kg/(m2·h), and the corresponding photothermal conversion efficiency was approximately 86.58%. Furthermore, the prepared evaporation membrane demonstrated high salt tolerance. The evaporation rate could still reach 1.33  kg/(m2·h) in 15% brine concentration, and it had excellent self-cleaning ability. Moreover, it showed good desalination performance in outdoor seawater desalination experiments. The ion concentrations of Na+, K+, Mg2+ and Ca2+ in the collected condensate all met the drinking water standards of the World Health Organization, indicating that it has broad application prospects in the field of seawater desalination. 
 

Funds:
国家重点研发计划项目(2023YFC3108300)

AuthorIntro:
邱春霞(1979-),女,辽宁东港人,硕士研究生,研究方向为油污水膜分离技术水处理.

Reference:
 [1] Xu Z R, Li Z, Jiang Y, et al. Recent advances in solar-driven evaporation systems[J]. J Mater Chem A, 2020, 8(48): 25571-25600.
[2]Lyu B W, Gao C, Xu Y L, et al. A self-floating, salt-resistant 3D Janus radish-based evaporator for highly efficient solar desalination[J]. Desalination, 2021, 510: 115093.
[3]Xu C, Yang Q, Wang F, et al. Research progress on novel solar steam generation system based on black nanomaterials[J]. Can J Chem Eng, 2018, 96(10): 2086-2099. 
[4]Xu Y L, Mu H C, Han X S, et al. A simple, flexible, and porous polypyrrole-wax gourd evaporator with excellent light absorption for efficient solar steam generation[J]. Int J Energy Res, 2021, 45(15): 21476-21486.
[5]Zang L L, Finnerty C, Zheng S X, et al. Interfacial solar vapor generation for desalination and brine treatment: evaluating current strategies of solving scaling[J]. Water Res, 2021, 198(13): 117135.
[6]Chen C J, Kuang Y D, Hu L B. Challenges and opportunities for solar evaporation[J]. Joule, 2019, 3(3): 683-718.
[7]Zhou X Y, Zhao F, Zhang P P, et al. Solar water evaporation toward water purification and beyond[J]. ACS Mater Lett, 2021, 3(8): 1112-1129.
[8]Margeson M J, Dasog M. Plasmonic metal nitrides for solar-driven water evaporation[J]. Environ Sci: Water Res Technol, 2020, 6(12): 3169-3177.
[9]Yu Y, Ming X, Xu Y, et al. Quasimetallic molybdenum carbide-based flexible polyvinyl alcohol hydrogels for enhancing solar water evaporation[J]. Adv Mater Interfaces, 2019, 6(24): 1901168.
[10]He W, Zhou L, Wang M, et al. Structure development of carbon-based solar-driven water evaporation systems[J]. Sci Bull, 2021, 66(14): 1472-1483.
[11]Yang J, Chen Y, Jia X, et al. Wood-based solar interface evaporation device with self-desalting and high antibacterial activity for efficient solar steam generation[J]. ACS Appl Mater Interfaces, 2020, 12(41): 47029-47037.
[12]Ying P J, Li M, Yu F L, et al. Bandgap engineering in efficient solar-driven interfacial evaporation system[J]. ACS Appl Mater Interfaces, 2020, 12: 32880-32887.
[13]Ai S, Ma M, Chen Y Z, et al. Metal-ceramic carbide integrated solar-driven evaporation device based on ZrC nanoparticles for water evaporation and desalination[J]. Chem Eng J, 2021, 429: 132014.
[14]Lu Y, Wang X, Fan D Q, et al. Biomass derived Janus solar evaporator for synergic water evaporation and purification[J]. Sustain Mater Technol, 2020, 25: e00180.
[15]Zhou X, Li J Y, Liu C, et al. Carbonized tofu as photothermal material for highly efficient solar steam generation[J]. Int J Energy Res, 2020, 44(11): 9213-9221.
[16]Liu C, Hong K W, Sun X, et al. An “antifouling” porous loofah sponge with internal microchannels as solar absorbers and water pumpers for thermal desalination[J]. J Mater Chem A, 2020, 8: 12323-12333.
[17]Lu H Y, Shi W, Zhao F, et al. High-yield and low-cost solar water purification via hydrogel-based membrane distillation[J]. Adv Funct Mater, 2021, 31(19): 2101036.
[18]Zhou X Y, Guo Y H, Zhao F, et al. Hydrogels as an emerging material platform for solar water purification[J]. Acc Chem Res, 2019, 52(11): 3244-3253.
[19]Xu Y L, Lyu B W, Yang Y, et al. Facile fabrication of low-cost starch-based biohydrogel evaporator for efficient solar steam generation[J]. Desalination, 2021, 517: 115260.
[20]Yang M, Luo H, Zou W Z, et al. Ultrafast solar-vapor harvesting based on a hierarchical porous hydrogel with wettability contrast and tailored water states[J]. ACS Appl Mater Interfaces, 2022, 14(21): 24766-24774.
[21]Lin X L, Wang P, Hong R T, et al. Fully lignocellulosic biomass-based double-layered porous hydrogel for efficient solar steam generation[J]. Adv Funct Mater, 2022, 32(51): 2209262.
[22]Dong W C, Zhou F F, Song X J, et al. Coffee grounds-based hydrogel as a high-performance and durable evaporator for solar-driven freshwater generation[J]. Mater Today Energy, 2022, 30: 101187.
[23]Traver E, Karaballi R A, Monfared Y E, et al. TiN, ZrN, and HfN nanoparticles on nanoporous aluminum oxide membranes for solar-driven water evaporation and desalination[J]. ACS Appl Nano Mater, 2020,  3: 2787-2794.
 

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号