膜科学与技术

Position：Home >> Abstract

Preparation and Pb2+-Detection Performance of Composite Membranes Based on Smart Microspheres

Authors： YAN Peijie, WANG Wei, XIE Rui, JU Xiaojie, LIU Zhuang, CHU Liangyin

Units： School of Chemical Engineering，Sichuan University

KeyWords： Smart composite membrane; Trace signal detection; Smart microsphere; Pb2+; Crown ether

ClassificationCode：TQ317

year,volume(issue):pagination： 2018,38(4):1-7

Abstract：

A novel type of smart-microsphere-based nylon-6/polyethersulfone membrane is developed by incorporating Pb2+-responsive poly(N-isopropylacrylamide-co-benzo-18-crown-6- acrylamide) microspheres in the membrane pores for highly-sensitive detection of trace Pb2+. The morphology, structure and Pb2+-responsive property of the microspheres are systematically investigated. The results show that the microspheres can exhibit the best Pb2+-responsive property at 37 oC. Meanwhile, the morphology, structure and Pb2+-detection performance of the smart-microsphere-based membrane are systematically studied. The results show that the Pb2+-detection limit of the membrane can be as low as 10-7 M, lower than the standard of Pb2+ for industrial wastewater indicating highly-sensitive Pb2+-detection. This work provides new opportunities for fabricating novel highly-sensitive Pb2+-detection systems.

Funds：

国家自然科学基金项目（21490582）、教育部创新团队发展计划滚动支持项目（IRT_15R48）

AuthorIntro：

第一作者介绍：颜培洁（1992-），女，山东泰安人，硕士研究生，主要研究方向为化工新技术，E-mail：415999369@qq.com. *通讯作者，E-mail：wangwei512@scu.edu.cn

Reference：

[1] 胡昌军, 张爱华. 生活中的铅污染及其防制对策[J]. 环境与职业医学, 2005, 22(3):283-284.
[2] F. Huber, H.P. Lang, N. Backmann, et al. Direct detection of a BRAF mutation in total RNA from melanoma cells using cantilever arrays[J]. Nature Nanotechnology, 2013, 8(2):125-129.
[3] P.M. Kosaka, V. Pini, J.J. Ruz, et al. Detection of cancer biomarkers in serum using a hybrid mechanical and optoplasmonic nanosensor[J]. Nature Nanotechnology, 2014, 9(12):1047-1053.
[4] L. Marbella, B. Serli-Mitasev, P. Basu. Development of a fluorescent Pb2+ sensor[J]. Angewandte Chemie International Edition, 2009, 48(22):3996-3998.
[5] 邬智高. 近年来水中铅离子的检测方法及研究进展[J]. 沿海企业与科技, 2011, 4:24-26.
[6] 沈新元. 智能高分子材料[J]. 现代化工, 2004, 24(3): 64-65.
[7] K. Liu, H.F. Ji. Detection of Pb2+ using a hydrogel swelling microcantilever sensor[J]. Analytical Sciences, 2004, 75(18):9-11.
[8] C.E. Reese, S.A. Asher. Photonic crystal optrode sensor for detection of Pb2+ in high ionic strength environments[J]. Analytical Chemistry, 2003, 75(15):3915-3918.
[9] X. Wang, G. Ye, X. Wang. Hydrogel diffraction gratings functionalized with crown ether for heavy metal ion detection[J]. Sensors and Actuators B: Chemical, 2014, 193(193):413-419.
[10] S. Lin, W. Wang, X.J. Ju, et al. Ultrasensitive microchip based on smart microgel for real-time online detection of trace threat analytes[J]. Proceedings of the National Academy of Sciences of the United States of America, 2016, 113(8):2023-2028.
[11] Z. Liu, W. Wang, R. Xie, et al. Stimuli-responsive smart gating membranes[J]. Chemical Society Reviews, 2016, 45(3):460-475.
[12] Y. Okahata, K. Ozaki, T. Seki. pH-Sensitive permeability control of polymer-grafted nylon capsule membranes[J]. Journal of the Chemical Society Chemical Communications, 1984, 8(8):519-521.
[13] L.Y. Chu. Smart membrane materials and systems[M]// Hangzhou: Zhejiang University Press: Springer, 2011, 27:1069-1072.
[14] F. Luo, R. Xie, Z. Liu, et al. Smart gating membranes with in situ self-assembled responsive nanogels as functional gates[J]. Scientific Reports, 2015, 5:14708-14721.
[15] Z. Liu, F. Luo, X. J. Ju, et al. Gating membranes for water treatment: detection and removal of trace Pb2+ ions based on molecular recognition and polymer phase transition[J]. Journal of Materials Chemistry A, 2013, 1(34):9659-9671.
[16] Q. Luo, Y. Guan, Y. Zhang, et al. Lead-sensitive PNIPAM microgels modified with crown ether groups[J]. Journal of Polymer Science Part A Polymer Chemistry, 2010, 48(18):4120-4127.
[17] P. Mi, L.Y. Chu, X.J. Ju, et al. A smart polymer with ion-induced negative shift of the lower critical solution temperature for phase transition[J]. Macromolecular Rapid Communications, 2008, 29(1):27-32.
[18] B. Zhang, X.J. Ju, R. Xie, et al. Comprehensive effects of metal ions on responsive characteristics of P(NIPAM-co-B18C6Am)[J]. Journal of Physical Chemistry B, 2012, 116(18):5527-5536.
[19] Takeda Y, Tanaka M, Yamada H, et al. Stabilities and Transfer Activity Coefficients from Water to Polar Nonaqueous Solvents of Benzo-15-Crown-5- and 15-Crown-5-Alkali Metal Ion Complexes[J]. Journal of Coordination Chemistry, 2002, 55(4):459-468.
[20] Ju X J, Zhang S B, Zhou M Y, et al. Novel heavy-metal adsorption material: ion-recognition P(NIPAM-co-BCAm) hydrogels for removal of lead(II) ions[J]. Journal of Hazardous Materials, 2009, 167(1-3):114.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com