膜气液接触过程的研究进展
作者:常 青,贾志谦,秦晋
单位: 北京师范大学化学学院膜科学与技术实验室,北京 100875
关键词: 膜气液接触器;膜吸收;中空纤维膜
DOI号:
分类号: TQ 028.1
出版年,卷(期):页码: 2010,30(6):0-0

摘要:
摘 要:在膜气液接触过程中,气液流速可操作范围宽,结构紧凑,易于放大,不存在液泛、沟流和雾沫夹带等问题,已成为膜科学与技术研究的热点之一。本文分别介绍了膜气液接触器的结构,气液传质过程中气膜传质阻力、膜阻力和液膜传质阻力的估算以及影响这些阻力的主要因素,膜气液接触过程在气体分离、无泡曝气、饱和烃/不饱和烃分离、废气中VOCs脱除和纳米粒子制备等方面的应用,并对膜气液接触过程的发展方向进行了展望。
Abstract:In gas-liquid membrane contacting process, the two phases are not interdispersed so that the problems often encountered in the conventional apparatus such as flooding, foaming and entrainment can be avoided. The compact modular structure of the membrane contactors also provides large and fixed gas-liquid interface. The process iseasily to scale up. This paper introduces the progress in the membrane gas-liquid contacting process, including the membrane gas-liquid contactors, the mass transfer process and mass transfer resistance, and the applications in gas separation, bubbleless aeration, removal of VOCs and preparation of nanoparticles etc.

基金项目:
国家自然科学基金(20676016)

作者简介:
常青(1987—),女,山西人,硕士研究生,主要研究方向为膜科学与技术

参考文献:
[1]Su-Hsia Lina, Kuo-Lun Tungb, Wei-Jie Chenb,et al.Absorption of carbon dioxide by mixed piperazine–alkanolamine absorbent in a plasma-modified polypropylene hollow fiber contactor. Journal of Membrane Science,2009,333:30–37.
[1]Zhang Qi, E L Cussler. Microporous Hollow Fibres for Gas Absorption. J Membr Sci, 1985,23: 321-345.
[1] Dindore V Y, Brilman D W F, Geuzebroek F H, et al. Membrane-solvent selection for CO2 rermoval using membrane gas-liquid contactors[J].Sep Purif Technol, 2004,40:133-145.
[1] Dindore V Y, Brilman D W F, Versteeg G F. Hollow fiber membrane contactor as a gas-1iquid model contactor[J]. Chem Eng Sci, 2005,60: 467-479.
[1] Jia Zhiqian, Chang Qing, Qin Jin, et al. Preparation of nanoparticles with a gas-liquid membrane contactor. J Membr Sci, 2009,342:1-5.
[1]Gabelman A, Hwang S-T. Hollow Fiber Membrane Contactors. J Membr Sci, 1999,159,61-106.
[1]Sengupta A, Peterson P A, Miller B D, et al. Large-scale application of membrane contactors for gas transfer from or to ultrapure water. Sep Purif Technol, 1998,14,189-200.
[1]Wickramasinghe S R, Semmens M J, Cussler E L. Mass Transfer in Various Hollow Fiber Geometries. J Membr Sci, 1993,69,235-250.
[1]Rami Faiz, M. Al-Marzouqi.Mathematical modeling for the simultaneous absorption of CO2 and H2S using MEA in hollow fiber membrane contactors.Journal of Membrane Science, 2009, 342: 269–278.
[1]Saeed Shirazian,Abdolreza Moghadassi, Sadegh Moradi.Numerical simulation of mass transfer in gas–liquid hollow fiber membrane contactors for laminar flow conditions.Simulation Modelling Practice and Theory, 2009, 17:708–718.
[1]张成芳.气液反应与反应器.北京:化学工业出版社,1985:6-8.
[1]Li Jing-Liang, Chen Bing-Hung. Review of CO2 absorption using chemical solvents in hollow fiber membrane contactors. Sep Purif Technol,2005,41:109-122.
[1]H. Kreulen, C.A. Smolders, G.F. Versteeg, W.P.M. Vanswaaij, Microporous hollow-?ber membrane modules as gas-liquid contactors. 2.Mass-transfer with chemical-reaction, J. Membr. Sci, 1993, 78:217–238.
[1]Qi Z, Cussler E L. Microporous hollow fibers for gas absorptionⅡ mass transfer across the membrane[J]. J Membr Sci, l985, 23:333-345.
[1]Gabelman A, Hwang S T, Hollow fiber membrane contactors. J Membr Sci,1999,159,61.
[1]Gao Jian, Zhang Weidong, Zhang Zc ting, el a1.The influence of membrane micro-structure on membrane absorption process[A].Asian International Conference Oil Advanced Materials[C]. Beijing:2005.11:167-173.
[1] Katja Simons,Kitty Nijmeijer,MatthiasWessling. Gas–liquid membrane contactors for CO2 removal. J Membr Sci. 2009.340:214–220.
[1]Lagana F, Barbieri G, Drioli E. Direct contact membrane distillation: modeling and concentration experiments[J]. J Membr Sci,2000,166:1-11.
[1]Wickramasinghe S R, Semmens M J, Cussler E L. Mass transfer in various hollow fiber geometries, J Membr Sci, 1993, 84,1-14.
[1]Danckwerts P V, F R S. Gas-Liquid Reactions.McGraw-Hill,1970.
[1]R.B. Bird,W.E. Stewart, E.N. Lightfoot, Transport Phenomena, JohnWiley & Sons,1960.
[1]Hagg M–B. Membrane technology in chemical. Sep Purif Methods,1998, 27,51-168.
[1]Abduireza T–M. A review of the application of membrane separation technology in natural gas treatment. Sep Sci Technolo,1999,34(10),2095-2111.
[1]Watanabe H. CO2 removal from synthetic natural gas for city gas use. J Membr Sci,1999,154,121-126.
[1]Jian-Gang Lu, You-Fei Zheng, Min-Dong Cheng. et al. Effects of activators on mass-transfer enhancement in a hollow fiber contactor using activated alkanolamine solutions.Journal of Membrane Science, 2007,289:138–149.
[1]A.F. Portugal, F.D. Magalhaes, A. Mendes.Carbon dioxide removal from anaesthetic gas circuits using hollow fibermembrane contactors with amino acid salt solutions.Journal of Membrane Science, 2009,339:275–286.
[1]Jansen A E, Klaassen K, Feron P H M, et al. Membrane gas absorption processes in environmental applications,in: Crespo J G, Boddeker K W (Eds.). Membrane proeesses in separation and purification,Kluwer Academic.
[1]Sengupta A, Sodaro R A, Reed B W. Oxygen removal from water using process-scale extra-flow membrane contactors and systems,Seventh Annual Meeting of the North American Membrane Society, Portland, OR, May 1995.
[1]Peterson P A, CELGARD LLC Corporation,personal communication,23 November 1998.
[1]Yang M-C, Cussler E L. Artificial gills. J Membr Sci,1989, 42, 273-284.
[1]Sirkar K K. Membrane separation:newer concepts and applications for the food industry,in: Singh R K, Rizvi S S H (Eds.). Bioseparation Processes in Foods,Marcel Dckker,New York, 1995, 353-356.
[1]Kreulen H, Smolders C A, Versteeg G F,et al. Microporous hollow fiber membrane Modules as gas-liquid contactors, Part l. Physical mass transfer proeess,A specific application: Mass Transfer in highly viseous liquids. J Membr Sci,1993,78,197-216.
[1]Tsou D T, Blachman M W, Davis J C. Silver-facilitated olefin/paraffin separation in a liquid membrane contactor system. Ind Eng Chem Res,1994,33,3209-3216.
[1]Poddar T K, Majumdar S, Sirkar K K. Membrane-based absorption of VOCs from a gas stream. AIChE Journal, 1996,42, 327-3282.

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