用稻草秸秆制备高气密性增强膜的方法其性能研究 |
作者:郭密,周晓洁,王晓广 |
单位: 武汉纺织大学 纺织科学与工程学院,武汉 430200 |
关键词: straw; composite;ionic liquid[bmim]Cl; enhanced membrane; airtightness antimicrobial;hygroscopic |
DOI号: |
分类号: TB332 |
出版年,卷(期):页码: 2013,33(4):59-62 |
摘要: |
将稻草经清洗、蒸汽爆破、粉碎等工艺处理后,在100℃条件下用离子液溶解稻草粉末,得到秸秆溶液,采用延流法制得了平面膜,并选用医用纱布和细平布做增强基材,将制得的秸秆溶液与细平布及医用纱布复合,冷却洗净,去除离子液后晾干,得到高气密性增强膜。并分析了平面膜的化学成分,结果表明其保留了原稻草秸秆的主要化学成分,且含量相差不大。还对增强膜与平面膜进行了表面形态、回潮率、透湿性能、透气性能、力学性能研究对比,研究结果表明,秸秆液在医用纱布和细平布表面形成无界面致密膜,这种增强膜具有高气密性、强吸湿性、较好的力学性能。 |
This paper provided a method of using straw to prepare high airtightness antimicrobial enhanced membrane, after cleaning, blasting and griding, dissolve the straw sample at 100°C in the ionic liquid [bmim]Cl, combine the straw solution with the medical gauze and cotton plain weave fabric, high airtightness antibacterial enhanced membrane can be obtained after washing and drying.Chemical composition of original membrane which hasn't composited with fiber has compared with straw's.The surface morphology, moisture regain, water vapor permeability, air permeability and mechanical properties of the enhanced membrane were studied and compared with the original membrane . The results showed basic chemical composition of the straw has been saved in the original membrane ; the straw liquid completely composites fabric surface to form a layer interface dense film; the tidied reinforced membrane has high air tightness, strong moisture absorption and good mechanical properties. |
基金项目: |
作者简介: |
郭密(1991—),女,本科生,湖北仙桃人。主要研究方向:纺织材料。通讯作者:王晓广E-mail:wangxg1978w@163.com。 |
参考文献: |
[1] 徐又一,徐志康著.高分子膜材料[M].北京:化学工业出版社,2005. [2] 杨鹏飞.纤维素在膜科学中的研究进展[J].河北化工出版社,2009,32(4):10-12. [3] 高洁,汤烈贵著.纤维素科学[M].北京:科学出版社,1999. [4] 吴翠玲,李新平,秦胜利.纤维素溶剂研究现状及应用前景[J].中国造纸学报,2004,19(2):171-175. [5] Millet M A,Baker A J,Seatter L D.Physical and chemical pretreatment for enhancing cellulose saccharification[J].Biotech Bioeng Symp,1976,6:125-53. [6] FENG L, CHEN Z L.Research Progress on Dissolution and Functional Modification of Cellulose in Ionic Liquids[J].Journal of Molecular Liquids,2008,142(1 /2 /3): 1-5. [7] SWATLOSKI R P,SPEARSK,HOLBREY J D,et al,Dissolution of cellulose with Ionic Liquids[J].Journal of the American chemical society,2002,124(18):4974-4975. [8] GAN Q,ALLEN S J, TAYLOR G.Design and operation of an integrated membrane reactor for enzymatic cellulose hydrolysis[J].Biochem Eng.J,2002,12(3):223-229. [9] Wu J, Yuan Q.Gas permeability of a novel cellulose membrane [J].Membr. Sci , 2002,(204):185-194. [10] Jie X M, Cao Y.M , Lin B,et al.Gas permeation performance of cellulose hollow fiber membrane made form the cellulose /N-methymorpholine -N-Oxide/H2O system[J].Appl.Polym.Sci,2004,(91):1873-1880. [11] 毕于运,王红彦,王道龙,等.中国稻草资源量估算及其开发利用[J].中国农学通报,2011,27(15):137-143. [12] Millet M A,Baker A J,Seatter L D.Physical and chemical pretreatment for enhancing cellulose saccharification[J].Biotech Bioeng Symp.1976,6:125-53. [13] FENG L, CHEN Z L. Research Progress on Dissolution and Functional Modification of Cellulose in Ionic Liquids[J]. Journal of Molecular Liquids, 2008, 142(1 /2 /3): 1-5. [14] SWATLOSKI R P,SPEARSK,HOLBREY J D,et al,Dissolution of cellulose with Ionic Liquids[J].Journal of the American chemical society,2002,124(18):4974-4975. [15] GAN Q, ALLEN S J, TAYLOR G. Design and operation of an integrated membrane reactor for enzymatic cellulose hydrolysis[J]. Biochem Eng. J, 2002,12(3): 223-229. [16] SWATLOSKI R P, SPEAR S K, HOLBREY J D, et al.Dissolution of Cellulose with Ionic Liquids [J]. Journal of the American Chemical Society, 2002, 124(18): 4974-4975. [17] HEINZE T,SCHWIKAL K,BARTHEL S. Ionic liquids as reaction medium in cellulose functionalization[J]. Macromol Biosci,2005,5( 6) : 520-525. [18] 瞿蔚,陈洪章,马润宇,等.皇竹草预处理制备新型再生纤维素膜[J].纤维素科学与技术,2007,15(2):2-7. |
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