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乳状液膜法提取模拟湿法磷酸中的稀土镧

作者：范文娟＊，党亚固，费德君，刘勇

单位：四川大学化工学院

关键词：磺化聚丁二烯；乳状液膜法；湿法磷酸；镧；P204

DOI号：

分类号： TF111.3

出版年,卷(期):页码： 2012,32(2):46-51

摘要：

采用自制的磺化聚丁二烯（LYF）做表面活性剂，以P204为萃取剂，以4mol/L HCl为内相，液体石蜡为膜稳定剂，制成乳状液膜，从模拟湿法磷酸中萃取了稀土镧。在膜内比为1.2 :1，制乳搅拌搅拌速度为2000 rpm，时间为20 min，提取搅拌速度为250 rpm，时间为10min，水乳比为2:1，磷酸浓度为10% P2O5，La3+含量为300 mg/L时，镧离子的迁移率达到86.67%。同时利用液液萃取通过斜率分析法讨论了P204从磷酸中提取镧离子的反应机理。对P204萃取镧离子进行了热力学研究，结果表明，萃取反应属于放热反应，反应热为-7.6971 kJ/mol。

Recently attention has been directed to wet-process phosphoric acid as a potential source of lanthanides. In this work emulsion liquid membrane which contained LYF (sulphonated polybutadiene) as surfactant, P204 as carrier, 2M HCl as internal phase, liquid paraffin as stabilizing agent was applied to removal of lanthanides. Results show that the degree of removal of lanthanides could be 86.67% with aqueous/organic phase ratio = 2:1, P2O5% = 15%, concentration of La3+ = 300 mg/L. The influence of various factors such as the concentration of H3PO4, H2PO42-, P204, HCl on the degree of removal has been established by liquid–liquid extraction. The mechanism of Lanthanide extraction from phosphoric acid by P204 has been determined via slope analysis. Meantime the results of thermomechanics show that the removal of lanthanide from phosphoric acid is an exothermic reaction with -7.6971 kJ/mol reaction heat.

基金项目：

高纯磷酸制备关键技术研究，20078AE58B01

作者简介：

范文娟（1986- ），女，四川南充人，硕士；研究方向：稀土湿法冶金

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