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分离CO2膜技术

作者：王志，²，³，袁芳¹，²，³，王明 ¹，²，³，王纪孝¹，²，³，王世昌¹，³

单位： 1.天津大学化工学院化学工程研究所，天津 300072；2. 化学工程联合国家重点实验室（天津大学），天津 300072；3. 天津市膜科学与海水淡化技术重点实验室，天津 300072

关键词： CO2；捕集；膜分离；选择透过机制

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2011,31(3):11-17

摘要：

分离CO2是当前能源和环境领域的最重要的课题之一。膜分离法在投资、能耗以及环境友好方面优于传统方法。文章提出了CO2分离膜的四种选择透过机制，着重论述了国内外在分离CO2膜技术方面的研究现状，介绍了本课题组在分离CO2反应选择膜方面的研究成果，并进一步探讨了分离CO2膜技术的未来发展趋势。

CO2 separation is one of the most important subjects on energy and environment. Compared with conventional CO2 capture processes, membrane technology for CO2 capture has been attracting more and more attention due to low investment, low energy consumption and environmental friendliness. In this paper, CO2 separation membranes were classified by permselective mechanisms. Recent research results on membranes for CO2 separation were mainly reviewed. Achievements of our research group on reaction-selective membranes for CO2 separation were introduced. Further more, future development trends for CO2 separation membranes were discussed.

基金项目：

国家自然科学基金资助项目(20836006)；国家“973计划”资助项目(2009CB623405)

作者简介：

王志(1966-) ，男，河北万全人，教授，博士生导师，主要从事膜过程、膜制备和膜材料等方面的研究。E-mail: wangzhi@tju.edu.cn

参考文献：

[1] Herzog H J. What Future for Carbon Capture and sequestration?.[J]. Environ Sci Technol, 2001, 35: 148~153.
[2] Herzog H, Golomb D. Carbon capture and storage from fossil fuel use.[J]. Encyclopedia of Energy, 2004, 1: 277~287.
[3] Favre E. Carbon dioxide recovery from post-combustion processes: can gas permeation membranes compete with absorption?.[J]. J Membr Sci, 2007, 294: 50~59.
[4] Pandey P, Chauhan R S. Membranes for gas separation.[J]. Prog Polym Sci, 2001, 26: 853~893.
[5] Van der Sluijs J P, Hendriks C A, Blok K. Feasibility of polymer membranes for carbon dioxide recovery from flue gases.[J]. Energy Convers Manage, 1992, 33: 429~436.
[6] Ho M T, Allison G W, Wiley D E. Reducing the cost of CO2 capture from flue gases using membrane technology.[J]. Ind Eng Chem Res, 2008, 47: 1562~1568.
[7] Zhao L, Riensche E, Menzer R, et al. A parametric study of CO2/N2 gas separation membrane processes for post-combustion capture.[J]. J Membr Sci, 2008, 325: 284~294.
[8] Yang D X, Wang Z, Wang J X, et al. Potential of Two-stage membrane system with recycle stream for CO2 capture from postcombustion gas.[J]. Energy & Fuels, 2009, 23: 4755~4762.
[9] Evan J G, Thomas O B. Review of novel methods for carbon dioxide separation from flue and fuel gases.[J]. Fuel Process Technol, 2005, 86: 1423~1434.
[10] Nunes S P, Peinemann K-V. Membrane Technology in the Chemical Industry[M]. Weinheim, Federal Republic of Germany: Wiley-Vch Verlag GmbH, 2001.112~120.
[11] Burns R L, Koros W J. Structure-Property Relationships for Poly(pyrrolone-imide) Gas Separation Membranes.[J]. Macromolecules, 2003, 36(7): 2374~2381.
[12] Powell C E, Qiao G G. Polymeric CO2/N2 gas separation membranes for the capture of carbon dioxide from power plant flue gases.[J]. J Membr Sci, 2006, 279(1-2): 1~49.
[13] Mulder M 著，李琳译. Basic principles of membrane technology, 膜技术基本原理[M]. 2nd ed. 北京：清华大学出版社，1999.40~41.
[14] Shiflett M B, Foley H C. Ultrasonic Deposition of High-selectivity Nanoporous Carbon Membranes.[J]. Science, 1999, 285: 1902~1904.
[15] Kita H, Nanbu K, Hamano T, et al. Carbon Molecular Sieving Membranes Derived from Lignin-Based Materials.[J]. Journal of Polymers and the Environment, 2002, 10: 69~75.
[16] Barsema J N, Klijnstra S D, Balster J H, et al. Intermediate polymer to carbon gas separation membranes based on Matrimid PI.[J]. J Membr Sci, 2004, 238: 93~102.
[17] Lie J A, Hägg M B. Carbon membranes from cellulose and metal loaded cellulose. [J]. Carbon, 2005, 43: 2600~2607.
[18] Zhang B, Wang T H, Zhang S H, et al. Preparation and characterization of carbon membranes made from poly(phthalazinone ether sulfone ketone).[J]. Carbon, 2006, 44: 2764~2769.
[19] Zhang B, Wang T H, Wu Y H, et al. Preparation and gas permeation of composite carbon membranes from poly (phthalazinone ether sulfone ketone).[J]. Sep Purif Technol, 2008, 60: 259~263.
[20] Wang T H, Zhang B, Qiu J S, et al. Effects of sulfone/ketone in poly(phthalazinone ether sulfone ketone) on the gas permeation of their derived carbon membranes.[J]. J Membr Sci, 2009, 330: 319~325.
[21] Lin H Q, Freeman B D. Materials selection guidelines for membranes that remove CO2 from gas mixture.[J]. J Mole Stru, 2005, 739: 57~74.
[22] Suzukia H, Tanakaa K, Kita H, et al. Preparation of composite hollow fiber membranes of poly(ethylene oxide)-containing polyimide and their CO2/N2 separation properties.[J]. J Membr Sci, 1998, 146: 31~37.
[23] Liu L, Chakma A, Feng X S. A novel method of preparing ultrathin poly(ether block amide) membranes.[J]. J Membr Sci, 2004, 235: 43~52.
[24] Car A, Stropnik C, Yave W, et al. PEG modified poly(amide-b-ethylene oxide) membranes for CO2 separation.[J]. J Membr Sci, 2008, 307: 88~95.
[25] Zhao H Y, Cao Y M, Ding X L, et al. Poly(ethylene oxide) induced cross-linking modification of Matrimid membranes for selective separation of CO2.[J]. J Membr Sci, 2008, 320: 179~184.
[26] Ji P F, Cao Y M, Zhao H Y, et al. Preparation of hollow fiber poly(N, N-dimethylaminoethyl methacrylate)–poly(ethylene glycol methyl ether methyl acrylate)/polysulfone composite membranes for CO2/N2 separation.[J]. J Membr Sci, 2009, 342: 190~197.
[27] Yave W, Car A, Peinemann K V. Nanostructured membrane material designed for carbon dioxide separation.[J]. J Membr Sci, 2010, 350: 124~129.
[28] Yave W, Car A, Funari S S, et al. CO2-philic polymer membrane with extremely high separation performance.[J]. Macromolecules, 2010, 43: 326~333.
[29] Kusuma V A, Freeman B D, Smith S L, et al. Influence of TRIS-based co-monomer on structure and gas transport properties of cross-linked poly(ethylene oxide).[J]. J Membr Sci, 2010, 359: 25~36.
[30] Ward W J, Robb W L. Carbon dioxide-oxygen separation: facilitated of carbon dioxide across a liquid film.[J]. Science, 1967, 156: 1481~1484.
[31] Teramoto M, Takeuchi N, Maki T, et al. Facilitated transport of CO2 through liquid membrane accompanied by permeation of carrier solution.[J]. Sep Purif Technol, 2002, 27: 25~31.
[32] 王志，张莉莉，张颖，等.分离CO2的促进传递膜.[J].膜科学与技术，2003, 23: 166~171.
[33] Yoshikawa M, Fujimoto K, Kinugawa H, et al. Selective permeation of carbon dioxide through synthetic polymeric membranes having amine moiety.[J]. Chem Lett, 1994, 23: 243~246.
[34] Matsuyama H, Teramoto M, Sakakura H. Selective permeation of CO2 through poly{2-(N, N-dimethyl) aminoethyl methacrylate} membrane prepared by plasma-graft polymerization technique.[J]. J Membr Sci, 1996, 114: 193~200.
[35] Matsuyama H, Terada A, Nakagawara T, et al. Facilitated transport of CO2 through polyethylenimine/poly(vinyl alcohol) blend membrane.[J]. J Membr Sci, 1999, 163: 221~227.
[36] Kim T J, Li B A, Hägg M B. Novel fixed-site-carrier polyvinylamine membrane for carbon dioxide capture.[J]. J Polym Sci Part B: Polym Phys, 2004,42: 4326~4336.
[37] Du R H, Feng X S, Chakma A. Poly(N, N-dimethylaminoethyl methacrylate)/polysulfone composite membranes for gas separations.[J]. J Membr Sci, 2006, 279: 76~85.
[38] Deng L Y, Kim T J, Hägg M B. Facilitated transport of CO2 in novel PVAm/PVA blend membrane.[J]. J Membr Sci, 2009, 340: 154~163.
[39] Sandru M, Haukebø S H, Hägg M B. Composite hollow fiber membranes for CO2 capture.[J]. J Membr Sci, 2010, 346: 172~186.
[40] 张颖，王志，伊春海，等. VSA-SA/PS固定载体复合膜的制备及其CO2/CH4分离性能.[J]. 化工学报，2006，57（1）：163~168.
[41] Zhang Y, Wang Z, Wang S C. Selective permeation of CO2 through new facilitated transport membranes.[J]. Desalination, 2002, 145(1-3): 385~388.
[42] Zhang Y, Wang Z, Wang J X, et al. Effect of heat cross-linking on carbon dioxide fixed-carrier membrane structure and performance.[J]. Desalination, 2006, 193(1-3): 299~303.
[43] Wang Z, Yi C H, Zhang Y, et al. CO2-facilitated transport through Poly(N-vinyl-γ-sodium aminobutyrate-co-sodium acrylate) /polysulfone composite membranes.[J]. Journal of Applied Polymer Science, 2006, 100(1), 275~282.
[44] Yi C H, Wang Z, Li M, et al. Facilitated transport of CO2 through polyvinylamine/polyethlene glycol blend membranes.[J]. Desalination, 2006, 193(1-3): 90~96.
[45] 伊春海，王志，张莉莉，等. 含聚乙烯基胺共混固定载体复合膜制备及其CO2/CH4分离性能.[J]. 化工学报，2006，57（4）：997~1002.
[46] Zhao J, Wang Z, Wang J X, et al. Influence of heat-treatment on CO2 separation performance of novel fixed carrier composite membranes prepared by interfacial polymerization.[J]. J Membr Sci, 2006, 283(1-2): 346~356.
[47] Wang Z, Li M, Cai Y, et al. Novel CO2 selectively permeating membranes containing PETEDA dendrimer.[J]. J Membr Sci, 2007, 290(1-2): 250~258.
[48] Cai Y, Wang Z, Yi C H, et al. Gas transport property of polyally lamine-poly(vinyl alcohol)/polysulfone composite membranes.[J]. J Membr Sci, 2008, 310(1-2): 184~196.
[49] Yu X W, Wang Z, Wei Z H, et al. Novel tertiary amino containing thin film composite membranes prepared by interfacial polymerization for CO2 capture.[J]. J Membr Sci, 2010, 362(1-2): 265~278.

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