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BDAF-PMDA型聚酰亚胺炭膜的制备及其气体分离性能的研究

作者：祁文博¹，王同华，李琳¹，张萍萍¹，孙美悦¹，李建新²，王虹²

单位： 1.大连理工大学化工学院精细化工国家重点实验室炭材料研究室膜科学与技术研究开发中心，大连 116023;2．天津工业大学中空纤维膜材料与膜过程省部共建国家重点实验室培育基地，天津 300160

关键词： BDAF-PMDA，聚酰亚胺，炭膜，化学结构，气体分离

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2012,32(3):6-10

摘要：

以2,2-双[4-(4-氨基苯氧基苯基)]六氟丙烷(BDAF)为二胺单体,均苯四酸二酐(PMDA)为二酐单体,采用两步法制备了BDAF-PMDA型聚酰亚胺，进一步高温热解制备炭膜。采用红外、热重、X射线衍射分析其结构变化，并测试炭膜对纯组分及混合气体的渗透性能和分离选择性。结果表明，BDAF-PMDA型炭膜具有较高的气体渗透性，在CO2/H2体系中可优先渗透CO2。提高炭化温度，炭膜孔径减小，气体的渗透性能降低，选择性提高，并使得BDAF-PMDA型炭膜的分离机理由表面扩散为主逐渐变为表面扩散和分子筛分共同控制。

The BDAF-PMDA polyimide which synthesized with the monomer of pyromellitic acid dianhydride and 2,2-Bis [4-(4-aminophenoxy)phenyl]-hexafluoropropanane by two step method was used to prepare the carbon membrane by the pyrolysis at the high temperature. The changes of chemical structure of BDAF-PMDA polyimide during the pyrolysis and gas separation properties of derived carbon membranes were characterized by FTIR, TG, XRD, and gas permeation tests of pure and mixed gas. Results indicate that the carbon membrane prepared from the BDAF-PMDA polyimide precursor exhibits the higher gas permeability for small gas molecules, especially for CO2 which can be permeated faster than H2 in the mixture of CO2/H2. With the increase of carbonization temperature, the pore size of carbon membrane decreased. As a result, the gas permeability of the derived carbon membrane was reduced and the gas selectivity was enhanced. And the separation mechanism of BDAF-PMDA carbon membrane was changed from the surface diffusion mechanism into the coexistence of surface diffusion and molecular sieving mechanism.

基金项目：

国家自然科学基金面上与重点项目(20776024,20976021,20836006), 国家863项目2009AA03Z215，天津工业大学中空纤维膜材料与膜过程省部共建国家重点实验室培育基地开放基金

作者简介：

作者简介：祁文博(1985-)，女，甘肃张掖，硕士生，从事炭材料及膜材料的研究

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