纳滤去除水中布洛芬
作者:黄丹,郑甜甜,刘蕊,班允赫,张阳
单位: 沈阳师范大学 化学与生命科学学院
关键词: PPCPs ;布洛芬; 纳滤; 膜分离技术
DOI号:
分类号: X52
出版年,卷(期):页码: 2014,34(2):72-76

摘要:
分别从污染物的纳滤过程、溶液性质以及预接触时间等因素探讨了纳滤膜去除环境微污染物布洛芬的性能。结果表明随着pH的增大布洛芬水溶液在纳滤过程中的通量也随之增大,布洛芬的离子化程度逐渐增大,其与膜面负电荷的互斥作用也增强,布洛芬溶液的纳滤过程持续保持较高的截留性能;加入NOM后,布洛芬溶液膜通量明显降低,截留率值增大,膜面对IBU的吸附量降低;预接触时间的增大,对IBU的纳滤过程起始通量影响较大,膜面对IBU的累积吸附量变化并不大。
Ibuprofen, a kind of environmental micro-pollutants has been studied by nanofiltration in view of nanofiltration process, solution chemistry and pre-contact time. The results showed that the membrane permeate flux increased with the increased pH. The nanofiltration membrane has kept high retention efficiency due to the higher ionization degree at higher pH. The membrane flux has decreased dramatically with the presence of  NOM and the higher retention can be obtained while the adsorption quantity decreased. The longer pre-contact time will affect initial flux and has no big effect on the accumulative adsorption quantity of IBU.

基金项目:
国家自然科学基金项目( 20706038) ; 辽宁省教育厅科学技术研究项目( LS2010155) ; 辽宁省百千万人才工程资助项目(2012921038); 沈阳市人才资源开发专项资金

作者简介:
黄丹 ( 1988-) ,女,辽宁朝阳人,硕士,研究方向: 膜生物污染控制,联系电话:18640077251,邮箱: 781322818@qq.com 通讯作者: 张 阳( 1975-) ,女,山西沁水人,教授,博士,硕导,研究方向: 膜生物污染控制的研究。联系电话:15640061039,邮箱: zywjb1975@hotmail.com

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