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扩散渗析法回收精氨酸生产过程中的盐酸

作者：李传润¹，²，王虎传¹，张旭²，陶振¹，华伟¹，杨伟华²，徐铜文²

单位： 1.安徽中医学院药学院，合肥 230031；2. 中国科学技术大学化学与材料科学学院功能膜研究室，合肥 230026

关键词：酸回收；扩散渗析；膜；精氨酸

DOI号：

分类号： TQ09

出版年,卷(期):页码： 2012,32(4):102-106

摘要：

为了解决精氨酸生产过程中的无机酸回收和循环再利用问题，本文采用阴膜扩散渗析法，针对模拟的精氨酸和盐酸混合液，在静态扩散条件下测定了盐酸的渗析系数，并考察了动态扩散渗析操作参数如流速、流速比对酸回收率的影响。结果表明，采用DF-120阴离子交换膜，在静态扩散渗析中，盐酸能够顺利地透过膜，精氨酸几乎不能透过；动态扩散实验中流速、流速比对酸的回收率和回收酸的浓度有重要影响，随着流速的增加，盐酸的回收率逐渐降低，精氨酸的截留率基本上没有改变，均达到98.5%以上。流速为2mL/min时，盐酸回收率最高，可达82%，水/料液流速比增大时，盐酸的回收率增大，但是过高的水/料液流速比又会使回收酸的浓度降低。经济核算表明，对于一个年产30吨精氨酸的企业，相对于中和法，膜扩散渗析法一年能节省的化学原料总费用约98万元，投资回收期为8个月。

Diffusion dialysis with DF-120 anion exchange membrane was adopted to achieve the objective of waste hydrochloric acid recycling and reusing during the Arginine (Arg) production process. The experiment was performed in a series of static and dynamic tests with a mixed Arginine and HCl industrial simulated waste acid. The diffusion dialysis coefficient of HCl across the chosen DF-120 anion exchange was measured in the static test, while some operation parameters such as flow rate and flow rate ratio on the performance of the diffusion dialysis process were investigated in the dynamic test. Results from the static experiment indicated that HCl could transport across the membrane while Arg was completely rejected and it could not be detected in the diffusate solution. Dynamic experimental results showed that the performance of the diffusion dialysis process was declined with an increase of flow rate, while the performance was enhanced with an increase of flow rate ratio. A high Arg rejection ratio of about 98.5% could be obtained and there was no obviously change of this ratio during the recovery process. The concentration of HCl in the diffusate and dialysate were decreased with an increase of water flow rate. A maximum HCl recovery ratio of about 82% could be achieved at a flow rate of 2 mL/min. A preliminary economic evaluation indicated that a 30 t/a Arg produced company could save ¥98000 per year compared with the conventional neutralization method for spent hydrochloric acid. The diffusion dialysis system also revealed that the investment-recovered period was short as about 8 months.

基金项目：

安徽省高等学校省级自然科学研究重大项目（ZD200901），安徽省教育厅重点基金（Nos. KJ2008A072,KJ2009A003）.

作者简介：

*通讯联系人

参考文献：

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