Preparation and Performance of TFC-FO membranes prepared on different support layers |
Authors: HU Lele, WANG Duo,WANG Meng |
Units: (College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China) |
KeyWords: Forward osmosis membrane;TFC membrane;substrate;structural parameter |
ClassificationCode:TQ028.8 |
year,volume(issue):pagination: 2017,37(2):19-25 |
Abstract: |
[1] 张乾, 时强, 阮国玲, 等. 正渗透水处理关键技术研究进展[J]. 工业水处理, 2012, 32(5):5-9. [2] Robert L M, Menachem E. Energy requirements of ammonia-carbon dioxide forward osmosis desalination[J]. Desalination, 2007, 207: 370-382. [3] Martinetti C R, Childress A E, Cath T Y. High recovery of concentrated RO brines using forward osmosis and membrane distillation[J]. J Membr Sci, 2009, 331: 31–39. [4] Tang W L, Ng H Y. Concentration of brine by forward osmosis: performance and influence of membrane structure[J]. Desalination, 2008, 224: 143-153. [5] Comelissen E R, Harmsen D,de Korte K F,et al.Membrane fouling and process performance of forward osmosis membranes on activated sludge[J]. J Membr Sci, 2008, 319(1-2): 158-168. [6] Garg A, Gupta M, Bhargava H N. Effect of formulation parameters on the release characteristics of propranolol from asymmetric membrane coated tablets[J]. European Jounral of Pharmaceutics and Biopharmaceutics, 2007, 67 (3): 725-731. [7] Su Y C, Lin L A. Water-powered micro drug delivery system[J]. Journal of Microelectromech System, 2004, 13: 75-82. [8] Herron J R, Beaudry E G, Jochums C E, et al. Apparatus for direct osmotic concentration of fruit juices[P]. US: 5281230, 1994. [9] Emadzadeh D, Lau W J, Matsuura T, et al. Synthesis and characterization of thin film nanocomposite forward osmosis membrane with hydrophilic nanocomposite support to reduce internal concentration polarization[J]. J Membr Sci, 2014, 449: 74-85. [10] Ma Ning, Wei Jing, Liao Rihong, et al. Zeolite-polyamide thin film nanocomposite membranes: Towards enhanced performance for forward osmosis[J]. J Membr Sci, 2012, 405-406:149-157. [11] Ma Ning, Wei Jing, Qi Saren, et al. Nanocomposite substrates for controlling internal concentration polarization in forward osmosis membranes[J]. J Membr Sci, 2013, 441: 54-62. [12] Emadzadeh D, Lau W J, Matsuura T, et al. The potential of thin film nanocomposite membrane in reducing organic fouling in forward osmosis process[J]. Desalination, 2014, 348: 82-88. [13] Xiao Peipei, Nghiem L D, Yin Y, et al. A sacricial-layer approach to fabricate polysulfone support for forward osmosis thin-film composite membranes with reduced internal concentration polarization[J]. J Membr Sci, 2015, 481:106-114. [14] Xiao Liu, Ng H Y. Fabrication of layered silica-polysulfone mixed matrix substrate membrane for enhancing performance of thin-film composite forward osmosis membrane[J]. J Membr Sci, 2015, 481: 148-163. [15] Su J C, Chung T S, Helmer B J, et al. Enhanced double-skinned FO membranes with inner dense layer for wastewater treatment and macromolecule recycle using Sucrose as draw solute[J]. J Membr Sci, 2012, 396: 92-100. [16] 肖佩佩, 殷勇, 宋健峰, 等. 界面聚合正渗透膜结构参数调控[J]. 膜科学与技术, 2014, 34(5):40-43. [17] Gordon T G, Jeffrey R M, Menachem E. Internal concentration polarization in forward osmosis: role of membrane orientation[J]. Desalination, 2006, 197:1-8. [18] Phillip W A, Yong J S, Elimelech M. Reverse draw solute permeation in forward osmosis: modeling and experiments[J]. Environmental Science and Technology, 2011, 44:5170-5176. [19] Widjojo N, Chung T S, Weber M, et al. The role of sulphonated polymer and macrovoid-free structure in the support layer for thin-film composite (TFC) forward osmosis (FO) membranes[J]. J Membr Sci, 2011, 383:214-223. [20] Thorsen T, Holt T, The potential for power production from salinity gradients by pressure retarded osmosis[J]. J Membr Sci, 2009, 335:103-110. |
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The structural parameter of the membrane is an important standard to measure the internal concentration polarization in forward osmosis process. In this paper, the impacts of different substrates on the porous structure of the polysulfone support layer and the performance of TFC-FO membranes formed on different support layers were investigated. Results showed that the hydrophilicity and the porous structure of the substrate are two important factors which influence the structure of the polysulfone support layer. Further more, the porous substrate exhibits better performance in improving the bottom surface porosity and the permeability of finger-like pore in the middle. The FO Membrane prepared on the support layer, which is cast on the porous substrate, shows an excellent flux of 38.6 L?m-2?h-1 and a reverse salt flux of 8.0 g?m-2?h-1 under FO mode for 1mol?L-1 NaCl draw solution from a de-ionized water feed solution. Compared with the traditional TFC-FO membrane when glass plate is used as the casting substrate, the structural parameter (S) of the membrane decreased from 386.0μm to 172.5μm. |
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