| 聚乳酸乙醇酸纤维增强全氟磺酸复合质子交换膜的研究 |
| 作者：王正帮1，2 唐浩林1，2， 郭伟1，2 潘牧1，2 |
| 单位： 1武汉理工大学材料复合新技术国家重点实验室, 武汉理工大学，武汉（430070） |
| 关键词： 燃料电池；聚乳酸乙醇酸；复合质子交换膜 |
| DOI号： |
| 分类号： TQ152 |
| 出版年,卷(期):页码： 2011,31(6):60-63 |
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摘要： |
| 本文以具有良好亲水性的聚乳酸乙醇酸(poly-lactide-co-glycolide, PLGA)纳米纤维制备了Nafion/PLGA复合质子交换膜，其屈服强度、断裂强度和弹性模量达到10.5MPa、19MPa和147.8MPa，优于相同条件下的Nafion均质膜。Nafion/PLGA复合质子交换膜电导率达到0.053Scm-1，结构致密、单电池开路电压达到0.96V，并在100mAcm-2-900mAcm-2的欧姆极化控制区域呈现良好的性能。 |
| The approach in this research is developing a composite proton exchange membrane with poly-lactide-co-glycolide (PLGA) fibers and perfluorosulfonic acid (PFSA, Nafion) ionomers. With the high strength and conductive PLGA fibers, the yield strength, breaking strength and elastic modulus of the Nafion/PLGA composite membrane achieved 10.5MPa、19MPa and 147.8MPa. The proton conductivity of Nafion/PLGA composite membrane was 0.053Scm-1. The single fuel cell assembled with the Nafion/PLGA composite membrane had a high open circuit voltage of 0.96 V and performed well at ohmic polarization (100mAcm-2-900mAcm-2), gave this membrane a positive further in high performance and durable PEM fuel cells. |
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基金项目： |
| “863”项目 (2009AA034400)、国家自然基金项目（50802072）、中央高校基本科研业务费专项资金（2010-Ia-055） |
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作者简介： |
| 王正帮 (1985-)，男，湖北咸宁人，硕士研究生，从事质子交换膜的研究；联系人，唐浩林，Email: tanghaolin2005@yahoo.com.cn |
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参考文献： |
| [1] de Bruijn F A, Dam V A T, Janssen G J M. Durability and degradation issues of PEM fuel cell components [ J]. Fuel Cells, 2008, 8( 1): 3- 22. [2] Borup R, Meyers J, Pivovar B, et al. Scientific aspects of polymer electrolyte fuel cell durability and degradation [ J]. Chemical Reviews, 2007, 107( 10): 3904- 3951. [3] Tang H L, Pan M, Wang F, et al. Highly durable proton exchange membranes for low temperature fuel cells [ J]. Journal of Physical Chemistry B, 2007, 111( 30): 8684- 8690. [4] Tang H L, Shen P K, Jiang S P, et al. A degradation study of Nation proton exchange membrane of PEM fuel cells [ J]. Journal of Power Sources, 2007, 170( 1): 85- 92. [5] Zhu J, Tang H L, Pan M. Fabrication and characterization of self-assembled Nafion-SiO2-ePTFE composite membrane of PEM fuel cell [ J]. Journal of Membrane Science, 2008, 312( 1- 2): 41- 47. [6] Tang H L, Pan M, Jiang S P, et al. Fabrication and characterization of PFSI/ePTFE composite proton exchange membranes of polymer electrolyte fuel cells [ J]. Electrochimica Acta, 2007, 52( 16): 5304- 5311. [7] Craparo E F, Teresi G, Ognibene M C, et al. Nanoparticles based on novel amphiphilic polyaspartamide copolymers [ J]. Journal of Nanoparticle Research, 2010, 12( 7): 2629- 2644. [8] Li J S, Yang X, Tang H L, et al. Durable and high performance Nafion membrane prepared through high-temperature annealing methodology [ J]. Journal of Membrane Science, 2010, 361( 1- 2): 38- 42. |
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