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NIPS法制备小孔径SPES-PES共混UF膜及其性能表征

作者：占琦伟¹，许振良¹，胡登¹，魏永明¹，江邦和²

单位： 1化学工程联合国家重点实验室，华东理工大学化学工程研究所膜科学与工程研发中心，上海200237； 2华东理工大学华昌聚合物有限公司，上海200237

关键词：磺化聚醚砜；聚醚砜；UF膜；非溶剂致相分离法

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2014,34(2):28-31

摘要：

采用非溶剂致相分离(NIPS，nonsolvent induced phase separation)法制备了小孔径磺化聚醚砜-聚醚砜（SPES-PES）共混超滤(UF)膜，对其进行了性能表征，讨论了溶剂、聚合物浓度、聚合物配比对膜性能的影响。结果表明，溶剂对膜性能的影响较大，用N,N-二甲基乙酰胺(DMAc)制得的UF膜通量和截留率相对来说都比较好；随着聚合物SPES-PES浓度的增大，水通量减小，对PEG10000的截留率先增大再基本保持不变；根据实验结果，共混UF膜的截留分子质量(MWCO)小于6000Da，其为负电荷小孔径共混UF膜。根据Matlab计算，共混UF膜的孔径为1.98nm，其MWCO为3060Da。

Sulfonated polyethersulfone(SPES)/polyethersulfone(PES) blend UF membrane with small pore size was prepared by the nonsolvent induced phase separation(NIPS) method, and the properties were also tested. The effects of solvents, concentration of polymers and the ratio of SPES to PES on membrane performance were considered. The result showed that the solvent had a huge impact on the membrane performance. The membrane made by dimethylacetamide (DMAc) had a better performance on flux and rejection. With an increasing of the concentration of polymers the flux of water decreased while the rejection of PEG-10000 increased first and then tended to be stable. The molecular-weight cut-off (MWCO) was under 6000Da, and the membrane was negatively charged blend UF membrane with small pore size by measuring the rejections of different solutions. On the basis of Matlab calculation, the pore size and MWCO of blend UF membrane were 1.98nm and 3060Da, respectively.

基金项目：

上海市科技攻关计划(11DZ1205201和1351102000)和江苏省科技工业支撑计划(BE2013031)

作者简介：

占琦伟(1982 ~)，女，湖北襄阳人，硕士研究生，研究方向为纳滤膜制备与应用等。*通信联系人：许振良，E-mail: chemxuzl@ecust.edu.cn；电话：021-64253061；传真：021-64252989

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