| 膜技术在沼气纯化中的应用:现状与未来 |
| 作者：邱天然 王曼娜 王学军 陈晨 郑祥 |
| 单位： 邱天然，1991年出生，男，籍贯湖北潜江，硕士研究生，中国人民大学，从事气体膜分离的研究，E-mail:qiutianran0624@126.com |
| 关键词： 气体膜分离;沼气纯化;单级/多级膜分离系统;新型膜材料；耦合工艺 |
| DOI号： |
| 分类号： TQ028.8 |
| 出版年,卷(期):页码： 2015,35(6):113-120 |
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摘要： |
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沼气纯化替代天然气将是缓解能源短缺、弥补天然气需求缺口的重要途径。2005年至2014年，处理量超过100Nm³/h的膜法沼气纯化厂从4座增长至73座，总规模从13800Nm³/h扩大至127000Nm³/h。目前膜法沼气纯化厂多集中在欧美地区，主要使用聚酰亚胺（PI）、醋酸纤维膜(CA)和聚砜膜(Psf)，其CO2渗透速率在2~80GPU，CO2/CH4选择性在16-100之间。沼气纯化以二级和二段膜分离系统为主，操作压力在0.5~3MPa之间，产气甲烷纯度和甲烷回收率均可达到98%以上。新型膜材料的研发，耦合工艺以及多杂质的同步脱除工艺的应用将是沼气纯化未来的发展趋势。 |
| Biogas upgrading is an effective way to alleviate energy shortage and make up for the demand of natural gas. Since 2005,the number of membrane-based upgrading plants with capacity more than 100 Nm³/h has increasedfrom 4 to 73,and the total capacity of these plants also has increased from 13800Nm³/h to 127000Nm³/h.Nowadays,most of themembrane-based upgrading plants are located in Europe and America.the membrane applied mainly includes cellulose acetate(CA), polyimide(PI) and polysulfone(PSf), besides,theCO2permeance of these kinds of membraneis 2-80GPU and the CO2/CH4 selectivity is 16-100.Biogas upgrading mainly choose the two-step and two-stage membrane-based systems at operating pressure of 0.5~3MPa,through the upgrading proceed, the methane purity and methane yield can both achieve at 98%. In the future, the developing of membrane-based biogas upgrading technology mostly focus on the research of new membrane materials, the application ofthe coupling technicsand the simultaneous removal of multi-impurities. |
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基金项目： |
| 教育部“新世纪优秀人才支持计划资助”（NCET-12-0531）；国家自然科学基金(51478460)；中国人民大学科学研究基金（中央高校基本科研业务费专项资金资助）项目成果（10XNJ023） |
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作者简介： |
| 邱天然，1991年出生，男，籍贯湖北潜江，硕士研究生，中国人民大学，从事气体膜分离的研究，E-mail:qiutianran0624@126.com。 |
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参考文献： |
| [1]李景明. 未来:中国沼气行业的发展[A]. 2014中国（国际）生物质能源与生物质利用高峰论坛（BBS 2014）分论坛三：沼气论文集[C]. 中国上海:2014:36. [2]可再生能源中长期发展规划[R]. 北京:国家发展与改革委员会 , 2007. [3]金潇,马泽宇,徐期勇. 填埋气中二氧化碳净化技术及研究进展[J]. 可再生能源,2013(01):87~92. [4]郑戈,张全国. 沼气提纯生物天然气技术研究进展[J]. 农业工程学报,2013,29(17):1~8. [5]Anneli Peterson,Arthur WELLINGER. Biogas Upgrading Technologies [R]. Paris, France:International Energy Agency, 2009. [6]国家质量技术监督局. GB18047-2000,车用压缩天然气[S]. 2000. [7]国家能源局. SYT 5922-2012,天然气管道运行规范[S]. 2012. [8]国家质检总局. GB17820-2012,天然气[S]. 2012. [9]江皓,吴全贵,周红军. 沼气净化提纯制生物甲烷技术与应用[J]. 中国沼气,2012,30(2):6~11. [10]biogas to biomethane technology review[R]. vienna university of technology, 2012. [11]Daniela Thrän. Biomethane——Status and Factors Affecting Market Development and Biomethane Status and Factors Affecting Market Development and Trade[R]. IEA, 2014. [12]J. K. Adewole,A. L. Ahmad,S. Ismail,et al. Current challenges in membrane separation of CO2 from natural gas: A review[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL,2013,17:46~65. [13]Colin A. Scholes,Geoff W. Stevens,Sandra E. Kentish. Membrane gas separation applications in natural gas processing[J]. Fuel,2012,96:15~28. [14]R. W. Baker,K. Lokhandwala. Natural gas processing with membranes: An overview[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2008,47(7):2109~2121. [15]Dian Andriani,Arini Wresta,Tinton Dwi Atmaja,et al. A Review on Optimization Production and Upgrading Biogas Through CO2 Removal Using Various Techniques[J]. Applied Biochemistry and Biotechnology,2014,172(4):1909~1928. [16]Fredric Bauer,Christian Hulteberg,Tobias Persson,et al. Biogas upgrading-Review of commercial technologies[R]., 2013. [17]Marco Scholz,Thomas Melin,Matthias Wessling. Transforming biogas into biomethane using membrane technology[J]. Renewable and Sustainable Energy Reviews,2013,17:199~212. [18]Energy from Biogas[R]. International Energy Agency, 2013. [19]Our references[EB/OL]. http://www.airliquideadvancedtechnologies.com/en/our-offer/biogas/nos-references.html?themesleft=&themesright=&themesyear=&page=1. [20]IEA. Plant Lists[Z]. 2014. [21]Yuan Zhang,Jaka Sunarso,Shaomin Liu,et al. Current status and development of membranes for CO2/CH4 separation: A review[J]. International Journal of Greenhouse Gas Control,2013,12(0):84~107. [22]S. Basu,A. L. Khan,A. Cano-Odena,et al. Membrane-based technologies for biogas separations[J]. Chem Soc Rev,2010,39(2):750~768. [23]A. Bos,I. G. M. Pünt,M. Wessling,et al. CO2-induced plasticization phenomena in glassy polymers[J]. Journal of Membrane Science,1999,155(1):67~78. [24]David F. Sanders,Zachary P. Smith,Ruilan Guo,et al. Energy-efficient polymeric gas separation membranes for a sustainable future: A?review[J]. Polymer,2013,54(18):4729~4761. [25]丑树人,任吉中,李晖,等. 高性能聚醚酰亚胺中空纤维气体分离膜的制备与分离性能[J]. 膜科学与技术,2010(03):21~26. [26]殷璎. 酸性气体分离膜的研究现状及进展[J]. 江西化工,2014(02):12~15. [27]谭婷婷,展侠,冯旭东,等. 高分子基气体分离膜材料研究进展[J]. 化工新型材料,2012(10):4~5. [28]谭喆,周勇,高从堦. 优先渗透CO_2的膜材料研究进展[J]. 膜科学与技术,2014(01):121~127. [29]郭正军,李辉,王树立. 膜分离-变压吸附集成工艺脱除天然气中酸性气体[J]. 过滤与分离,2008(01):34~35. [30]S. Sridhar,R. S. Veerapur,M. B. Patil,et al. Matrimid polyimide membranes for the separation of carbon dioxide from methane[J]. Journal of Applied Polymer Science,2007,106(3):1585~1594. [31]丁晓莉,曹义鸣,赵红永,等. 聚酰亚胺中空纤维气体分离膜的物理老化现象[J]. 高校化学工程学报,2010(03):382~387. [32]Marco Scholz,Michael Alders,Theresa Lohaus,et al. Structural optimization of membrane-based biogas upgrading processes[J]. Journal of Membrane Science,2015,474(0):1~10. [33]Prodip K. Kundu,Amit Chakma,Xianshe Feng. Modelling of multicomponent gas separation with asymmetric hollow fibre membranes—methane enrichment from biogas[J]. The Canadian Journal of Chemical Engineering,2013,91(6):1092~1102. [34]A. Molino,F. Nanna,M. Migliori,et al. Experimental and simulation results for biomethane production using peek hollow fiber membrane[J]. Fuel,2013,112:489~493. [35]P. Iovane,F. Nanna,Y. Ding,et al. Experimental test with polymeric membrane for the biogas purification from CO2 and H2S[J]. Fuel,2014,135(0):352~358. [36]A. Molino,F. Nanna,Y. Ding,et al. Biomethane production by anaerobic digestion of organic waste[J]. Fuel,2013,103(0):1003~1009. [37]黑龙江省森林工程与环境研究所. 一种同步分离纯化沼气中甲烷与二氧化碳的膜装置[P]. 发明专利,201110366049.5. [38]梁素钰,王述洋,李二平,等. 沼气制取车用天然气级燃料系统[J]. 农业工程学报,2009(06):210~213. [39]Kee Hong Kim,Ki Jun Baik,In Won Kim,et al. Optimization of Membrane Process for Methane Recovery from Biogas[J]. Separation Science and Technology,2012,47(7):963~971. [40]阮雪华,贺高红,肖武,等. 生物甲烷膜分离提纯系统的设计与优化[J]. 化工学报,2014(05):1688~1695. [41]L. Y. Deng,M. B. Hagg. Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL,2010,4(4):638~646. [42]R. Rautenbach. 膜工艺-组件和装置设计基础[M]. 化学工业出版社,1998:352~353. [43]王志,袁芳,王明,等. 分离CO_2膜技术[J]. 膜科学与技术,2011(03):11~17. [44]Dongxiao Yang,Zhi Wang,Jixiao Wang,et al. Parametric Study of the Membrane Process for Carbon Dioxide Removal from Natural Gas[J]. Industrial & Engineering Chemistry Research,2009,48(19):9013~9022. [45]Martin Miltner,Aleksander Makaruk,Michael Harasek. Investigation of the long-term performance of an industrial-scale biogas upgrading plant with grid supply applying gas permeation membranes[J]. CHEMICAL ENGINEERING,2010,21. [46]Martin Miltner,Aleksander Makaruk,Harald Bala,et al. Biogas Upgrading for Transportation Purposes--Operational Experiences with Austria’s First Bio-CNG Fuelling Station[J]. Chemical Engineering Transactions,2009,18:617~622. [47]M. Miltner,A. Makaruk,M. Harasek. APPLICATION OF GAS PERMEATION FOR BIOGAS UPGRADE – OPERATIONAL EXPERIENCES OF FEEDING BIOMETHANE INTO THE AUSTRIAN GAS GRID[A]. 16th European biomass conference and exhibition[C]. Valencia，Spain:2008. [48]S. O. Masebinu,A. O. Aboyade,E. Muzenda. Parametric Study of Single and Double Stage Membrane Configuration in Methane Enrichment Process[C]. San Francisco, USA: 2014. [49]A. K. Datta,P. K. Sen. Optimization of membrane unit for removing carbon dioxide from natural gas[J]. JOURNAL OF MEMBRANE SCIENCE,2006,283(1-2):291~300. [50]王学松. 气体膜技术[M]. 北京:化学工业出版社,2010:13~22. [51]王剑,张晓萍,李恩田,等. 膜法天然气脱硫的研究进展[J]. 环境工程,2014(01):135~139. [52]Hafez Maghsoudi,Mohammad Soltanieh. Simultaneous separation of H2S and CO2 from CH4 by a high silica CHA-type zeolite membrane[J]. Journal of Membrane Science,2014,470(0):159~165. [53]K. A. Lokhandwala,I. Pinnau,Z. J. He,et al. Membrane separation of nitrogen from natural gas: A case study from membrane synthesis to commercial deployment[J]. JOURNAL OF MEMBRANE SCIENCE,2010,346(2):270~279. |
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