膜科学与技术

位置：首页 >> 期刊内容阅读

应用于酯化反应的亲水性渗透汽化膜研究进展

作者：祝春芳¹²，王忠铭¹，袁振宏¹，黄大隆¹²

单位： 1.中国科学院广州能源研究所，中国科学院可再生能源与天然气水合物重点实验室，广东广州，510640; 2.中国科学院研究生院，北京 100039

关键词：渗透汽化；酯化反应；亲水性；膜

DOI号：

分类号：

出版年,卷(期):页码： 2011,31(5):94-99

摘要：

渗透汽化是分离共沸混合物或者某一物质含量较低混合液的方法。在酯化反应中，耦合渗透汽化可以提高反应转化率。本文根据膜的制备材料，对有机膜、无机膜、有机无机杂化膜在该方面的应用进行了较详细的报道。且分析了各种膜在酯化反应中的催化效果。

Pervaporation is a method for separating mixtures that are azeotropic or have a lower component. Its conversion could be improved via coupling with pervaporation. The application of inorganic membrane, organic inorganic composite membrane, and organic membrane in esterification was reported in detail, and their catalytic effect on esterification was also analyzed.

基金项目：

国家高技术研究发展计划（863计划）（2009AA05Z403）,广东省科技计划项目（2009B030802014）

作者简介：

祝春芳（1985-）,女,硕士,广州能源研究所,从事渗透汽化膜分离耦合酯化反应研究. *通讯联系人zhucf@ms.giec.ac.cn

参考文献：

1 Korkmaz. S, Yavuz Salt, Ayca Hasanoglu, et al. Pervaporation membrane reactor study for the esterification of acetic acid and isobutanol using polydimethylsiloxane membrane. [J] .Appl Catal a-Gen,2009, 366: 102-107.
2 Zhu M,Benqiao He, Wenying Shi, et al. Preparation and characterization of PSSA/PVA catalytic membrane for biodiesel production. [J].Fuel ,2010, 89: 2299–2304.
3 Cao, P. G., Dube, M. A. & Tremblay, A. Y. High-purity fatty acid methyl ester production from canola, soybean, palm, and yellow grease lipids by means of a membrane reactor. [J]. Biomass Bioenerg ,2008,32: 1028-1036.
4 Dube M, Tremblay A, Liu J. Biodiesel production using a membrane reactor. [J].Bioresource technology,2007, 98: 639-647 .
5 Guerreiro L, J.E. Castanheiro, I.M. Fonseca, et al. Transesterification of soybean oil over sulfonic acid functionalised polymeric membranes.[J].Catalysis Today ,118: 166-171 .
6 KITA H, TANAKA K, OKAMOTO K ,et al. The esterition of oleic Acid with Ethanol Accompanied by Membrane Separation.[J]. Chem Lett, ,1987, 2053-2056 .
7 Vankelecom I, Polymeric membranes in catalytic reactors. [M].Chem. Rev,2002, 102: 3779-3810 .
8 Hasanoglu A, Salt Y, Keleser S,et al. The esterification of acetic acid with ethanol in a pervaporation membrane reactor. [J]. Desalination,2009, 245: 662-669 .
9 Sanz M, Gmehling J, Esterification of acetic acid with isopropanol coupled with pervaporation:: Part II. Study of a pervaporation reactor. [J]. Chem Eng J ,2006,123: 9-14 .
10 Zhou H, LI Yanshuo, ZHU Guangqi, et al. Microwave synthesis of a&b-oriented zeolite T membranes and their application in pervaporation-assisted esterification. [J]. Chinese J Catal,2008, 29, 592-594 .
11 Keurentjes J, Janssen G.,Gorissen J. The esterification of tartaric acid with ethanol: kinetics and shifting the equilibrium by means of pervaporation. [J].Chem Eng Sci ,1994,49: 4681-4689 .
12 Ma J, Minhua Zhang, Lianyu Lu, et al. Intensifying esterification reaction between lactic acid and ethanol by pervaporation dehydration using chitosan-TEOS hybrid membranes. [J].Chem Eng J,2009, 155: 800-809.
13 刘鲜红, 孙元 , 胡玥. 纳米SiO2改性聚合物渗透汽化膜. [J]. 天津工业大学学报 ,2008, 27: 13-15 .
14 余立新 , 陈翠仙. 二醛交联pva／Pan复合膜的渗透汽化脱水性能. [J]. 膜科学与技术,2000, 20: 23-25 .
15 郑金花, 许振良, 李井峰,et al. Pva／Pan渗透汽化膜分离乙酸乙酯-乙醇-水体系的研究. [J].膜科学与技术 ,2009, 29: 52-56 .
16 David M, Nguyen Q, Neel J. Pervaporation membranes endowed with catalytic properties, based on polymer blends. [J]. Journal of Membrane Science,1992, 73: 129-141 .
17 李雪辉, 王乐夫. Ppva／Pan渗透汽化复合膜分离特性研究. [J]. 水处理技术,2000, 26: 207-212 .
18 刘兵兵, 曹义呜, 李雄岩, et al. 聚乙烯醇/壳聚糖共混膜渗透汽化性能研究. [J]. 膜科学与技术,2007, 27: 37-41 .
19 周继青, 叶匀分, 胡晓华 ,et al. PVA/PVP互穿网络膜的渗透汽化性质(Ⅱ). [J].高等学校化学学报,2000, 21: 301-305.
20 蔡邦肖,张佩琴. 新型pva／Pa复合膜的微结构及其成膜条件. [J].高校化学工程学报 ,2009,23: 142-147 .
21 章龙, 彭勇, 余立新 ,et al. 己二酸和甲醇酯化反应与渗透汽化脱水耦合过程的研究. [J].膜科学与技术 ,2008,28: 99-101 .
22 潘岚 , 周志军. 渗透汽化膜材料的选择. [J].高分子材料科学与工程 ,1997,13: 138-143 .
23 KITA H, KOHJI HORII, YASUHARU OHTOSHI, et al. Synthesis of a zeolite NaA membrane for pervaporation of water/organic liquid mixtures. [J].J Mater Sci Lett,1995, 14, 206-208 .
24 Kita H, Asamura H, Tanaka K,et al. Preparation and pervaporation properties of X-and Y-type zeolite membranes. [J]. Membrane formation and modification,2000, 330 .
25 Kita H, Fuchida K, Horita T, et al. Preparation of faujasite membranes and their permeation properties. [J].Separation and Purification Technology ,2001,25: 261-268 .
26 颜正朝, 宋军, 林晓,et al. 沸石分子筛膜的合成与应用. [J].石油化工,2004, 891-900 .
27 M.Yamamoto. Vapor-Permeation-Aided Esterification of Oleic Acid: application of pressurized vapor circulation system and zeolite membrane. [J]. Maku (Membran e ) ,1995,20: 143-148.
28 Takagi.S, Kita.H , Okamoto.K. Kagaku Kogaku Symposium Series,1999, 66: 90.
29 Tanaka K, Yoshikawa R, Ying C, et al. Application of zeolite membranes to esterification reactions. [J].Catalysis Today ,2001,67: 121-125 .
30 Tanaka K, Yoshikawa R, Ying C, et al. Application of zeolite T membrane to vapor-permeation-aided esterification of lactic acid with ethanol. [J].Chem Eng Sci ,2002,57: 1577-1584 .
31 阎建民 , 陈观文. 渗透汽化脱水技术及其在酯化工业中的应用. [J]. 现代化工,2001, 21: 12-15 .
32 Ferreira P, Fonseca I M, Ramos A M, Vital J,et al. J. E. Glycerol acetylation over dodecatungstophosphoric acid immobilized into a silica matrix as catalyst. [J]. Applied Catalysis B-Environmental ,2009,91: 416-422, doi:10.1016/j.apcatb.2009.06.009 .
33 苑丽, 张晓丽, 高文艺,et al. 固体酸催化大豆油与乙醇酯交换制备生物柴油. [J].辽宁石油化工大学学报,2008, 28: 4-7 .
34 Ferreira P, Fonseca I M, Ramos A M, et al . E. Esterification of glycerol with acetic acid over dodecamolybdophosphoric acid encaged in USY zeolite. [J]. Catal Commun ,2009,10: 481-484.
35 Tuan V A, Falconer J L , Noble R D. Alkali-Free ZSM-5 Membranes Preparation Conditions and Separation Performance. [J].Department of Chemical Engineering , 1999, 38:3635-3646 .
36 Pilar Bernal M, Coronas J, Menéndez M,et al. Coupling of reaction and separation at the microscopic level: esterification processes in a H-ZSM-5 membrane reactor. [J]. Chem Eng Sci, 2002, 57: 1557-1562 .
37 Ulutan S , Nakagawa T. Separability of ethanol and water mixtures through PTMSP¨Csilica membranes in pervaporation. [J].Journal of Membrane Science, 1998, 143: 275-284 .
38 Zhu Y, Minet R , Tsotsis T. A continuous pervaporation membrane reactor for the study of esterification reactions using a composite polymeric/ceramic membrane. [J].Chem Eng Sci , 1996,51: 4103-4113.
39 Zhu Y , Chen H. Pervaporation separation and pervaporation-esterification coupling using crosslinked PVA composite catalytic membranes on porous ceramic plate. [J]. Journal of Membrane Science,1998, 138:123-134 .
40 Sakohara S, Muramoto F, Sakata T,et al. Separation of Acetone/Water Mixture by Thin Acrylamide Gel Membrane Prepared in Pores of Thin Ceramic Membrane. [J].J Chem Eng Jpn,1990, 23: 40-45 .
41 夏海平, 周花, 陈小艾, et al. 硫酸铁掺杂聚乙烯醇复合膜的催化酯化作用. [J]. 功能材料,2001, 32: 445-446 .
42 刘庆林 , 朱玉山. 交联聚乙烯醇渗透汽化膜用于酯化反应过程. [J].高校化学工程学报 ,1997,11: 172-176 .
43 Bhat S D , Aminabhavi T M. Pervaporation-Aided Dehydration and Esterification of Acetic Acid with Ethanol Using 4A Zeolite-Filled Cross-linked Sodium Alginate-Mixed Matrix Membranes. [J]. Journal of Applied Polymer Science,2009, 113: 157-168.
44 邵士俊, 曹淑琴 , 俞贤达. 渗透汽化型酯化膜反应器研究聚合物/无机固体酸管式复合膜的膜反应性能. [J]. 功能高分子学报,1999, 157-161 .
45 Jou J.-D., Yoshida W, Cohen Y. A novel ceramic-supported polymer membrane for pervaporation of dilute volatile organic compounds. [J].Journal of Membrane Science ,1999,162: 269-284 .
46 Chaimberg M, Parnas R ,Cohen Y. Graft polymerization of polyvinylpyrrolidone onto silica. [J]. Journal of Applied Polymer Science ,1989,37: 2921-2931 .
47 Chaimberg M , Cohen Y. Free-radical graft polymerization of vinylpyrrolidone onto silica. [J]. Ind Eng Chem Res,1991, 30: 2534-2542 .
48 Browne T, Chaimberg M , Cohen Y. Graft polymerization of vinyl acetate onto silica. [J]. Journal of Applied Polymer Science ,1992,44: 671-677 .
49 周立志, 王星, 程晓维, et al. 一种新型亲水性有机-无机渗透汽化分离膜——聚丙烯酰胺复合膜的制备. [J]. 高等学校化学学报 ,2005,26: 567-570 .
50 张桃周 , 平郑骅. 一种新型的亲水性聚丙烯酸-陶瓷复合膜. [J]. 化学学报,2007, 65: 2046-2050 .

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com