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响应面法优化PSSA/PVA共混膜催化酯化制备生物柴油

作者：朱木兰，何本桥?，石文英，刘安元，冯耀辉，李建新

单位：天津工业大学中空纤维膜材料与膜过程省部共建国家重点实验室培育基地

关键词：响应面法；生物柴油；酯化；PSSA/PVA

DOI号：

分类号： TQ032.41 ，TQ028．8

出版年,卷(期):页码： 2011,31(4):89-94

摘要：

采用响应面法考察了聚苯乙烯磺酸（PSSA）/聚乙烯醇（PVA）共混型催化膜催化酯化制备生物柴油工艺中催化膜用量、醇油质量比、反应时间和反应温度及其交互作用对酯化率的影响，结果发现各因素对转化率影响顺序为醇油比>催化剂用量>反应温度>反应时间。同时，醇油比与催化剂量的交互作用对转化率的影响最强，而与反应时间相关的交互作用则弱。最佳条件为：催化剂用量1.56meq、醇油质量比1.2：1、反应时间7h和反应温度64.5℃。预测酯化转化率（97.27%）与实验验证结果（94.60%）比较接近。

A poly(styrene sulfonic acid) (PSSA)/poly(vinyl alcohol) (PVA) blend membrane was used as a catalyst for producing biodiesel from acidic oil. The effects of methanol-oil ratio, reaction time, catalyst amount and temperature on the esterification conversion of fatty acids were investigated through response surface method. Results show that the order of their effects on the conversion was methanol-oil ratio > catalyst amount > temperature > reaction time. The interaction effect between methanol-oil ratio and catalyst amount on the conversion was most significant; nevertheless the interaction effects related with reaction time was less significant. A quadratic polynomial equation was obtained for esterification conversion by multiple regression analysis. The optimum conditions for the esterification obtained were methanol-oil mass ratio of 1.2:1, the amount of catalyst of 1.56meq/g of oil, temperature of 64.5℃ and reaction time of 7 h. The experimental conversion was 94.60%，close to the predicted conversion(97.27 %) by the equation.

基金项目：

国家高科技（863）计划（项目编号2009AA03Z223)；天津市应用基础及前沿技术研究计划(项目编号 08JCYBJC26400、08JCZDJC24000)

作者简介：

朱木兰(1984-），女，江苏宿迁市人，硕士研究生，主要从事膜催化方面的研究。 ?联系人电话：022-24528072， hebq2008@gmail.com

参考文献：

[1] 颜姝丽，鲁厚芳，姜利寒, 等. 固体碱催化剂用于油脂甲醇酯交换反应制备生物柴油[J]. 化工学报, 2007, 58（10）:2506
[2] Ghesti, G F, Macedo J L ,Vicente C I P, et al. Synthesis, characterization and reactivity of Lewis acid/surfactant cerium trisdodecylsulfate catalyst for transesterification and esterification reactions[J]. Appl Catal A, 2009, 355(1-2): 139-147.
[3] 高静, 马丽, 李伟杰, 等. 复合固定化脂肪酶催化麻疯树油生产生物柴油[J]. 化工学报, 2005, 56(9):1727
[4] Feng Y H, He B Q, Cao Y H, et al. Biodiesel production using cation-exchange resin as heterogeneous catalyst[J]. Bioresour Technol, 2010, 101(5): 1518-1521.
[5] 王建宇，徐又一，朱宝库. 高分子催化膜及膜反应器研究进展[J].膜科学与技术，2007，27（06）：82
[6] Liu Q L, Zhang Z B, Chen H F. Study on the coupling of esteri?cation with pervaporation[J]. J Membr Sci, 1999, 182: 173–181.
[7] Caetano C S, Guerreiro L, Fonseca I M, et al. Esterification of fatty acids to biodiesel over polymers with sulfonic acid groups[J]. Appl Catal A, 2009, 359(1-2): 41-46.
[8] Guerreiro L, Castanheiro J, Fonseca I M. Transesterification of soybean oil over sulfonic acid functionalised polymeric membranes[J]. Catal Today. 118 (2006), 166-171.
[9] Yuan X, Liu J, Zeng, G. Optimization of conversion of waste rapeseed oil with high FFA to biodiesel using response surface methodology[J], Renewable Energy, 2008, 33(7): 1678-1684.
[10] Kalam M A, Masjuki H H, et al. Biodiesel from palmoil-an analysis of its properties and potential[J]. Biomass Bioenergy, 2002, 23(2): 471-479.
[11] Ghadge S V, Raheman H. Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology[J]. Bioresour Technol, 2006,97(3):379
[12] Wang Y, Wu H, Zong M H. Improvement of biodiesel production by lipozyme TL IM-catalyzed methanolysis using response surface methodology and acyl migration enhancer[J]. Bioresour Technol, 2008, 99(15): 7232-7237.
[13]梅建凤, 闵航, 吕镇梅.利用酵母细胞生物催化合成2-苯乙醇[J]. 催化学报, 2007,28(11):993
[14] Sdrula N.A study using classical or membrane separation in the biodiesel process [J]. Desalination, 2010，250: 1070–1072
[15] WIMCO (World Industrial Membrane)—web Information: www.wimco1989.ca.
[16 ] Zhu M, He B, Shi W, et al. Preparation and characterization of PSSA/PVA catalytic membrane for biodiesel production[J].Fuel, 2010，89：2299–2304
[17] Peng B X, Shu Q, Wang J F, et al. Biodiesel production from waste oil feedstocks by solid acid catalysis[J]. Process Saf Environ, 2008,86(6):441
[18] Halim S F A, Kamaruddin A H, Fernando W J N. Continuous biosynthesis of biodiesel from waste cooking palm oil in a packed bed reactor: Optimization using response surface methodology (RSM) and mass transfer studies[J]. Bioresour Technol, 2009,100(2):710
[19] Rashid U, Anwar F, Arif M. Optimization of Base Catalytic Methanolysis of Sunflower (Helianthus annuus) Seed Oil for Biodiesel Production by Using Response Surface Methodology[J]. Ind. Eng. Chem. Res, 2009,48(4): 1719-1726.

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