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乙烯基PDMS/PSF复合膜及其乙醇/水分离性能研究

作者：张国军，王乃鑫，李杰，闫浩，纪树兰

单位：北京工业大学环境与能源工程学院，北京 100124

关键词：乙烯基聚二甲基硅氧烷；渗透汽化；复合膜；分离性能

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2016,36(4):103-109

摘要：

采用浸渍法将不同端基的聚二甲基硅氧烷（PDMS）复合在聚砜基膜表面形成分离层，从而制备优先透醇渗透汽化复合膜。利用扫描电镜与接触角仪对复合膜表面的形貌和疏水性进行了表征，结果表明复合膜表面均致密均匀无缺陷，并且乙烯基PDMS（Vi-PDMS）复合膜具有更好的疏水性。通过对比两种不同端基PDMS复合膜的溶胀度以及成膜湿度对其性能的影响，发现Vi-PDMS复合膜比羟基PDMS（OH-PDMS）复合膜具有更好的耐溶胀性和抗湿性。考察了铸膜液中Vi-PDMS含量、进料液中乙醇浓度以及进料液温度对复合膜渗透汽化分离性能的影响。结果表明，当铸膜液中Vi-PDMS浓度为15wt%，进料液中乙醇浓度为5wt%，料液温度为60℃时，复合膜的渗透通量为857.1g/(m2•h)，分离因子为8.9。通过对复合膜的长期稳定性考察，表明该复合膜在700h内可稳定运行，具有一定的应用前景。

The vinyl PDMS (Vi-PDMS) and hydroxyl PDMS(OH-PDMS) were used to prepare PDMS/PSFcomposite membranesfor ethanol permselectivepervaporation via dip-coating method. Themorphology and hydrophobicity of the membranes were characterized by scanning electron microscopy (SEM) andcontact angle (CA), respectively. The results showed that the surfaceof Vi-PDMS/PScomposite membraneswere defect-freewithgood hydrophobicity. The swelling degrees and effect of humidity on pervaporation performance of the different PDMS composite membranes were compared. It is demonstrated that the Vi-PDMS composite membrane had better resistance to swelling and humidity than the OH-PDMS composite membrane. Therefore, the Vi-PDMS composite membrane has a potential application in ethanol permselectivepervaporation. The effects of casting solution concentration, feed concentration,and feed temperatureon the separation performance of the membranes were investigated. When the feed solution is 5wt% ethanol/water mixtures at 60 °C, the total permeate flux and separation factor were857.1g/(m2•h) and 8.9 respectively.Moreover, the composite membrane had a stable separation performance in 700 h, which indicated that it has a potential in industry.

基金项目：

国家“863”计划资助项目(2012AA03A607)；国家自然科学基金资助项目（21176007）

作者简介：

作者简介：张国军(1989—)，男，河北沧州人，硕士研究生，主要从事膜分离技术与应用方面的研究E-mail:hnzhangguojun@emails.bjut.edu.cn* 联系人E-mail:jshl@bjut.edu.cn

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