耐氧化芳香聚酰胺反渗透膜的研究进展 |
作者:邴绍所,周勇*,高从堦 |
单位: 浙江工业大学 海洋学院,杭州 310014 |
关键词: 反渗透膜;芳香聚酰胺;耐氯性;研究进展 |
DOI号: |
分类号: TQ028.8 |
出版年,卷(期):页码: 2016,36(2):115-121 |
摘要: |
复合反渗透膜耐氧化性差,其聚酰胺皮层易受活性氯的攻击而发生结构降解,使膜性能迅速下降,寿命衰减。本文介绍了聚酰胺膜的氯化机理以及膜性能的衰减机理。然后综述了三十多年来,尤其是近几年来国内外耐氯反渗透膜的研究工作,并将其归纳为三类:聚酰胺膜材料的改性、开发新型耐氯膜材料和改进制膜工艺等。最后对耐氯聚酰胺反渗透膜的发展提出了几点建议。 |
Aromatic polyamide reverse osmosis(RO)membrane has poor tolerance to chlorine, because its active layer is very sensitive to attack by active chlorine, which affects the structural integrity of the layer leading to impaired performance. The mechanism of chlorination and its subsequent performance degradation was described. Works on chlorine-resistant RO membrane were reviewed over past thirty years, especially in recent years, which could be summarized as: modification of polyamide membrane, the search for new materials and improvements to the technique of making membranes. Finally, several suggestions for the developments chlorine-resistant polyamide RO membrane were made. |
基金项目: |
国家973项目,海水淡化膜高性能化的混合基质方法(2015CB655303) |
作者简介: |
邴绍所(1991-),男,山东省日照市人,硕士生,从事分离膜制备及改性研究. *通讯作者,E-mail:zhouy@zjut.edu.cn |
参考文献: |
[1] Sourirajan S. Reverse osmois[M]. New York:Academic Press,1970 [2] Lacey R E,Loeb S. Industrial processing with membranes[M]. New York:Wiley-Interscience,1972 [3] Kesting R. Synthetic polymeric membranes. New York:McGraw-Hill,1971 [4] Koo J Y,Kim N. Composite polyamide reverse osmosis membrane and method of producing the same[P]. US Pat,6015495.2000-1-18 [5] Cadotte J E,BatzelD A,Stocker T F. Use of inorganic ammonium cation salts to maintain the flux and salt rejection characteristics of reverse osmosis and nanofiltration membranes during drying[P]. US Pat,5658460.1997-8-19 [6] 董晓静,胡小玲,岳红,等. 复合反渗透膜研究进展[J].材料导报,2002,16:52—55 [7] Arthur S D.Multilayer reverse osmosis membrane of polyamide-urea[P]. US Pat,5019264. 1991-5-28 [8] Pterson R J. Composite reverse osmosis and nanofiltrationmembranes[J]. J MembrSci,1993,83:81—150 [9] Baker R W. Membrane technology and applications[M].Third edition. John Wiley and Sons Ltd.,Chichester,2012 [10] Wilf M,Alt S. Application of low fouling RO membrane elements forreclamation of municipal wastewater[J].Desalination,2000,132:11—19 [11] Kwak S Y. Relationship of relaxation property to reverse osmosis permeability inaromatic polyamide thin-film-composite membranes[J]. Polymer,1999,40:6361—6368. [12]Konagaya S,Watanabe O. Influence of chemical structure of isophthaloyl dichloride and aliphatic, cycloaliphatic, and aromatic diamine compound polyamides on their chlorine resistance[J]. J ApplPolymSci,2000,76:201—207 [13] Avlonitis S,Hanbury W T,Hodgkiess T. Chlorine degradation of aromatic polyamide[J]. Desalination,1992,85:321—334 [14] Singh R. Polyamide polymer solution behavior under chlorination conditions[J]. JMembrSci,1994,88:285—287 [15] Wu S,Xing J,Zheng G,et al. Chlorination and oxidation of aromatic polyamides II.chlorination of some aromatic polyamides[J]. JApplPolymSci,1996,61:1305—1314 [16] Singh R. Characteristics of a chlorine-resistant reverse osmosis membrane[J]. Desalination,1994,95:27—37 [17]Kawaguchi T,Tamura H. Chlorine-resistant membrane for reverse osmosis. I. Correlation between chemical structures and chlorine resistance of polyamides[J]. JApplPolymSci,1984,29:3359—3367 [18] Zhai X,Meng J,Li R,et al. Hypochlorite treatment on thin film composite RO membrane to improve boronremoval performance[J]. Desalination,2011,274:136—143 [19] Kwon Y N,Leckie J O. Hypochlorite degradation of crosslinked polyamide membranesI. changes in chemical/morphological properties[J]. J MembrSci,2006,283:21—26 [20] Kwon Y N,Leckie J O. Hypochlorite degradation of crosslinked polyamide membranesII. Changes in hydrogen bonding behavior and performance[J]. J MembrSci,2006,282:456—464 [21] Jensen J S,Lam Y F,Helz G R. Role of amide nitrogen in water chlorination: proton NMR evidence[J]. EnvironSciTechnol,1999,33:3568—3573 [22]Zabicky J. The Chemistry of Amides[M]. New York:Wiley-Interscience,1970. 775—779 [23] 邢其毅. 基础有机化学[M]. 第2版.北京:高等教育出版社,2003 [24] Orton K J P,Soper F G,Williams G. The chlorination of anilides.PartⅢ.N-chlorination and C-chlorination as simultaneous side reactions[J]. JChemSoc,1998,998—1005 [25] Soice N P,Maladono A C,Takigawa D Y,et al. Oxidative degradation of polyamide reverse osmosis membrane: Studies of molecular model compounds and selected membranes[J]. JApplPolymSci,2003,90:1173—1184 [26] Kang G D,Gao C J,Chen W D,et al. Study on hypochlorite degradation of aromatic polyamide reverse osmosis membrane[J]. JMembrSci,2007,300:165—171 [27] 魏新渝. 高耐氯性复合反渗透膜的制备研究[D]:[博士学位论文]. 天津:天津大学,2010 [28] Gabelich C J,Frankin J C,Gerringer F W,et al. Enhanced oxidation of polyamide membranesusing monochloramine and ferrous iron[J].J MembrSci,2005,258:64—70 [29] Tessaro I C,Silva J B A,Wada K. Investigation of some aspects related to the degradation ofpolyamide membranes: aqueous chlorine oxidation catalyzed byaluminum and sodium laurel sulfate oxidation during cleaning[J].Desalination,2005,181:275—282 [30] Soice N P,Greenberg A R,Krantz W B,et al. Studies of oxidative degradation in polyamide RO membrane barrier layers using pendant drop mechanical analysis[J].J MembrSci,2004,243:345—355. [31]Konagaya S,Kuzumoto H,Watanabe O. New reverse osmosis membrane materials with higher resistance to chlorine[J]. JApplPolySci,2000,75:1357—1364 [32] Shintani T,Matsuyama H,Kurata N. Development of a chlorine-resistant polyamide reverse osmosis membrane[J]. Desalination,2007,207:340—348 [33] Buch P R,Mohan D J,Reddy A V R. Preparation, characterization and chloride stability of aromatic-cycloapliphatic polyamide thin film composite memberane[J]. J MembrSci,2008,309:36—44 [34] Murphy A P,Murugaverl B,Riley R L. Chlorine resistant polyamides and membranes made from the same[P]. US Pat,2008/0277333 A1. 2008-11-13 [35] Xu J,Wang Z,Yu L,et al. A novel reverse osmosis membrane with regenerable anti-biofouling and chlorine resistant properties[J]. J MembrSci,2013,435:80—91 [36] Zhang Z,Wang Z,Wang J,et al. Enhancing chlorine resistances and anti-biofouling properties of commercial aromatic polyamide reverse osmosis membranes by grafting 3-allyI-5,5-dimethylhydantoin and N,N′-Methylenebis (acrylamide) [J]. Desalination,2013,309:187—196 [37] 蔡志奇,梁松苗. 抗氧化复合反渗透膜的制备及其在强氧化环境下的结构与性能研究[J]. 水处理技术,2015,41(1):20—24 [38] Kwon YN,Hong S,Choi H,et al. Surface modification of a polyamide reverse osmosis membrane for chlorineresistance improvement[J]. J MembrSci,2012,415:192—198 [39] Shin D H,Kim N,Lee Y T. Modification to the polyamide TFC RO membranes for improvement of chlorine-resistance[J]. J MembrSci,2011,376:302—311. [40] 黄海,张林,侯立安. 海水淡化反渗透耐氯膜材料的研究与制备进展[J]. 中国工程科学,2014,16(7):89—94 [41] Zhang Y,Zhao C,Yan H,et al. Highly chlorine-resistant multilayer reverse osmosis membranes based on sulfonated poly (arylene ether sulfone) and poly(vinyl alcohol)[J]. Desalination,2014,336:58—63 [42] Park H B,Freeman B D,Zhang ZB,et al. Highly chlorine-tolerant polymers for desalination[J]. AngewChem,2008,120:6108—6113 [43] Jayarani M M,Kulkarni S S. Thin-film composite poly (esteramide)-based membrane[J]. Desalination,2000,130:17—30 [44]Kim S G,Hyeon D H,Chun J H,et al.NovelthinnanocompositeROmembranesforchlorineresistance[J]. Desalination and Water Treatment,2013,51:6338–6345. [45] Chae H R,Lee J,Lee C H,et al. Grapheneoxide-embeddedthin-film compositereverseosmosismembranewithhigh flux,anti-biofouling,andchlorineresistance[J]. J MembrSci,2015,483:128—135 [46] Shintani T,Matsuyama H,Kurata N. Effect of heat treatment on performance of chlorine-resistantpolyamide reverse osmosis membranes[J]. Desalination,2009,247:370—377 [47]Wu S,Zheng C,Zheng G. Truly chlorine-resistant polyamide reverse osmosis composite membrane[J]. JApplPolySci,1996,61:1147—1148 [48] Kim Y K,Lee S Y,Kim D H,et al. Preparation and characterization of thermally crosslinked chlorine resistant thin filmcomposite polyamide membranes for reverse osmosis [J]. Desalination,2010,250:865—867 [49] 吴宗策,赵小阳,何耀华,等.一种耐氧化复合反渗透膜[P]. 中国,CN200610051219.X.2006-9-19. [50] 赵小阳,何耀华,吴宗策,等. 耐氧化复合反渗透膜[P]. 中国,CN200610051200.5. 2006-8-25. |
服务与反馈: |
【文章下载】【加入收藏】 |
《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com
京公网安备11011302000819号