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温控开/关分离膜：接枝PNIPAAm的改性研究进展

作者：简嫩梅，韩磊，徐涛

单位：贵州大学材料与冶金学院贵阳550025

关键词：温控开/关分离膜；温敏性；抗污染性

DOI号：

分类号： TQ028；TQ32

出版年,卷(期):页码： 2014,34(4):115-119

摘要：

分离膜是一种用于浓缩、分离、提纯的功能材料。但分离膜由于自身材料的限制，存在易受污染、使用寿命短等问题。在分离膜上接枝PNIPAAm，可以改善分离膜的亲水性，获得抗污染性；同时可获得温敏性，得到温控开/关分离膜。本文论述了近年来接枝PNIPAAm温敏改性在温控开/关分离膜上的研究概况及进展

Separation membranes, as functional materials, are applied to concentration, separation, refinement, etc. However, due to the limitation from the properties of component materials, separation membranes are vulnerable to be polluted and short-life. Recently, researches have fund that grafting poly(N-isopropylacrylamide) (PNIPAAm) on separation membranes directly, can confer hydrophily and pollution resistance on them. At the same time, owning to the thermosensitivity of PNIPAAm, the grafted separation membranes become thermally on-off switching separation membranes. This paper presents recent researches on them.

基金项目：

贵州大学研究生创新基金资助项目（研理工2014083）; 贵州大学教育教学改革研究项目（JG2013049）

作者简介：

简嫩梅，1991，女，江西新余，硕士研究生；研究方向：聚合物结构与性能。E-mail：xxlhtt@sina.com

参考文献：

[ ] 时钧,袁权,高从阶.膜技术手册[M].北京:化学工业出版社,2001. 225-230.
[ ]Chen Y S, Tsou P C, Lo J M, etal. Poly(N-isopropylacrylamide) hydrogels with interpenetrating multi-walled carbon nanotubes for cell sheet engineering [J]. Biomaterials, 2013, 34: 7328–7334.
[ ]Kim M, Kiyohara S, Konishi S, etal. Ring-opening Reaction of Poly-GMA Chain Grafted onto a Porous Membrane[J]. Journal of Membrane Science, 1996, 117: 33-38.
[ ]Synthesis of modifi ed poly(ether ether ketone) polymer for the preparation of ultra fi ltration and nanofiltration membranes via phase inversion[J].Journal of Membrane Science, 2013, 447: 96-106.
[ ]Ye L, Zhai L F, Fang J H, etal. Synthesis and characterization of novel cross-linked quaternized poly(vinyl alcohol) membranes based on morpholine for anion exchange membranes[J].Solid State Ionics, 2013,240: 1-9.
[ ]Nonaka T, Ogata T, Kurihara S. Preparation of Poly (vinyl alcohol)-graft-N- isopropylacrylamide Copolymer Membranes and Permeation of Solutes through the Membranes[J]. Journal of Applied Polymer Science, 1994, 52: 951-957.
[ ] Ogata T, Nonaka T. Permeation of solutes with different molecular size and hydrophobicity through the poly(vinyl alcohol)-graft-N-isopropylacrylamide copolymer membrane[J].Journal of Membrane Science,1995,103: 159-165.
[ ] 翟茂林,余振，李军等.PVA膜共辐射接枝改性的初步研究[J].同位素,1999,12: 146-149.
[ ] 李旭祥.分离膜制备与应用[M],北京:化学工业出版社,2004.69-71.
[ ]Peng Y L, Dong Y J, Fan H W, etal. Preparation of polysulfone membranes via vapor-induced phase separation and simulation of direct-contact membrane distillation by measuring hydrophobic layer thickness[J]. Desalination, 2013, 316: 53-66.
[ ]董春华,齐崴,何志敏.接枝丙烯酸亲水化改性聚砜及其在多肽分离中的应用[J].化工学报,2007,58: 1501-1506.
[ ]Hesampour M, Huuhilo T, Makinen K, etal. Grafting of temperature sensitive PNIPAAm on hydrophilised polysulfone UF membranes[J].Journal of Membrane Science, 2008, 310: 85–92.
[ ]Drioli E, Ali A, Simone S, etal. Novel PVDF hollow fiber membranes for vacuum and direct contact membrane distillation applications[J]. Separation and Purification Technology, 2013, 115: 27-38.
[ ] 陈莉,陆尔力,王闻宇等.温敏型聚偏氟乙烯膜材料的合成及表征[J].功能材料, 2007, 38: 1990-1992.
[ ] 王闻宇,陈莉.聚偏氟乙烯复合膜的温度响应性研究[A].复合材料—基础、创新、高效：第十四届全国复合材料学术会议论文集（下）[C]. 中国湖北: 第十四届全国复合材料学术会议,2006.702-705.
[ ]Guo Y, Feng X, Chen L, etal. Influence of the Coagulation-Bath Temperature on thePhase-Separation Process of Poly(vinylidene Fluoride)-graft-Poly(N-isopropylacrylamide) Solutions and Membrane Structures[J]. Journal of Applied Polymer Science, 2010, 116: 1005–1009.
[ ]林先凯,冯霞,陈莉.ATRP法合成接枝共聚物PVDF-g-PNIPAAm及其分离膜的研究[J].高等学校化学学报, 2010,31: 402-405.
[ ] Wang W, Chen L. “Smart” Membrane Materials: Preparation andCharacterization of PVDF-g -PNIPAAm Graft Copolymer[J].Journal of Applied Polymer Science, 2007,104:1482–1486.
[ ]Ying L, Kang E T, Neoh K G. Synthesis and Characterization of Poly(N-isopropylacrylamide)–graft– Poly (vinylidenefluoride) Copolymers and Temperature-Sensitive Membranes [J].Langmuir, 2002,18: 6416-6423.
[ ] Ying L, Kang E T, Neoh K G., etal. Novel Poly(N-isopropylacrylamide)-graft-poly(vinylidene ?uoride) Copolymers for Temperature-Sensitive Micro?ltration Membranes[J].Macromolecular Material Engineering,2003,288: 11–16.
[ ]Yu J, Zhu L, Zhu B, etal. Poly(N-isopropylacrylamide) grafted poly(vinylidene ?uoride) copolymers for temperature-sensitive membranes[J]. Journal of Membrane Science, 2011, 366: 176–183.
[ ]Shen X, Zhao Y, Zhang Q, etal. Dry – wet spinning of temperature-sensitive PVDF hollow-fiber membranes at different bore fluid flow rates[J].Polym Res 2013, 20: 136.
[ ]Wang W Y, Chen L, Yu X. Preparation of Temperature Sensitive Poly(vinylidene?uoride) Hollow Fiber Membranes Grafted with N-isopropylacrylamide by a Novel Approach[J].Journalof Applied Polymer Science, 2006,101:833–837.
[ ]Liu Q, Zhu Z, Yang X, etal. Temperature-sensitive porous membrane production throughradiation co-grafting of NIPAAm on/in PVDFporous membrane[J]. Radiation Physics and Chemistry, 2007,76: 707–713.
[ ]Mazzei R, Smolko E, Tadey D, etal. Radiation grafting of NIPAAm on PVDF nuclear trackmembranes [J].Nuclear Instruments and Methods in Physics Research, B. 2000,170: 419–426.
[ ]Huang J, Wang X L, Qi W S, etal. Temperature sensitivity and electrokinetic behavior of a NGsopropylacrylamide grafted microporous polyethylene membrane[J].Desalination,2002,146: 345-351.
[ ] 齐旺顺,王晓琳,黄健等.N-异丙基丙烯酰胺接枝聚乙烯微孔膜的结构形态和动电现象[J].膜科学与技术,2003,23: 001-006.
[ ]Jacobasch H J, Schurz J. Characterization of polymer surfaces by means of electrokinetic measurements [J ]. Prog Colloid Polym Sci, 1988,77: 40-48.
[ ]Liang L, Feng X, Peurrung L, etal. Temperature-sensitive membranes prepared by UV photopolymerization of N-isopropylacrylamide on asurface of porous hydrophilic polypropylene membranes[J].Journal of Membrane Science,1999,162: 235–246.
[ ]Yang B, Yang W. Thermo-sensitive switching membranes regulated by pore-covering polymer brushes[J].Journal of Membrane Science,2003,218: 247–255.
[ ] Chan C M. Polymer Surface Modification and Characterization[M]. Munich Germany: Carl Hanser, GmbH & Co. 1993.204-206.
[ ]Wang W, Tian X D, Feng Y, etal. Thermally On-Off Switching Membranes Prepared by Pore-Filling Poly(N-isopropylacrylamide) Hydrogels[J]. Ind Eng Chem Res, 2010, 49: 1684–1690.
[ ]Li P, Xie R, Jiang J, etal. Thermo-responsive gating membranes with controllable length and density ofpoly(N-isopropylacrylamide) chains grafted by ATRP method[J].Journal of Membrane Science,2009,337: 310–317.

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