聚乳酸乙醇酸纤维增强全氟磺酸复合质子交换膜的研究 |
作者:王正帮1,2 唐浩林1,2, 郭伟1,2 潘牧1,2 |
单位: 1武汉理工大学材料复合新技术国家重点实验室, 武汉理工大学,武汉(430070) |
关键词: 燃料电池;聚乳酸乙醇酸;复合质子交换膜 |
出版年,卷(期):页码: 2011,31(6):60-63 |
摘要: |
本文以具有良好亲水性的聚乳酸乙醇酸(poly-lactide-co-glycolide, PLGA)纳米纤维制备了Nafion/PLGA复合质子交换膜,其屈服强度、断裂强度和弹性模量达到10.5MPa、19MPa和147.8MPa,优于相同条件下的Nafion均质膜。Nafion/PLGA复合质子交换膜电导率达到0.053Scm-1,结构致密、单电池开路电压达到0.96V,并在100mAcm-2-900mAcm-2的欧姆极化控制区域呈现良好的性能。 |
The approach in this research is developing a composite proton exchange membrane with poly-lactide-co-glycolide (PLGA) fibers and perfluorosulfonic acid (PFSA, Nafion) ionomers. With the high strength and conductive PLGA fibers, the yield strength, breaking strength and elastic modulus of the Nafion/PLGA composite membrane achieved 10.5MPa、19MPa and 147.8MPa. The proton conductivity of Nafion/PLGA composite membrane was 0.053Scm-1. The single fuel cell assembled with the Nafion/PLGA composite membrane had a high open circuit voltage of 0.96 V and performed well at ohmic polarization (100mAcm-2-900mAcm-2), gave this membrane a positive further in high performance and durable PEM fuel cells. |
王正帮 (1985-),男,湖北咸宁人,硕士研究生,从事质子交换膜的研究;联系人,唐浩林,Email: tanghaolin2005@yahoo.com.cn |
参考文献: |
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