| 正渗透膜分离关键技术及其应用进展 |
| 作者：胡群辉，邹昊，姜莹，彭博，刘旦，梁剑 |
| 单位： 株洲时代新材料科技股份有限公司 株洲 湖南省 412007 |
| 关键词： 正渗透；渗透压；膜材料；驱动液 |
| DOI号： |
| 分类号： TQ 028. 8 |
| 出版年,卷(期):页码： 2014,34(5):109-115 |
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摘要： |
| 正渗透是一种新型的膜分离技术，具有能耗低、膜污染小及回收率高等优点，近年来在国际上得到了广泛的关注。本文简要介绍了正渗透膜分离技术的基本原理，综述了正渗透膜分离关键技术驱动液与膜材料的最新进展，简述了正渗透膜分离技术的最新应用，展望了正渗透膜分离技术的重点研究方向。 |
| Forward osmosis(FO)is a novelenvironmentally friendly membrane separation technique.In recent years, FO has drawn a lot of attentions because it possesses many advantages, including low energy consumption, low fouling propensity and high water recovery. In this paper, the principles of FO are introduced. Moreover, the key techniques (draw solutions and membranes) and application progresses are reviewed. At last, the research tendencies of FO are discussed. |
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基金项目： |
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作者简介： |
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胡群辉（1986-），男，硕士，助理工程师，从事膜材料与膜过程的研究. * 联系人 |
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参考文献： |
| [1] Elimelech M. The global challenge for adequate and safe water [J]. Journal of Water Supply: Research and Technology- AQUA 2006,55:3-10. [2] Ge Q, Ling M, Chung T-S. Draw Solutions for Forward Osmosis Processes: Developments, Challenges, and Prospects for the Future [J]. Journal of Membrane Science 2013,442:225-237. [3]高从堦, 郑根江, 汪锰, 等. 正渗透-水纯化和脱盐的新途径 [J]. 水处理技术2008,34(2):1-8. [4]解一君, 马睿, 夏圣骥, 等. 正渗透水处理技术研究进展 [J]. 给水排水2012,38:109-112. [5] 施人莉, 杨庆峰. 正渗透膜分离的研究进展 [J]. 化工进展2011,30(1):66-73. [6] Cath T Y, Childress A E, Elimelech M. Forward osmosis: Principles, applications, and recent developments [J]. Journal of Membrane Science 2006,281:70-87. [7] Zhao S, Zou L, Tang C Y, et al. Recent developments in forward osmosis: Opportunities and challenges [J]. Journal of Membrane Science 2012,396:1-21. [8]方彦彦, 田野, 王晓琳. 正渗透的机理 [J]. 膜科学与技术2011,31(6):95-100. [9]王亚琴, 徐铜文, 王焕庭. 正渗透原理及分离传质过程浅析 [J]. 化工学报2013,64(1):252-260. [10] 王薇, 孙静, 王宝春. 正渗透过程参数对渗透性的影响[J]. 高分子材料科学与工程2012,28(1):86-88. [11] 李刚, 李雪梅, 柳越, 等. 正渗透原理及浓差极化现象 [J]. 化学进展2010,22(5):812-821. [12] 王一鸣, 杨贵盛, 李习臣. 正渗透基本原理及其工程应用 [J]. 化工技术与开发2012,41(4):24-26. [13] Mi B X, Elimelech M. Organic fouling of forward osmosis membranes: Fouling reversibility and cleaning without chemical reagents [J]. Journal of Membrane Science 2010,348:337-345. [14] Chung T S, Zhang S, Wang K Y, et al. Forward osmosis processes: yesterday, today and tomorrow [J]. Desalination 2012,287:78-81. [15] Shannon M A, Bohn P W, Elimelech M, et al. Science and technology for water purification in the coming decades [J]. Nature 2008,452:301-310. [16] 贾奇博, 韩洪亮, 刘必前, 等. 基于海水淡化的正渗透膜分离技术的发展 [J]. 化学通报2012,75(9):771-780. [17] 李海兰,贾玉香, 胡仰栋. 以荷电化碳纳米管构筑正渗透膜用于海水淡化的分子动力学模拟[J]. 物理化学学报2012,28(3):573-577. [18] 崔迎, 顾玲, 吴国旭. 正向渗透分离技术在水处理中的应用研究进展 [J]. 中国给水排水2010,26(14):38-41. [19] 林红军, 陈建荣, 陆晓峰, 等. 正渗透膜技术在水处理中的应用进展 [J]. 环境科学与技术2010,33(12F):411-415. [20] 李刚, 李雪梅, 王铎, 等. 正渗透膜技术及其应用 [J]. 化工进展2010,29(8):1388-1398. [21] 佘乾洪, 迟莉娜, 周伟丽, 等. 正渗透膜分离技术及其在水处理中的应用与研究 [J]. 环境科学与技术2010,33(3):117-122. [22] McGinnis R L, Elimelech M. Global challenges in energy and water supply: the promise of engineered osmosis [J]. Environmental Science & Technology 2008,42:8625-8629. [23]Yang Q, Wang KY, Chung T-S. A novel dual-layer forward osmosis membrane for protein enrichment and concentration [J].Separation and Puri?cationTechnology 2009,69:269–274. [24] WangKY, Teoh MM, Nugroho A, et al. Integrated forwardosmosis–membranedistillation(FO–MD)hybrid system for the concentration of protein solutions [J].Chemical Engineering Science 2011,66:2421–2430. [25] 李丽丽, 许春玲, 王铎. 正渗透膜用于橙汁浓缩及其污染研究 [J]. 膜科学与技术2012,32(6):87-91. [26] Popper K, Camirand WM, Nury F, et al. Dialyzer concentratesbeverages[J].Food Eng. 1966,38:102–104. [27] Garcia-Castello E M, McCutcheon J R, Elimelech M. Performance evaluation of sucrose concentration using forward osmosis [J]. Journal of Membrane Science 2009,338:61-66. [28]李刚, 李雪梅, 何涛, 等. 正渗透膜材料与驱动体系的研究 [J]. 膜科学与技术2012,32(2):104-106. [29]张乾, 时强, 阮国岭, 等. 正渗透水处理关键技术研究进展 [J]. 工业水处理2012,32(5):5-9. [30]Phuntsho S, Sahebi S, Majeed T, et al. Assessing the major factors affecting the performances of forward osmosis and its implications on the desalination process [J]. Chemical Engineering Journal,231:484-496. [31] 宗同强, 赵玉宏, 张芙蓉, 等. 正渗透驱动液的发展状况与趋势 [J]. 广州化学2013,38(2):72-76. [32] 魏金枝, 孙晓君, 宫正. 正渗透技术中汲取液的研究进展 [J]. 哈尔滨理工大学学报2013,18(1):61-66. [33] 刘蕾蕾, 王铎, 汪锰, 等. 三醋酸纤维素正渗透膜制备过程中影响因素的研究 [J]. 膜科学与技术2011,31(1):77-83. [34] 李丽丽, 王铎. 醋酸纤维素正渗透膜的制备与性能研究 [J]. 功能材料2012,5(43):595-598. [35] 宣瑶芳, 吕振华, 俞三传, 等. 荷电中空纤维复合膜及其正渗透性能研究 [J]. 水处理技术2012,38(11):65-68. [36] 樊晋琼, 苏燕, 王铎. 二氧化钛/聚酰胺正渗透复合膜的制备与表征 [J]. 水处理技术2012,38(9):43-53. [37] Neff R A. Solvent extractor [P]. US: 3,130,156, 1964. [38] McCutcheon J R, McGinnis R L, Elimelech M. Desalination by a novel ammonia–carbon dioxide forward osmosis process: In?uence of draw and feed solution concentrations on process performance [J]. Journal of Membrane Science 2006,278:114-123. [39] Batchelder G W. Process for the demineralization of water [P]. US: 3,171,799, 1965. [40] Glew D N. Process for liquid recovery and solution concentration [P]. US: 3,216,930, 1965. [41] McGinnis R L. Osmotic desalination process [P]. US: 6,391,205 B1, 2002. [42] Frank B S. Desalination of sea water [P]. US: 3,670,897, 1972. [43]Achilli A, Cath T Y, Childress A E. Selection of inorganic-based draw solutions for forward osmosis applications [J]. Journal of Membrane Science 2010,364:233-241. [44] Phuntsho S, Shon H K, Hong S, et al. A novel low energy fertilizer driven forward osmosis desalination for direct fertigation: Evaluating the performance of fertilizer draw solutions [J]. Journal of Membrane Science 2011,375:172-181. [45]Su J, Chung T-S, Helmer B J, et al. Enhanced double-skinned FO membranes withinner dense layer for wastewater treatment and macromolecule recycle using Sucrose as draw solute [J]. Journal of Membrane Science 2012,396:92-100. [46] Yen S K, Haja F M, Su M, et al. Study of draw solutes using 2-methylimidazole-based compounds in forward osmosis [J]. Journal of Membrane Science 2010,364:242-252. [47] Stone M L, Wilson A D, Harrup M K, et al. An initial study of hexavalent phosphazene salts as draw solutes in forward osmosis [J]. Desalination 2013,312:130-136. [48] Ling M M, Wang K Y, Chung T-S. Highly Water-Soluble Magnetic Nanoparticles as Novel Draw Solutes in Forward Osmosis for Water Reuse [J]. Ind. Eng. Chem. Res. 2010,49:5869-5876. [49] Ling M M, Chung T-S. Desalination process using super hydrophilic nanoparticles via forward osmosis integrated with ultra?ltration regeneration [J]. Desalination 2011,278:194-202. [50] Ge Q, Su J, Amy G L, et al. Exploration of polyelectrolytes as draw solutes in forward osmosis processes [J]. Water Research 2012,46:1318-1326. [51] Li D, Zhang X, Simon G P, et al. Forward osmosis desalination using polymer hydrogels as a draw agent: In?uence of draw agent, feed solution and membrane on process performance [J]. Water Research 2013,47:209-215. [52] Noh M, Mok Y, Lee S, et al. Novel lower critical solution temperature phase transition materials effectively control osmosis by mild temperature changes [J]. Chem. Commun. 2012,48:3845-3847. [53] Li D, Zhang X, Simon G P, et al. Forward osmosis desalination using polymer hydrogels as a draw agent: Influence of draw agent, feed solution and membrane on process performance [J]. Water Research 2013,47(1):209-215. [54] Ou R, Wang Y, Wang H, et al. Thermo-sensitive polyelectrolytes as draw solutions in forward osmosis process [J]. Desalination 2013,318:48-55. [55] Razmjou A, Simon G P, Wang H. Effect of particle size on the performance of forward osmosis desalination by stimuli-responsive polymer hydrogels as a draw agent [J]. Chemical Engineering Journal 2013,215(16):913-920. [56] Su J, Yang Q, Teo J F, et al. Cellulose acetate nano?ltration hollow ?ber membranes for forward osmosis processes [J]. Journal of Membrane Science 2010,355:36-44. [57] Wang K Y, Ong R C, Chung T S. Double-skinned forward osmosis membranes for reducing internal concentration polarization within the porous sublayer [J]. Industrial & Engineering Chemistry Research 2010,49:4824-4831. [58] McCutcheon J R, Elimelech M. In?uence of membrane support layer hydrophobicity on water ?ux inosmotically driven membrane processes[J]. Journal of Membrane Science 2008,318:458-466. [59] Sairam M, Sereewatthanawut E, Li K, et al. Method for the preparation of cellulose acetate ?at sheet composite membranes for forward osmosis- desalination using MgSO4 draw solution [J]. Desalination 2011,273:299-307. [60] Wang K Y, Chung T S, Qin J J. Polybenzimidazole(PBI) nano?ltration hollow ?ber membranes applied in forward osmosis process [J]. Journal of Membrane Science 2007,300:6-12. [61] Yip N Y, Tiraferri A, Phillip W A, et al. High performance thin-?lm composite forward osmosis membrane [J]. EnvironmentalScience & Technology 2010, 44:3812-3818. [62] Wang R, Shi L, Tang C Y, et al. Characterization of novel forward osmosis hollow ?ber membranes [J]. Journal of Membrane Science 2010,355:158-167. [63] Widjojo N, Chung T-S, Weber M, et al. The role of sulphonated polymer and macrovoid-free structure in the support layer for thin-?lm composite (TFC) forward osmosis (FO) membranes [J]. Journal of Membrane Science 2011,383:214-223. [64] Bui N-N, Lind M L, Hoek E M V, et al. Electrospun nano?ber supported thin ?lm composite membranes for engineered osmosis [J]. Journal of Membrane Science 2011,385-386:10-19. [65] Cho Y H, Han J, Han S, et al. Polyamide thin-film composite membranes based on carboxylated polysulfone microporous support membranes for forward osmosis [J]. Journal of Membrane Science 2013,445:220-227. [66] Tian M, Qiu C, Liao Y, et al. Preparation of polyamide thin film composite forward osmosis membranes using electrospun polyvinylidene fluoride (PVDF) nanofibers as substrates [J]. Separation and Purification Technology 2013,118:727-736. [67] Wang Y, Ou R, Ge Q, et al. Preparation of polyethersulfone/carbon nanotube substrate for high-performance forward osmosis membrane [J]. Desalination 2013,330:70-78 [68] Tiraferri A, Kang Y, Giannelis E P, et al.Highly hydrophilic thin-film composite forward osmosis membranes functionalized with surface-tailored nanoparticles [J]. Applied Materials & Interfaces 2012,4:5044-5056. [69] Arena J T, McCloskey B, Freeman B D, et al. Surface modi?cation of thin ?lm composite membrane support layers with polydopamine: Enabling use of reverse osmosis membranes in pressure retarded osmosis [J]. Journal of Membrane Science 2011,375:55-62. [70] Setiawan L, Wang R, Li K, et al. Fabrication of novel poly(amide–imide) forward osmosis hollow fiber membranes with a positively charged nanofiltration-like selective layer [J]. Journal of Membrane Science 2011,369:196-205. [71] Goh K, Setiawan L, Wei L, et al. Fabrication of novel functionalized multi-walled carbon nanotube immobilized hollow fiber membranes for enhanced performance in forward osmosis process [J]. Journal of Membrane Science 2013,446:244-254. [72] Saren Q, Qiu C Q, Tang C Y. Synthesis and characterization of novel forward osmosis membranes based on layer-by-layer assembly [J]. Environmental Science & Technology 2011,45:5201-5208. [73] Liu X, Qi S, Li Y, et al. Synthesis and characterization of novel antibacterial silver nanocomposite nanofiltration and forward osmosis membranes based on layer-by-layer assembly [J]. Water Research 2013,47:3081-3092. [74] Amini M, Jahanshahi M, Rahimpour A. Synthesis of novel thin ?lm nanocomposite (TFN) forward osmosis membranes using functionalized multi-walled carbon nanotubes [J]. Journal of Membrane Science 2013,435:233-241. [75] Kim D Y, Gu B, Kim J H, et al. Theoretical analysis of a seawater desalination process integratingforward osmosis, crystallization, and reverse osmosis[J]. Journal of Membrane Science2013,444:440-448. [76] Cath TY, Hancock NT, Lundin CD, et al.Amulti-barrier osmotic dilution process for simultaneous desalination andpuri?cation of impaired water[J]. Journal of Membrane Science 2010,362:417-426. [77] Hancock N T, Xu P, Roby M J, et al. Towards direct potable reuse with forward osmosis: Technical assessment of long-term process performance at the pilot scale[J]. Journal of Membrane Science 2013,445:34-46. [78] Cornelissen ER, Harmsen D, de Korte KF, et al. Membranefouling and process performance of forward osmosis membranes on activated sludge[J]. Journal of Membrane Science2008,319:58-168. |
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