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离子液体支撑液膜用于有机物分离的研究进展

作者：丁少杰，郭亚红，滕一万，金凯洪，樊文玲，李磊，吴有庭

单位： a南京大学化学化工学院化工系，江苏南京 210093; b 南京中医药大学药学院，江苏南京 210029

关键词：离子液体;支撑液膜;有机物分离

DOI号：

分类号：

出版年,卷(期):页码： 2010,30(6):0-0

摘要：

摘要：离子液体支撑液膜传质速率高，选择性好，稳定性高，在有机物分离中具有独特的优势。本文总结了离子液体作为膜液相的优点，介绍了离子液体支撑液膜材料的选择，制备以及在有机物分离中的应用，分析了影响离子液体支撑液膜稳定性的因素，展望了其工业化前景。

Abstract：Supported ionic liquid membrane (SILM) technology has been used widely for separating organic mixtures with the particular advantage of high flux, selectivity and stability. The excellencies of ionic liquids as liquid phase in SILM are concluded. The selection of material for SILM and the preparation methods of SILM are introduced. The application of SILM is also reviewed. Besides, the factors leading to the instability of SILM are analyzed. Furthermore, the prospects for the commercialization of SILM are presented.

基金项目：

国家自然科学基金面上项目（20776065,30801552）；江苏省自然科学基金项目（BK2008275）。

作者简介：

丁少杰(1984-），女，硕士研究生，主要研究方向为膜分离，籍贯山西。

参考文献：

参考文献
    [1]    Alguacil F J. Facilitated transport and separation of manganese and cobalt by a supported liquid membrane using DP-8R as a carrier mobile [J].Hydrometallurgy，2002，65(1)：9-14.
    [2]    Qin Y J，Sheth J P，Sirkar K K. Supported liquid membrane-based pervaporation for VOC removal from water[J].Engineering Chemistry Research，2002，41(1)：3413-3428.
    [3]    Ishizu H，Habaki H，Kawasaki J. Permeation and concentration of compacting by a li-quid membrane technique[J].Membrane Science，2003，213(1)：209-219.
    [4]    黄蓓，杨立荣，吴坚平.手性拆分技术的工业应用[J].化工进展，2002，21(6)：375-380.
    [5]    Bao C Z，Gozzelino G，Baldi G. State of art of the research on supported liquid me-mbranes[J].Membrane Science and Technology，2000，20(6)：46-54.
    [6]    邓友全.离子液体：性质、制备和应用[M].北京：中国石化出版社，2006.
    [7]    Rogers R D，Huddl Eston J G，Wilauer H D. Room temperature ionic liquids as novel media for clean liquid-liquid extraction [J].Chemical Communication，1998，21(8)：1765-1766.
    [8]    李闲，张锁江，张建敏，等.疏水性离子液体用于萃取酚类物质[J].过程工程学报，2005，2(5)：148-151.
    [9]    范洪富，王达，马军，等.用离子液体[bmim]PF6和[emim]Beti萃取水中的氯酚[J].大庆石油学院学报，2007，31(6)：68-70.
[10]    Matsumoto M，Inomoto Y，Kondo K. Selective separation of aromatic hydrocarbons t-hrough supported liquid membranes based on ionic liquids[J].Journal of Membrane Sci-ence，2005，246(1)：77-81.
[11]    Luis C，Branco，Joao G. Studies on the selective transport of organic compounds by using ionic liquids as novel supported liquid membranes [J].Chemistry-A European Journal，2002，8(1)：3865-3869.
[12]    de los Ríos A P，Hernández-Fernández F J，Presa H，et al. Tailoring supported ionic liquid membranes for the selective separation of transesterification reaction compounds [J]. Journal of Membrane Science，2009，328(1)：81–85.
[13]    曾昭容，吴峰，林佳，等.离子液体支撑液膜用于苯/环己烷体系分离研究[J].天津工业大学学报，2008，8(4)：1-3.
[14]    de los Ríos A P，Hernández-Fernández F J，Tomás-Alonso F，et al. On the importan-ce of the nature of the ionic liquids in the selective simultaneous separation of the su-bstrates and products of a transesterification reaction through supported ionic liquid me-mbranes[J].Journal of Membrane Science，2008，307(2) ：233-238.
[15]    Hernández-Fernández F J，de los Ríos A P，Tomás-Alonso F，et al. On the development of an integrated membrane process with ionic liquids for the kinetic resolution of rac-2-pentanol [J]. Journal of Membrane Science，2008，314 (1)：238–246.
[16]    Matsumoto M，Inomoto Y，Kondo K. Selective separation of aromatic hydrocarbons through supported liquid membranes based on ionic liquids[J].Journal of Membrane Science，2005，246(1)：77-81.
[17]    Peng Jin-feng，Liu Jing-fu，Hu Xia-Lin，et al. Direct determination of chlorophenols in environmental water samples by hollow fiber supported ionic liquid membrane extraction coupled with high performance liquid chromatography[J].Journal of Chromatography，2007，1139(2)：165-170.
[18]    Krull F F，Medved M，Melin T. Novel supported ionic liquid membranes for simultaneous homogeneously catalyzed reaction and vapor separation[J].Chemical Engineering Science，2007，62 (10)：5579-5585.
[19]    Gan Quan，Rooney D，Zou Y. Supported ionic liquid membranes in nanopore structure for gas separation and transport studies[J].Desalination，2006，199(1/2/3)：535-537
[20]    Izák P，Ruth W，Fei Zhaofu，et al. Selective removal of acetone and bu-tan-1-ol from water with supported ionic liquid-polydimethylsiloxane membrane by pervaporation [J].ChemicalEngineering Journal，2007，139(2)：318-321.
[21] Bonne U，Deetz A W，Lai J H，et al. Membrane dehumidification[P]. US，Honeywell Inc.，4 915 838 .1990.
[22] Cull SG，Holbrey JD，Seddon KR，et al .Room temperature ionic liquids as replacements for organic solvents in multiphase bioprocess operations[J].Biotechnology And Bioengineering，2000，69(2)：227-233.
[23]王明玺，王保国，赵洪，等.支撑液膜蒸汽渗透法分离甲苯/环己烷[J].石油化工，2004，33(8)：747-751.
[24] Hernández-Fernández F J，de los Ríos A P，Tomás-Alonso F，et al. Preparation of supported ionic liquid membranes: Influence of the ionic liquid immobilization method on their operational stability [J]. Journal of Membrane Science，2009，341(1)：172-177.
[25] 王彩玲，张立志, 支撑液膜稳定性研究进展[J].化工进展，2007，26(7)：949-950.
[26]de los Ríos A P，Hernández-Fernández F J，Tomás-Alonso F，et al. Stability studies of supported liquid membranes based on ionic liquids：Effect of surrounding phase nature [J].Desalination，2009，245 (1)：776-782.
[27] Fortunato R，Afonso C A M，Benavente J，et al.Stability of supported ionic liquid membranesas studied by X-ray photoelectron spectroscopy[J].Journal of Membrane Science，2005，256(1/2)：216-223.
[28] Akira Ito，Shuhong Duan，Yoshiaki Ikenori，et al.Permeation of wet CO2/CH4 mixed gasthrough a liquid membrane supported of a hydrophobic microporous membrane[J].Seperation and purification Technology，2001，24(1):235-242.
[29] Shuhong Duan，Akira Ito，Akira Ohkawa，et al.Seperation of Propylene/Propane mixture by a supported liquid membrane containing triethylene
glycoland a silver sait[J].Membrane Science，2003，215(1)：53-60.
[30] 金美芳，Strathmann H.复合支撑液膜[J].水处理技术，2000，26(1)：18-21.
[31] 易涛，严纯华，李标国.平板夹芯型支撑液膜萃取体系中La3+迁移行为[J].中国稀土学报1995，13(3)：197-200.
[32] 杜启云，易涛，朱国斌.几种新型的支撑液膜组件的结构型式[J].水处理技术，1995，21(5)：249-251.
[33] 朱国斌，李国标.中空纤维管夹心型支撑液膜萃取体系中La(Ⅲ)的迁移行为[J].中国稀土学报，1995，13(4)：303-307.
[34]王捷，张宏伟，贾辉.浸没式中空纤维膜组件的优化和设计[J].膜科学与技术，200727(8)：83-87.
[35] 刘丽英，李利君，丁忠伟.缠绕式中空纤维膜组件强化膜两侧传质过程[J].膜科学与技术，2005，25（6）：18-20.
[36] Francisco J，Hernández-Fernández F J，de los Ríos A P，et a1.A novel application of supported liquid membranes based on ionic liquids to the selective
simultaneous separation of the substrates and products of a transesterification reaction[J].Membrane Science，2007，293(1)：73-80.
[37] Mousumi C，Hans-Jorg B.Highly selective and efficient transport of toluene in bulk ionic liquid membranes containing Ag+ as carrier[J].Fuel
Processing Technology，2007，88(1)：43-49.
[38] 吴锋，王保国.离子液体充填型支撑液膜分离乙醇/水混合物[J].膜科学与技术，2008，28(5)：68-70.
[39] Yong Tao，Jing-Fu Liu，Xia-Lin Hu，et al.Hollow fiber supported ionic liquid membrane micro-extraction for determination of sulfonamides
in environmental water samples by high-performance liquid chromatography[J].Journal of Chromatography，2009，1216 (1/2)：6259-6266.
[40] Matsumoto M，Inomoto Y，Kondo K.Selective separation of aromatic hydrocarbons through supported liquid membranes based on ionic liquids[J].Journal of Membrane Scie-nce，2005，246(1)：77-81.
[41] Ilconich J，Myers C，Pennline H，et al.Experimental investigation of the permeability and selectivity of supported ionic liquid membranes for CO2/He at temperature up to 125℃[J].Journal of Membrane Science，2007，298(1)：41-47.
[42] Hanioka S，Maruyama T，Sotani T，et al.CO2 separation facilitated by task-specific ionic liquids using a supported liquid membrane[J]. Journal of Membrane Science，2008，314 (1/2)：1-4.
[43] Kim KW，Song B，Choi MY，et al.Biocatalysis in ionic liquid:markedly enhanced enantio- aelectivity of lipase[J].Organic Letters，2001，3(1)：1507-1509.
[44] Itoh T，Akasaki E，Kudo K，et al.Lipase-catalyzed enantioselective acylation in the ionic liquid solvent system: reaction of enzyme anchored to the
solvent[J].Chemistry Letters，2001，30(1)：262-263.
[45] Jastorff B，Sttirmann B，Ranke J. How hazardous are ionic liquids? Structure-activity relationships and biological testing as important elem
nts for sustainability evaluation[J].Green Chemistry，2003，5(1)：136-142

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