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粘度法测定聚偏氟乙烯溶液凝胶分相温度的研究

作者：殷勇¹，李雪梅¹，何涛¹，²

单位： 1材料化学工程国家重点实验室, 南京工业大学化学与化工学院,南京210009

关键词：聚偏氟乙烯;粘度法;凝胶分相温度;热力学

DOI号：

分类号： TQ050.4+25;TQ028.8

出版年,卷(期):页码： 2011,31(5):40-45

摘要：

本文采用粘度法测定了聚偏氟乙烯(PVDF)/N,N-二甲基乙酰胺(DMAc)/一缩二乙二醇(DEG)体系的凝胶分相温度,考察了粘度计转子的转速、高分子浓度、溶液的邻近比及熟化时间对溶液凝胶分相温度的影响.结果显示高分子溶液凝胶分相温度与粘度计转子的转速无关,但随着高分子浓度、溶液的邻近比及熟化时间的增加而升高.粘度法来确定PVDF溶液的凝胶分相温度是一种简单、准确地确定铸膜液状态的方法.

The gelation temperature of PVDF/DMAc/DEG ternary solution was determined by viscosity measurement. The effect of the shear rate, PVDF concentration, approaching value and aging time were investigated. Results indicated that the gelation temperature is not related to the shear rate, however increases with PVDF concentration, approaching value and aging time. The new method in determination of gelation temperature is simple, accurate for investigating polymer solution thermodynamic

基金项目：

科学技术部中小企业创新基金(No.08C26223201857), 国家重大基础研究973项目(No.2009CB623402),材料化学工程国家重点实验室基金(NoZK200804),自然科学基金No. 20976083

作者简介：

殷勇（1984-）,女,河南南阳人,硕士研究生,主要从事有机高分子膜制备和应用的研究.( yinan1984@126.com).

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