平板膜生物反应器膜间距与曝气气泡形态对膜污染形成的影响
作者:王栋, 冯超, 陈亚中, 朱昊, 王琪, 崔鹏
单位: 合肥工业大学化学工程学院, 安徽省可控化学与材料化工重点实验室, 合肥, 230009
关键词: 平板膜生物反应器; 膜污染; 膜间距; 气泡形态; 曝气孔径
DOI号:
分类号: X703.1
出版年,卷(期):页码: 2014,34(6):100-105

摘要:
以平板膜生物反应器为研究对象, 研究了不同膜间距(4.0mm, 8.0mm, 12.0mm)和不同曝气管开孔直径(1.0mm, 2.0mm, 3.0mm)对膜污染的影响. 同时建立了模拟膜生物反应器, 采用摄像和图形分析法观测了气泡在膜间的上升运动. 结果表明在相同比曝气量下, 膜间距为4.0mm时, 膜污染程度最轻. 摄像和图形分析结果表明膜间距为4.0mm 时, 气泡形状为球帽形, 气泡扭曲变形程度最大, 单个气泡冲刷面积最大, 但气泡上升速度由于“壁效应”而明显减小. 在不同曝气孔径下比较了膜阻力上升速率和活性污泥悬浮液中溶解氧的差异, 曝气开孔直径为1.0mm时, 膜阻力上升速率最小, 活性污泥悬浮液中溶解氧浓度最大, 曝气开孔直径为1.0mm的管状曝气器既能有效控制膜污染, 又能给微生物提供较高的溶解氧, 是较为理想的曝气器.
Membrane bioreactor constructed from flat-sheet membranes was built on a lab scale to study the influences of clearance between membranes (4.0, 8.0 and 12.0 mm, respectively), air bubbling intensity and air bubbling size (tubular bubbling device with orifices of different diameter of 1.0, 2.0 and 3.0 mm) on the membrane fouling process.  A simulated membrane bioreactor was constructed to study the bubble formation, shapes and rising between membrane clearances using clean water as permeate.  The results indicated that when the membrane clearance was 4.0 mm, membrane fouling rate was the smallest.  Observation of the bubble formation and movement through image pickup in the simulated membrane bioreactor and image analysis revealed that when the clearance of the membranes was 4.0 mm, the bubble deforms through distortion to the largest extent and emerges as cap shape, providing the largest scouring surface of the membranes.  The uprising velocity of bubble is significantly reduced due to the “wall effects”.  For the bubbling devices with different orifice diameter, the one with 1.0 mm orifice diameter efficiently reduced the membrane fouling rate, simultaneously providing higher concentration dissolved oxygen for the aeration MBR.

基金项目:
安徽省高等学校自然科学研究项目(KJ2012A240)

作者简介:
王栋(1988—), 男, 安徽省安庆市人, 硕士, 主要从事膜生物反应器过程的膜污染及其控制研究.

参考文献:
[1] Drews A. Membrane fouling in membrane bioreactors-characterisation, contradictions, cause and cures [J]. J Membr Sci, 2010, 363 (1–2):1–28.
[2] Yang W, Cicek N, Ilg J. State-of-the-art of membrane bioreactors: worldwide research and commercial applications in North America [J]. J Membr Sci, 2006, 270 (2):201–211.
[3] 华娟, 吴志超, 刘江峰, 等. 影响一体式平板膜生物反应器临界通量的因素[J]. 膜科学与技术, 2007, 27(6):13-16.
[4] Böhm L, Drews A, Kraume M. Bubble induced shear stress in flat sheet membrane systems-Serial examination of single bubble experiments with the electrodiffusion method [J]. J Membr Sci, 2013, 437 (1):131–140.
[5] Ndinisa N V, Fane A G, Wiley D E. Fouling control in a submerged flat sheet membrane system: Part I–Bubbling and hydrodynamic effects [J]. Sep Sci Technol, 2006, 41(7): 1383–1409.
[6] Essemiani K, Ducom G, Cabassud C, et al. Spherical cap bubbles in a flat sheet nanofiltration module: experiments and numerical simulation [J]. Chem Eng Sci, 2001, 56(21-22):6321-6327.
[7] Prieske H, Bohm L, Drews A, et al. Optimized hydrodynamics for membrane bioreactors with immersed flat sheet membrane modules[J]. Desalination Water Treat, 2010, 18(1-3):270–276.
[8] 张传义, 王勇, 黄霞, 等. 一体式膜生物反应器经济曝气量的试验研究[J]. 膜科学与技术., 2004, 24(5):11-15.
[9] 欧阳科, 谢珊, 刘辉. 曝气量对膜生物反应器污泥特性和膜污染的影响[J]. 中国给水排水, 2011, 27(13):19-22.
[10] Fan F S, Zhou H D. Interrelated effects of aeration and mixed liquor fractions on membrane fouling for submerged membrane bioreactor processes in wastewater treatment [J]. Environ Sci Technol, 2007, 41(7):2523–2528.
[11] Guglielmi G, Chiarani D, Judd S J, et al. Flux criticality and sustainability in a hollow fiber submerged membrane bioreactor for municipal wastewater treatment [J]. J Membr Sci, 2007, 289(1-2):241–248.
[12] 姜韶堃, 马友光, 陶志勇. 非牛顿流体中运动气泡的形变[J]. 舰船科学技术, 2010, 32(12): 38-41.
[13] Liu Z L, Zheng Y. PIV study of bubble rising behavior[J]. Powder technology, 2006, 168(1): 10-20.
[14] 肖斌. 用Adobe Photoshop CS2 图像处理软件测定油膜面积[J]. 物理教师, 2008, 29(3):39-40.
[15] Cui Z F, Chang S, Fane A G. The use of gas bubbling to enhance membrane processes [J]. J Membr Sci, 2003, 221(1-2):1–35.
[16] 李春丽, 邢世录, 陶中兰, 等. 膜生物反应器近膜面流场特性实验研究[J]. 膜科学与技术, 2013, 33(2):63-69.
[17] Krishna R, Urseanu M I, van Baten J M, et al. Wall effects on the rise of single gas bubbles in liquids[J]. Int Commun Heat Mass Transfer, 1999, 26(6):781-790.
[18] Tian J Y, Xu Y P, Chen Z L, et al. Air bubbling for alleviating membrane fouling of immersed hollow-fiber membrane for ultrafiltration of river water[J]. Desalination, 2010, 260(1-3):225–230.  
[19] 羊寿生, 曝气的理论与实践[M]. 北京:中国建筑工业出版社, 1982. 74–78.

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号